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Chemosphere ; 198: 68-74, 2018 May.
Artigo em Inglês | MEDLINE | ID: mdl-29421762

RESUMO

Haloacetamides (HAcAms) are nitrogenous disinfection byproducts in drinking water. The profiles of six HAcAms and their formation potentials (FPs) upon chlorination at water purification plant 1 (WPP-1) in September 2016 and at WPP-2 in September 2016 and January 2017 were investigated. HAcAms were removed effectively when they were formed via intermediate chlorination during water purification processes. Removal of total HAcAm-FPs ranged from 50% to 75%. Coagulation/flocculation/sand filtration showed the highest removal of total HAcAm-FPs. As for individual HAcAms, while chlorinated acetamide-FPs were removed, brominated acetamide-FPs, particularly 2,2-dibromoacetamide, remained. The bromine incorporation factors increased during all water purification processes except ozonation and the ozone/hydrogen peroxide process for diHAcAms (2,2-dichloroacetamide, 2-bromo-2-chloroacetamide, and 2,2-dibromoacetamide). The trends in relationships between DOM indices (fractions of dissolved organic matter, ultraviolet absorbance at 260 nm, and fluorescence intensities representing humic-like and tryptophan-like compounds) and total HAcAm-FPs during ozonation and ozone/hydrogen peroxide process were different from those during other processes.


Assuntos
Acetamidas/isolamento & purificação , Carvão Vegetal/química , Floculação , Ozônio/química , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água/métodos , Carvão Vegetal/farmacologia , Desinfecção/métodos , Filtração , Halogenação , Peróxido de Hidrogênio
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