RESUMO
Iridium, the most widely used anode catalyst in proton exchange membrane water electrolysis (PEMWE), must be used minimally due to its high price and limited supply. However, reducing iridium loading poses challenges due to abnormally large anode polarization. Herein, we present an anode catalyst layer (CL) based on a one-dimensional iridium nanofiber that enables a high current density operation of 3 A cm-2 at 1.86 V, even at an ultralow loading (0.07 mgIr cm-2). The performance is maintained even with a Pt coating-free porous transport layer (PTL) because our nanofiber CL circumvents the interfacial electron transport problem caused by the native oxide on the Ti PTL. We attribute this to the low work function and the low-ionomer-exposed surface of the nanofiber CL, which prevent the formation of Schottky contact at the native oxide interface. These results highlight the significance of optimizing the electronic properties of the CL/PTL interface for low-iridium-loading PEMWE.
RESUMO
The interface between the catalyst and the ionomer in the catalyst layer of polymer electrolyte membrane fuel cells (PEMFCs) has been a subject of keen interest, but its effect on durability has not been fully understood due to the complexity of the catalyst layer structure. Herein, we utilize a Pt nanoparticle (NP) array electrode fabricated using a block copolymer template as the platform for a focused investigation of the interfacial change between the Nafion thin film and the Pt NP under a constant potential. A set of analyses for the electrodes treated with various potentials reveals that the Nafion thin film becomes densely packed at the intermediate potentials (0.4 and 0.7 V), indicating an increased ionomer-catalyst interaction due to the positive charges formed at the Pt surface at these potentials. Even for a practical PEMFC single cell, we demonstrate that the potential holding at the intermediate potentials increases ionomer adsorption to the Pt surface and the oxygen transport resistance, negatively impacting its power performance. This work provides fresh insight into the mechanism behind the performance fade in PEMFCs caused by potential-dependent ionomer rearrangement.
RESUMO
Sharks, marine creatures that swim fast and have an antifouling ability, possess dermal denticle structures of micrometer-size. Because the riblet geometries on the denticles reduce the shear stress by inducing the slip of fluid parallel to the stream-wise direction, shark skin has the distinguished features of low drag and antifouling. Although much attention has been given to low-drag surfaces inspired from shark skin, it remains an important challenge to accurately mimic denticle structures in the micrometer scale and to finely control their structural features. This paper presents a novel method to create shark skin-mimetic denticle structures for low drag by exploiting a photoreconfigurable azopolymer. The light-designed denticle structure exhibits superior hydrophobicity and an antifouling effect as sharks do. This work suggests that our novel photoreconfiguration technology, mimicking shark skin and systematically manipulating various structural parameters, can be used in a reliable manner for diverse applications requiring low-drag surfaces.