1.
Org Lett
; 15(2): 306-9, 2013 Jan 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23268700
RESUMO
Two new expanded calix[4]pyrroles 3 and 4 were synthesized by '2 + 2' cyclocoupling of easily prepared diboryldipyrromethane 7 (by Ir-catalyzed CH-bond activation) with appropriate diiodoarenes using the Suzuki protocol. Owing to the unique design, both macrocycles exhibited extended π-conjugation and enhanced fluorescence. Upon complexation with anions (fluoride and acetate), receptor 3 displayed turn-on sensing of fluorescence, whereas 4 showed turn-off sensing.