RESUMO
The structure of the title compound, C27H22F2O4, at 193â K has triclinic (P ) symmetry. The hy-droxy and meth-oxy groups at the 1,2-positions of the acenaphthene core display a cis configuration. Both substituents are involved in the formation of a five-membered intra-molecular O-Hâ¯O hydrogen-bonded ring. The 4-fluoro-phenyl rings make dihedral angles of 87.02â (7) and 51.86â (8)° with the naphthalene ring system. In the crystal, a pair of non-classical C-Hâ¯O hydrogen bonds forms centrosymmetric dimeric structures. The dimeric aggregates are linked in the ac plane through non-classical C-Hâ¯F hydrogen bonds and C-Hâ¯π interactions.
RESUMO
In the title compound, C25H12Cl6O4, the two carbonyl groups are oriented in a same direction with respect to the naphthalene ring system and are situated roughly parallel to each other, while the two 2,4,6-tri-chloro-benzene rings are orientated in opposite directions with respect to the naphthalene ring system: the carbonyl C-(C=O)-C planes subtend dihedral angles of 45.54â (15) and 30.02â (15)° to the naphthalene ring system are. The dihedral angles formed by the carbonyl groups and the benzene rings show larger differences, the C=O vectors being inclined to the benzene rings by 46.39â (16) and 79.78â (16)°. An intra-molecular O-Hâ¯O=C hydrogen bond forms an S(6) ring motif. In the crystal, no effective inter-molecular hydrogen bonds are found; instead, Oâ¯Cl and Câ¯Cl close contacts are observed along the 21 helical-axis direction. The Hirshfeld surface analysis reveals several weak interactions, the major contributor being Clâ¯H/Hâ¯Cl contacts.