RESUMO
Nanoparticles (NPs) are materials considered to be 1-100 nm in size and are available in different dimensional shapes, geometrical sizes, physical morphologies, mechanical robustness, and chemical compositions. Irrespective of the dimensions (i.e., zero-dimensional (0D), one-dimensional (1D), and two-dimensional (2D)), NPs have a tendency to become entangled together, forming aggregations due to high attraction, making it hard to realize their full potential from their ordered counterparts. Many challenges exist to attain high-quality stabilized dispersion and long-range ordered assembly of NPs. Three-dimensional printing (3DP), also known as additive manufacturing (AM), is a technique dependent on layer-by-layer material addition for building 3D structures and encompasses a few categories based on the feedstock material types and printing mechanisms. One benefit from the 3DP procedures is their capability to produce anisotropic microstructural/nanostructural characteristics for desired mechanical reinforcement, transport phenomena, energy management, and biomedical implants. This paper briefly overviews relevant 3DP methods with an embedded nature to assemble nanoparticles without interference with external fields (e.g., magnetic or electrical). Our focus is the shear-field-induced nanoparticle alignment, covering material jetting-, electrohydrodynamic-, filament melting-, and ink writing-based 3DP. A concise summary of photopolymerization and its "optical tweezer" effects on nanoparticle confinement also inspires creative approaches in generating ordered nanostructures. The nanoparticles and polymers involved in this review are diverse, consisting of metallic, ceramic, and carbon nanoparticles in matrices or on surfaces of varying macromolecules. A short statement of challenges (e.g., low resolution, slow printing speed, limited material options) for 3DP-enabled nanoparticle orders provides some perspectives toward the enormous potential of 3DP in directing NPs assembly and fabricating high-performance polymer/nanoparticle composites.
RESUMO
3D printing (additive manufacturing (AM)) has enormous potential for rapid tooling and mass production due to its design flexibility and significant reduction of the timeline from design to manufacturing. The current state-of-the-art in 3D printing focuses on material manufacturability and engineering applications. However, there still exists the bottleneck of low printing resolution and processing rates, especially when nanomaterials need tailorable orders at different scales. An interesting phenomenon is the preferential alignment of nanoparticles that enhance material properties. Therefore, this review emphasizes the landscape of nanoparticle alignment in the context of 3D printing. Herein, a brief overview of 3D printing is provided, followed by a comprehensive summary of the 3D printing-enabled nanoparticle alignment in well-established and in-house customized 3D printing mechanisms that can lead to selective deposition and preferential orientation of nanoparticles. Subsequently, it is listed that typical applications that utilized the properties of ordered nanoparticles (e.g., structural composites, heat conductors, chemo-resistive sensors, engineered surfaces, tissue scaffolds, and actuators based on structural and functional property improvement). This review's emphasis is on the particle alignment methodology and the performance of composites incorporating aligned nanoparticles. In the end, significant limitations of current 3D printing techniques are identified together with future perspectives.