Adsorption Capacity of Silica SBA-15 and Titanosilicate ETS-10 toward Indium Ions.

Indium is an extremely important element for industry that is distributed in the Earth's crust at very low concentrations. The recovery of indium by silica SBA-15 and titanosilicate ETS-10 was investigated at different pH levels, temperatures, times of contact and indium concentrations. A maximum removal of indium by ETS-10 was achieved at pH 3.0, while by SBA-15 it was within the pH range of 5.0-6.0. By studying kinetics, the applicability of the Elovich model for the description of indium adsorption on silica SBA-15 was shown, while its sorption on titanosilicate ETS-10 fitted well with the pseudo-first-order model. Langmuir and Freundlich adsorption isotherms were used to explain the equanimity of the sorption process. The Langmuir model showed its applicability for the explanation of the equilibrium data obtained for both sorbents, the maximum sorption capacity obtained using the model constituted 366 mg/g for titanosilicate ETS-10 at pH 3.0, temperature 22 °C and contact time 60 min, and 2036 mg/g for silica SBA-15 at pH 6.0, temperature 22 °C and contact time 60 min. Indium recovery was not dependent on the temperature and the sorption process was spontaneous in nature. The interactions between the indium sulfate structure and surfaces of adsorbents were investigated theoretically using the ORCA quantum chemistry program package. The spent SBA-15 and ETS-10 could be easily regenerated by using 0.01 M HCl and reused with up to 6 cycles of adsorption/desorption with a decrease in the removal efficiency between 4% and 10% for SBA-15 and 5% and 10% for ETS-10, respectively.

Ion-Imprinted Polymeric Materials for Selective Adsorption of Heavy Metal Ions from Aqueous Solution.

The introduction of selective recognition sites toward certain heavy metal ions (HMIs) is a great challenge, which has a major role when the separation of species with similar physicochemical features is considered. In this context, ion-imprinted polymers (IIPs) developed based on the principle of molecular imprinting methodology, have emerged as an innovative solution. Recent advances in IIPs have shown that they exhibit higher selectivity coefficients than non-imprinted ones, which could support a large range of environmental applications starting from extraction and monitoring of HMIs to their detection and quantification. This review will emphasize the application of IIPs for selective removal of transition metal ions (including HMIs, precious metal ions, radionuclides, and rare earth metal ions) from aqueous solution by critically analyzing the most relevant literature studies from the last decade. In the first part of this review, the chemical components of IIPs, the main ion-imprinting technologies as well as the characterization methods used to evaluate the binding properties are briefly presented. In the second part, synthesis parameters, adsorption performance, and a descriptive analysis of solid phase extraction of heavy metal ions by various IIPs are provided.

Feather-weight cryostructured thiourea-chitosan aerogels for highly efficient removal of heavy metal ions and bacterial pathogens.

Designing of economically feasible and recyclable polysaccharide-based materials with thiourea functional groups for removal of specific metal ions such as Ag(I), Au(I), Pb(II) or Hg(II) remains a major challenge for environmental applications. Here, we introduce ultra-lightweight thiourea-chitosan (CSTU) aerogels engineered by combining successive freeze-thawing cycles with covalent formaldehyde-mediated cross-linking and lyophilization. All aerogels exhibited outstanding low densities (0.0021-0.0103 g/cm3) and remarkable high specific surface areas (416.64-447.26 m2/g), outperforming the common polysaccharide-based aerogels. Benefitting from their superior structural features (honeycomb interconnected pores and high porosity), CSTU aerogels demonstrate fast sorption rates and excellent performance in sorption of heavy metal ions from highly-concentrated single or binary-component mixtures (1.11 mmol Ag (I)/g and 0.48 mmol Pb(II)/g). A remarkable recycling stability was observed after five sorption-desorption-regeneration cycles when the removal efficiency was up to 80 %. These results support the high potential of CSTU aerogels in the treatment of metal-containing wastewater. Moreover, the Ag(I)-loaded CSTU aerogels exhibited excellent antimicrobial properties against Escherichia coli and Staphylococcus aureus bacterial strains, the killing rate being around 100 %. This data points towards the potential application of developed aerogels in circular economy, by employing the spent Ag(I)-loaded aerogels in the biological decontamination of waters.

Sustainable Multi-Network Cationic Cryogels for High-Efficiency Removal of Hazardous Oxyanions from Aqueous Solutions.

It is still a challenge to develop advanced materials able to simultaneously remove more than one pollutant. Exclusive cationic composite double- and triple-network cryogels, with adequate sustainability in the removal of Cr2O72- and H2PO4- oxyanions, were developed in this work starting from single-network (SN) sponges. Chitosan (CS), as the only polycation originating from renewable resources, and poly(N,N-dimethylaminoethylmethacrylate) (PDMAEMA) and polyethyleneimine (PEI), as synthetic polycations, were employed to construct multi-network cationic composite cryogels. The properties of the composites were tailored by the cross-linking degree of the first network (SN5 and SN20, which means CS with 5 or 20 mole % of glutaraldehyde, respectively) and by the order of the successive networks. FTIR, SEM-EDX, equilibrium water content and compressive tests were used in the exhaustive characterization of these polymeric composites. The sorption performances towards Cr2O72- and H2PO4- anions were evaluated in batch mode. The pseudo-first-order, pseudo-second-order (PSO) and Elovich kinetics models, and the Langmuir, Freundlich and Sips isotherm models were used to interpret the experimental results. The adsorption data were the best fitted by the PSO kinetic model and by the Sips isotherm model, indicating that the sorption mechanism was mainly controlled by chemisorption, irrespective of the structure and number of networks. The maximum sorption capacity for both oxyanions increased with the increase in the number of networks, the highest values being found for the multi-network sponges having SN5 cryogel as the first network. In binary systems, all sorbents preferred Cr2O72- ions, the selectivity coefficient being the highest for TN sponges. The high sorption capacity and remarkable reusability, with only a 4-6% drop in the sorption capacity after five sorption-desorption cycles, recommend these composite cryogels in the removal of two of the most dangerous pollutants represented by Cr2O72- and H2PO4-.

Optimization of Arsenic Removal from Aqueous Solutions Using Amidoxime Resin Hosted by Mesoporous Silica.

The paper reports on the performances of cross-linked amidoxime hosted into mesoporous silica (AMOX) in the removal of As(III) and As(V). The optimum pH for sorption of As(III) and As(V) was pH 8 and pH 5, respectively. The PFO kinetic model and the Sips isotherm fitted the best the experimental data. The thermodynamic parameters were evaluated using the equilibrium constant values given by the Sips isotherm at different temperatures and found that the adsorption process of As(III) and As(V) was spontaneous and endothermic on all AMOX sorbents. The spent AMOX sorbents could be easily regenerated with 0.2 mol/L HCl solution and reused up to five sorption/desorption cycles with an average decrease of the adsorption capacity of 18%. The adverse effect of the co-existing inorganic anions on the adsorption of As(III) and As(V) onto the sorbent with the highest sorption capacity (AMOX3) was arranged in the following order: H2PO4 - > HCO3 - > NO3 - > SO4 2-.

Aminopolycarboxylic Acids-Functionalized Chitosan-Based Composite Cryogels as Valuable Heavy Metal Ions Sorbents: Fixed-Bed Column Studies and Theoretical Analysis.

Over the years, a large number of sorption experiments using the aminopolycarboxylic acid (APCA)-functionalized adsorbents were carried out in batch conditions, but prospective research should also be directed towards column studies to check their industrial/commercial feasibility. In this context, sorption studies of five-component heavy metal ion (HMI) solutions containing Zn2+, Pb2+, Cd2+, Ni2+, and Co2+ in equimolar concentrations were assessed in fixed-bed columns using some APCA-functionalized chitosan-clinoptilolite (CS-CPL) cryogel sorbents in comparison to unmodified composite materials. The overall sorption tendency of the APCA-functionalized composite sorbents followed the sequence Co2+ < Zn2+ < Cd2+ ≤ Pb2+ < Ni2+, meaning that Co2+ ions had the lowest affinity for the sorbent's functional groups, whereas the Ni2+ ions were strongly and preferentially adsorbed. To get more insights into the application of the composite microbeads into continuous flow set-up, the kinetic data were described by Thomas and Yoon−Nelson models. A maximum theoretical HMI sorption capacity of 145.55 mg/g and a 50% breakthrough time of 121.5 min were estimated for the column containing CSEDTA-CPL cryogel sorbents; both values were much higher than those obtained for the column filled with pristine CS-CPL sorbents. In addition, desorption of HMIs from the composite microbeads in dynamic conditions was successfully achieved using 0.1 M HCl aqueous solution. Moreover, a theoretical analysis of APCA structures attached to composite adsorbents and their spatial structures within the complex combinations with transition metals was systematically performed. Starting from the most stable conformer of EDTA, coordinative combinations with HMIs can be obtained with an energy consumption of only 1 kcal/mole, which is enough to shift the spatial structure into a favorable conformation for HMI chelation.

Experimental Studies on the Removal of Aluminium Ions from Synthetic Aqueous Solution by Hydroxyapatites.

In this work we have presented the results obtained in the adsorption behavior of hydroxyapatite with different treatment towards aluminium ions from synthetic wastewaters. Experiments were performed in batch technique at different pH values, temperatures, sorbent dosage, contact time and initial aluminium concentration. The thermodynamic studies on the adsorption process of aluminium onto hydroxyapatite indicated that the process is spontaneous and endothermic. The Langmuir, Freundlich, Flory-Huggins, Dubinin-Radushkevich and Temkin equilibrium models were applied to the description of experimental data. The adsorption of aluminium follows the Langmuir adsorption isotherm. The kinetics of adsorption was evaluated using the pseudo-first order, pseudo-second order and intraparticle diffusion kinetic models. The rate of aluminium adsorption was successfully described by a pseudo-second-order kinetic model. The obtained results indicated that hydroxyapatite treated with Pluronic P123 surfactant has a higher sorption capacity toward aluminium ions (117.65 mg g-1) than hydroxyapatite treated with Pluronic F127 surfactant (109.89 mg g-1) while untreated hydroxyapatite exhibited the lowest one (104.17 mg g-1).

Analysis of Copper(II), Cobalt(II) and Iron(III) Sorption in Binary and Ternary Systems by Chitosan-Based Composite Sponges Obtained by Ice-Segregation Approach.

With the intensive industrial activity worldwide, water pollution by heavy metal ions (HMIs) has become a serious issue that requires strict and careful monitoring, as they are extremely toxic and can cause serious hazards to the environment and human health. Thus, the effective and efficient removal of HMIs still remains a challenge that needs to be solved. In this context, copper(II), cobalt(II) and iron(III) sorption by chitosan (CS)-based composite sponges was systematically investigated in binary and ternary systems. The composites sponges, formed into beads, consisting of ethylenediaminetetraacetic acid (EDTA)- or diethylenetriaminepentaacetic acid (DTPA)-functionalized CS, entrapping a natural zeolite (Z), were prepared through an ice-segregation technique. The HMI sorption performance of these cryogenically structured composite materials was assessed through batch experiments. The HMI sorption capacities of CSZ-EDTA and CSZ-DTPA composite sponges were compared to those of unmodified sorbents. The Fe(III) ions were mainly taken up when they were in two-component mixtures with Co(II) ions at pH 4, whereas Cu(II) ions were preferred when they were in two-component mixtures with Co(II) ions at pH 6. The recycling studies indicated almost unchanged removal efficiency for all CS-based composite sorbents even after the fifth cycle of sorption/desorption, supporting their remarkable chemical stability and recommending them for the treatment of HMI-containing wastewaters.

Evaluation of phosphate adsorption by porous strong base anion exchangers having hydroxyethyl substituents: kinetics, equilibrium, and thermodynamics.

Phosphate anions are recognized as the main responsible for the eutrophication of surface waters. In this work, two strong base anion exchangers having either N,N-dimethyl 2-hydroxyethylammonium (SBAEx.2M) or N,N-diethyl 2-hydroxyethylammonium (SBAEx.2E) functional groups, as highly efficient sorbents in the removal of phosphate anions, are presented. The influence of the main parameters (pH, contact time, initial concentration of phosphate, temperature) on the adsorption performances was investigated in batch mode. Modeling the kinetics data by Lagergren, Ho and McKay, and Elovich kinetic models indicated chemisorption as the main mechanism of sorption. The sorption at equilibrium was modeled with Langmuir, Freundlich, Sips, Dubinin-Radushkevich, and Temkin isotherm models. The experimental isotherms were the best fitted by Langmuir and Sips isotherms, the maximum sorption capacity for phosphate anions being 233.88 mg g-1 SBAEx.2M and 223.5 mg g-1 SBAEx.2E, at pH 3, and 23 °C. Adsorption of phosphate anions in competitive conditions showed that the interference with co-existing anions was low in the case of Cl- ions and much higher with SO42- ions, the ion exchange having an important contribution in the adsorption process. The adsorption was spontaneous and endothermic, the degree of spontaneity increasing with the increase of temperature. The high level of reusability, the adsorption capacity decreasing with only ~ 7% in the case of SBAEx.2E and with ~ 9% in the case of SBAEx.2M, after five sorption/desorption cycles, recommends these SBAEx as promising adsorbents for phosphate removal.

Superadsorbents for Strontium and Cesium Removal Enriched in Amidoxime by a Homo-IPN Strategy Connected with Porous Silica Texture.

In light of the fact that two with good compatibility are better than one, the homo-interpenetrating polymer network (IPN) strategy was used in this work to design novel amidoxime (AOX)-interpenetrating networks into porous silica (PSi) with the final aim to enhance the sorption performances of composite sorbents toward Cs+ and Sr2+. To achieve this goal, first, a homo-IPN of poly(acrylonitrile) (PAN) was constructed inside the channels of two kinds of porous silica, one mesoporous (PSi1) and one macroporous (PSi2), the textural properties of silica being exploited in controlling the sorption performances of the composites. The novel composites were fully characterized by thermogravimetric analysis (TGA), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and the nitrogen sorption/desorption isotherms (Brunauer-Emmett-Teller (BET) analysis). The sorption properties of the PSi1/AOX and PSi2/AOX composite sorbents for Sr2+ and Cs+ were investigated in the batch mode to determine the effect of solution pH, contact time, initial metal ion concentration, temperature, and the presence of competitive ions on the adsorption performances. The fast kinetics of sorption was supported by the fact that ∼80% of Sr2+ and ∼65% of Cs+ were adsorbed in the first 30 min, the kinetic data being better described by the pseudo-second-order kinetic model. The experimental isotherms were well fitted by the Langmuir and Sips isotherm models. The superadsorption of Sr2+ and Cs+ is demonstrated by the values of the maximum sorption capacity of the best sorbent constructed with mesoporous silica (PSi1/IPN-AOX), which were 344.23 mg Cs+/g and 360.23 mg Sr2+/g. The sorption process was spontaneous and endothermic for both metal ions. The presence of interfering cations (Na+, K+, Ca2+, and Mg2+), at a concentration of 10-2 M, only slightly influenced the sorption capacity for the main cation. The composite sorbents were still highly efficient after five sorption/desorption cycles.

Erratum: Dragan, E.S., et al., Contribution of Cross-Linker and Silica Morphology on Cr(VI) Sorption Performances of Organic Anion Exchangers Embedded into Silica Pores. Molecules 2020, 25, 1249.

The authors wish to make a change to the published paper [...].

Contribution of Cross-Linker and Silica Morphology on Cr(VI) Sorption Performances of Organic Anion Exchangers Embedded into Silica Pores.

Removal of Cr(VI) from the environment represents a stringent issue because of its tremendous effects on living organisms. In this context, design of sorbents with high sorption capacity for Cr(VI) is getting a strong need. For this purpose, poly(vinylbenzyl chloride), impregnated into porous silica (PSi), was cross-linked with either N,N,N',N'-tetramethyl-1,2-ethylenediamine (TEMED) or N,N,N',N'-tetramethyl-1,3-propanediamine, followed by the reaction of the free -CH2Cl groups with N,N-diethyl-2-hydroxyethylamine to generate strong base anion exchangers (ANEX) inside the pores. The PSi/ANEX composite sorbents were deeply characterized by FTIR spectroscopy, SEM-energy dispersive X-ray spectroscopy (EDX), thermogravimetric analysis (TGA), and water uptake. The sorption performances of composites against Cr(VI) were investigated as a function of pH, contact time, initial concentration of Cr(VI), and temperature. It was found that the cross-linker structure and the silica morphology are the key factors controlling the sorption capacity. The adsorption process was spontaneous and endothermic and well described by pseudo-second-order kinetic and Sips isotherm models. The maximum sorption capacity of 311.2 mg Cr(VI)/g sorbent was found for the composite prepared with mesoporous silica using TEMED as cross-linker. The PSi/ANEX composite sorbents represent an excellent alternative for the removal of Cr(VI) oxyanions, being endowed with fast kinetics, equilibrium in about 60 min, and a high level of reusability in successive sorption/desorption cycles.

Removal of heavy metal ions from multi-component aqueous solutions by eco-friendly and low-cost composite sorbents with anisotropic pores.

Copper, nickel, zinc, chromium, and iron ions are the prevailing contaminants in the aqueous effluents resulting from the photo-etching industry. In this context, we investigate here the metal ion sorption performance of an ion-imprinted cryogel (IIC), consisting of low-cost materials coming from renewable resources, towards multi-component metal ion solutions. The IIC sorbent, which is based on a chitosan matrix embedding a natural zeolite, was synthesized using a straightforward strategy by coupling copper-imprinting and unidirectional ice-templating methods. As consequence, the 1D-orientation and the interconnectivity of flow-channels sustain the fast metal ion diffusion within the IIC anisotropic structure. The removal efficiency of IIC sorbent reached 50% after 30 min, and the sorption equilibrium was attained within 150 min. For assessing the successful formation of imprinted cavities with well-defined sizes controlled by the radius of copper ions used as template, selectivity studies were performed on binary, ternary, and five-component synthetic mixtures. The efficiency of IIC as sorbent was further evaluated on real-life aqueous effluents discharged from photo-etching processes; thus, an IIC dosage of 6 g L-1 was found to remove 98.89% of Cu2+, 94.56% of Fe3+, 91.67% of Ni2+, 92.24% of Zn2+, and 82.76% of Cr3+ ions from this type of industrial wastewaters.

Development of chitosan-poly(ethyleneimine) based double network cryogels and their application as superadsorbents for phosphate.

The fabrication of novel chemically cross-linked double network cryogels (DNC), with an abundant number of amine groups, based on chitosan (CS) cross-linked with glutaraldehyde (GA), as the first network, and poly(ethyleneimine) (PEI), with a concentration up to 15% cross-linked with ethyleneglycol diglycidyl ether (EGDGE), as the second network, and their enhanced sorption capacity for phosphate ions are presented here. The phosphate sorption was fast (equilibrium in three hours) and well modeled by the pseudo-second-order kinetic model. The experimental sorption isotherms were fitted with Langmuir, Freundlich, Sips and Dubinin-Radushkevich isotherm models. The Langmuir and Sips isotherms were the best in modeling the sorption process. The maximum sorption capacity given by the Langmuir isotherm for the DNC having the highest content of GA and the highest concentration of PEI was about 343 mg phosphate/g, which placed this novel sorbent among the best sorbents for phosphate recently reported in literature.

Adsorptive Performance of Soy Bran and Mustard Husk Towards Arsenic (V) Ions from Synthetic Aqueous Solutions.

Recently, there is growing attention on the use of low-cost sorbents in the depollution of contaminated waters. As a consequence, the present work investigates the potential of soy bran and mustard husk as possible sorbent for the removal of arsenic(V) from residual water. Effects of various operating parameters such as: contact time, pH, initial arsenic concentration, pH, sorbent dose, temperature were investigated to determine the removal efficiency of arsenic(V). Thermodynamic parameters that characterize the process indicated that the adsorption is spontaneous and endothermic. The values for the separation factor, RL were less than one which confirms that the adsorption process was favorable. Equilibrium data fitted well to the Langmuir model with a higher adsorption capacity of soy bran (74.07 mg g-1) towards arsenic(V) ions than mustard husk (65.79 mg g-1). It was found that the pseudo-second order kinetic model was the best applicable model to describe the adsorption kinetic data.

Evaluation of Adsorption Capacity of Montmorillonite and Aluminium-pillared Clay for Pb2+, Cu2+ and Zn2.

Adsorption capacity of the two adsorbents was investigated as a function of contact time between adsorbent and heavy metal ions solutions, the initial heavy metals concentration of the synthetic wastewater, pH value, temperature and adsorbent mass. Preliminary experiments at different pH values between 2.0 and 7.0 were performed, and were observed that maximum adsorption occurs at pH 5 for copper (q(max) = 92.59 mg · g(­1)), 6.0 for lead (qmax = 97.08 mg · g(­1)) and 6.5 for zinc ions (q(max) = 73.52 mg · g(­1)), respectively. The sorption capacity of studied adsorbents for Pb(2+), Cu(2+) and Zn(2+) was calculated using Langmuir and Freundlich models. Thermodynamic parameters ­ enthalpy change (ΔH(0)), entropychange (ΔS(0)) and free energy (ΔG(0)) ­ were calculated for predicting the nature of adsorption. Scanning electron micrograph(SEM) revealed changes in the surface morphology of the adsorbent as a result of heavy metal ions adsorption.EDS characterization confirmed qualitatively the presence of adsorbed species in the samples. On the basis of the obtained results the adsorption it was proposed an ordered adsorption: Pb(2+), Cu(2+) and Zn(2+), on the sorbents we investigated.

Uptake of uranyl ions from uranium ores and sludges by means of Spirulina platensis, Porphyridium cruentum and Nostok linckia alga.

In this paper was studied the uranyl ions biosorption on three types of alga: Nostok linckia, Porphyridium cruentum and Spirulina platensis. These ions were supplied either from a pure solution of uranyl nitrate, or after leaching process of uranium ore, or from the sludge resulting in the output of pure UO(2) technology. It was investigated the retention degree versus contact time and afterwards the Langmuir and Freundlich biosorption isotherms of uranyl ions on the three alga types. The retention of UO(2)(2+) ions on alga was proved through FTIR spectra plotted before and after biosorption processes. From the experimental data it was found that regardless of origin of uranyl ions, the retention degree on alga decreased in the series. Spirulina platensis > Porphyridium cruentum ≥ Nostok linckia.

Adsorption characteristics of UO(2)(2+) and Th(4+) ions from simulated radioactive solutions onto chitosan/clinoptilolite sorbents.

Adsorption features of UO(2)(2+) and Th(4+) ions from simulated radioactive solutions onto a novel chitosan/clinoptilolite (CS/CPL) composite as beads have been investigated compared with chitosan cross-linked with epichlorohydrin. The effects of contact time, the initial metal ion concentration, sorbent mass and temperature on the adsorption capacity of the CS-based sorbents were investigated. The adsorption kinetics was well described by the pseudo-second order equation, and the adsorption isotherms were better fitted by the Sips model. The maximum experimental adsorption capacities were 328.32 mg Th(4+)/g composite, and 408.62 mg UO(2)(2+)/g composite. The overall adsorption tendency of CS/CPL composite toward UO(2)(2+) and Th(4+) radiocations in the presence of Cu(2+), Fe(2+) and Al(3+), under competitive conditions, followed the order: Cu(2+)>UO(2)(2+)>Fe(2+)>Al(3+), and Cu(2+)>Th(4+)>Fe(2+)>Al(3+), respectively. The negative values of Gibbs free energy of adsorption indicated the spontaneity of the adsorption of radioactive ions on both the CS/CPL composite and the cross-linked CS. The desorption level of UO(2)(2+) from the composite CS/CPL, by using 0.1M Na(2)CO(3), was around 92%, and that of Th(4+) ions, performed by 0.1M HCl, was around 85%, both values being higher than the desorption level of radiocations from the cross-linked CS, which were 89% and 83%, respectively.

On the retention of uranyl and thorium ions from radioactive solution on peat moss.

The efficiency of the radioactive uranyl and thorium ions on the peat moss from aqueous solutions has been investigated under different experimental conditions. The sorption and desorption of uranyl and thorium ions on three types (unmodified peat moss, peat moss treated with HNO(3) and peat moss treated with NaOH) of peat moss were studied by the static method. Peat moss was selected as it is available in nature, in any amount, as a cheap and accessible sorbent. Study on desorption of such ions led to the conclusion that the most favourable desorptive reagent for the uranyl ions is Na(2)CO(3) 1M while, for the thorium ions is HCl 1M. The results obtained show that the parameters here under investigation exercise a significant effect on the sorption process of the two ions. Also, the investigations performed recommend the peat moss treated with a base as a potential sorbent for the uranyl and thorium ions from a radioactive aqueous solution.

A fluorescence emission, FT-IR and UV-VIS absorption study of the some uranium (VI) Schiff bases complexes.

The capacity of metallic ions to form complexes depends on the electric charge and its mass and on the ligands nature. In this study we followed the coordination capacity of the uranyl ion (UO2(2+)) with a series of Schiff bases. The Schiff bases have been obtained through the condensation of some salicylic aldehyde derivates with a series of diamines. As a result of the reaction between these substances and the uranyl ions the mono-, bi-, or poly-nuclear complexes, depend on the nature of the ligands. The forming of the complexes is highlighted through ultraviolet-visible, Fourier transform infrared (IR), and fluorescence spectroscopy. In the IR studies the forming of the complexes is highlighted by the apparition of a new band at approximately 920 cm(-1,) characteristic to the O=U=O group. Also modifications of valence vibrations appear characteristic to the azomethinic groups, nu(C=N,) and the apparition of some new bands in the 300-500 cm(-1) domain, characteristic to forming of some new bonds U-O and U-N. The formed complexes represent tetragonal bipyramidal geometry. The study of the capacity coordination of uranyl ions is important in determining, dozing and precipitin of the ions in diverse used waters.