Integrated Fenton-like and ozonation based advanced oxidation processes for treatment of real-time textile effluent containing azo reactive dyes.

The treatment of real-time textile effluent, collected from the Common Effluent Treatment Plant (CETP) of Kerala Industrial Infrastructure Development Corporation (KINFRA) at Kannur (District), Kerala (State), India, have been studied by utilizing the Fenton-like and ozone (O3) based advanced oxidation processes (AOPs). The Fenton-like AOP has been conducted as the pre-treatment of textile effluent involving the activation of persulfate (PS) and hydrogen peroxide (H2O2) as a single and the mixed oxidants by using the Flyash (FA)-Pd composite particles as the activator. The maximum chemical oxygen demand (COD) removal of 84% has been observed for a stand-alone O3 based treatment at an O3 flow rate of 5-6 g h-1. By conducting the pre-treatment of textile effluent with the PS, H2O2, and mixed oxidants (PS and H2O2) based Fenton-like AOPs, the COD removal after an O3 based post-treatment has been observed to be 83, 87, and 93% respectively at an O3 flow rate of 2, 3, and 5 g h-1. Hence, the Fenton-like pre-treatment involving the activation of mixed oxidants has been determined to be the best method for the highest COD removal of real-time textile effluent. The optimum values of initial oxidant-ratio (initial [H2O2]:initial [PS]), initial oxidant-dosage, and ozonation time, for the mixed oxidants based Fenton-like pre-treatment, have been determined to be 3 wt% mM-1, 6:2 wt% mM-1, and 60 min respectively. Under the most optimum conditions, the COD removal has been attributed to the combination of O2•- (for the pre-treatment) and •OOH (for the post-treatment) which possess relatively lower oxidation potential values.

Effects of flashing-diffuse light on [2-14C]deoxyglucose uptake in the visual system of the black-hooded rat.

What components of the visual system process diffuse light information? A [2-14C]deoxyglucose (2-DG) autoradiographic analysis revealed that exposure of freely moving rats (wearing light-diffusing masks) to flashing-diffuse light consistently elevated 2-DG uptake in the lateral geniculate nucleus and superior colliculus to levels rivalling those occurring in rats exposed to flashing-gratings. Uptake in visual cortex (area 17) in response to flashing-diffuse light, however, varied as a function of early contour experience, i.e. lower than that produced by darkness in rats reared with high contrast patterns, higher than darkness in rats which had been lid-sutured from the time of eye opening, and falling between these two extremes in 'ordinary' cage-reared rats. The findings point to subcortical mediation of discriminations based on diffuse light information. Cortex might participate in the processing of diffuse light information in the special case of animals lacking contour experience during development.