RESUMO
Supramolecular assembly of chromophores with inherent resistance to aggregation-induced self-quenching is significant to applications such as chemical sensing and organic light emitting diodes (OLEDs). In this work, molecular gels with aggregation-induced emission (AIE) are constructed by simply coassembling AIE chromophores (electron donor or acceptor) with a nonfluorescent molecular gelator. The binary gels are fluorescent even at very low concentrations of the AIE chromophores, indicating that the rotation of their aromatic cores is restricted in the gel network. In tertiary gels, the fluorescence of the donor chromophore can be efficiently reduced by the acceptor chromophore through a combination of static and dynamic quenching process, via charge transfer from the donor to the acceptor. This work demonstrates a convenient approach to fabricate a supramolecular charge transfer system using an AIE donor and acceptor.
Assuntos
Materiais Biomiméticos/química , Aminopiridinas/química , Ciclopentanos/química , Dimetil Sulfóxido/química , Géis/química , Microscopia Confocal , Microscopia Eletrônica de Varredura , Ácidos Pentanoicos/química , Teoria Quântica , Espectrofotometria , Estilbenos/química , Temperatura , Raios Ultravioleta , Difração de Raios XRESUMO
We demonstrate an all-optical strategy for realizing spherical three-dimensional (3D) super-resolution (â¼λ3/22) spot arrays of pure longitudinal magnetization by exploiting a 4π optical microscopic setup with two high numerical aperture (NA) objective lenses, which focus and interfere two modulated vectorial beams. Multiple phase filters (MPFs) are designed via an analytical approach derived from the vectorial Debye diffraction theory to modulate the two circularly polarized beams. The system is tailored to constructively interfere the longitudinal magnetization components, while simultaneously destructively interfering the azimuthal ones. As a result, the magnetization field is not only purely longitudinal but also super-resolved in all three dimensions. Furthermore, the MPFs can be designed analytically to control the number and locations of the super-resolved magnetization spots to produce both uniform and nonuniform arrays in a 3D volume. Thus, an all-optical control of all the properties of light-induced magnetization spot arrays has been demonstrated for the first time. These results open up broad applications in magnetic-optical devices such as confocal and multifocal magnetic resonance microscopy, 3D ultrahigh-density magneto-optic memory, and light-induced magneto-lithography.
RESUMO
Spontaneous emission lifetime distribution in the basic unit cell or on a plane of the excited emitters embedded in woodpile photonics crystals with low refractive index contrast are investigated. It is found that the spontaneous emission lifetime distribution strongly depends on the position and transition frequency of the emitters, and has the same symmetry as that of the unit cell. The lifetimes of emitters near the upper gap edge are longer than that in the center of the pseudo-gap, which is quite a contrast to the conventional concept. Furthermore, it is revealed that the polarization orientation of the emitters has significant influence on the lifetime distribution, and may result in a high anisotropy factor (defined as the difference between the maximum and minimum values of the lifetime) up to 4.2. These results may be supplied in probing the lifetime distribution or orientation-dependent local density of states in future experiments.