Hydrogen cyanide production due to mid-size impacts in a redox-neutral N2-rich atmosphere.

Cyanide compounds are amongst the most important molecules of the origin of life. Here, we demonstrate the importance of mid-size (0.1-1 km in diameter) hence frequent meteoritic impacts to the cyanide inventory on the early Earth. Subsequent aerodynamic ablation and chemical reactions with the ambient atmosphere after oblique impacts were investigated by both impact and laser experiments. A polycarbonate projectile and graphite were used as laboratory analogs of meteoritic organic matter. Spectroscopic observations of impact-generated ablation vapors show that laser irradiation to graphite within an N2-rich gas can produce a thermodynamic environment similar to that produced by oblique impacts. Thus, laser ablation was used to investigate the final chemical products after this aerodynamic process. We found that a significant fraction (>0.1 mol%) of the vaporized carbon is converted to HCN and cyanide condensates, even when the ambient gas contains as much as a few hundred mbar of CO2. As such, the column density of cyanides after carbon-rich meteoritic impacts with diameters of 600 m would reach ~10 mol/m(2) over ~10(2) km(2) under early Earth conditions. Such a temporally and spatially concentrated supply of cyanides may have played an important role in the origin of life.

Three-dimensional structure of Hayabusa samples: origin and evolution of Itokawa regolith.

Regolith particles on the asteroid Itokawa were recovered by the Hayabusa mission. Their three-dimensional (3D) structure and other properties, revealed by x-ray microtomography, provide information on regolith formation. Modal abundances of minerals, bulk density (3.4 grams per cubic centimeter), and the 3D textures indicate that the particles represent a mixture of equilibrated and less-equilibrated LL chondrite materials. Evidence for melting was not seen on any of the particles. Some particles have rounded edges. Overall, the particles' size and shape are different from those seen in particles from the lunar regolith. These features suggest that meteoroid impacts on the asteroid surface primarily form much of the regolith particle, and that seismic-induced grain motion in the smooth terrain abrades them over time.

Fragment velocity distribution in the impact disruption of thin glass plates.

We present the experimental results of the measurement of fragment velocity in an impact disruption. Cylindrical projectiles impact on a side (edge) of thin glass plates, and the dispersed fragments were observed using a high-speed camera. The fragment velocity did not depend on the mass but rather on the initial position of the fragment; the velocity component parallel to the projectile direction increased with the distance from the impacted side, while the component perpendicular to the projectile direction increased with the distance from the central axis parallel to the projectile direction. It appears that there are two mechanisms for fragment ejection: one is "spallation," where the fragment velocities depend on the particle velocity induced by shock waves, and the other is "elastic ejection," where the velocities are controlled by the strain energy stored in targets and are at most a few tens of meters per second. We performed a one-dimensional numerical simulation of elastic ejection with a discrete element method and obtained the velocity distribution as a function of the initial position. The numerical results are qualitatively consistent with the experimental ones.

Crack propagation in thin glass plates caused by high velocity impact.

Crack propagation within thin glass plates under high shock loading is directly observed using a high speed camera. The fractal dimension of cracks and the power-law exponents of the fragment area distributions are investigated as a function of time. Two models of the fragmentation process are proposed: in one case the cracks are net-like, while in the other the cracks are tree-like, and the relations between fractal dimension and power-law exponent are estimated and compared with the experimental results. It appears that at early stages of the fragmentation process the relation is described by the latter case, while at later stages it approaches that of the former case.