Production of MgFe2O4/activated carbons derived from a harmful grass Cynodon dactylon and their utilization for ciprofloxacin removal.

Cynodon dactylon, an invasive species, exhibits its robust adaptability, reproduction and nutrient regime against the local species. Taking advantage of this harmful grass as a raw precursor to produce valuable materials for wastewater treatment has paid much attention. Herein, we report on the fabrication of Cynodom dactylon derived MgFe2O4@AC with a main goal of effective removal of ciprofloxacin antibiotic from water. Our findings showed that MgFe2O4@ACK1 composites attained mesoporous textures, high specific surface areas (884.3-991.6 m2 g-1), and MgFe2O4-20%@ACK1 was the most effective with a very high removal efficiency of 96.7%. The Elovich model was suitable for describing the kinetic of adsorption with (Radj)2 of 0.9988. Meanwhile, the isotherm data obeyed the Langmuir model corresponding to (Radj)2 of 0.9993. Qmax value of MgFe2O4-20%@ACK1 was determined at 211.67 mg g-1. The proposed adsorption mechanism primarily comprises five routes as follows, (i) pore-filling, (ii) π-π interaction, (iii) electrostatic interaction, (iv) hydrogen bonding, and (v) hydrophobic interaction. MgFe2O4-20%@ACK1 adsorbent could reuse with three cycles. We recommend that MgFe2O4/ACs derived from Cynodom dactylon could be high-efficiency adsorbents for the elimination of antibiotics.

Occurrence, toxicity, impact and removal of selected non-steroidal anti-inflammatory drugs (NSAIDs): A review.

Non-steroidal anti-inflammatory drugs (NSAIDs) are among the most frequently used pharmaceuticals for human therapy, pet therapeutics, and veterinary feeds, enabling them to enter into water sources such as wastewater, soil and sediment, and seawater. The control of NSAIDs has led to the advent of the novel materials for treatment techniques. Herein, we review the occurrence, impact and toxicity of NSAIDs against aquatic microorganisms, plants and humans. Typical NSAIDs, e.g., ibuprofen, ketoprofen, diclofenac, naproxen and aspirin were detected at high concentrations in wastewater up to 2,747,000 ng L-1. NSAIDs in water could cause genotoxicity, endocrine disruption, locomotive disorders, body deformations, organs damage, and photosynthetic corruption. Considering treatment methods, among adsorbents for removal of NSAIDs from water, metal-organic frameworks (10.7-638 mg g-1) and advanced porous carbons (7.4-400 mg g-1) were the most robust. Therefore, these carbon-based adsorbents showed promise in efficiency for the treatment of NSAIDs.