RESUMO
This study is a first attempt to assess the trace element contamination status in the surface sediments of the Hellenic Seas since the first environmental studies in the country commenced in the mid-1970s. All available trace element data from the last 20 years have been collected and assessed using sediment quality guidelines and application of single- and multielement pollution indices. Although Hellenic marine sediments initially appear as anthropogenically enriched in Cr and As, this enrichment is attributed to the natural background. Central Greece appears more polluted, followed by Northern Greece and lastly Southern Greece. The element pollution indices featured the influence of industrial activities such as mining, steel industry and chemical factories, shipyards, and secondarily the influence of port activities.
Assuntos
Metais Pesados , Oligoelementos , Poluentes Químicos da Água , Monitoramento Ambiental , Sedimentos Geológicos , Grécia , Metais Pesados/análise , Oligoelementos/análise , Poluentes Químicos da Água/análiseRESUMO
Heavy metal contamination of the aquatic environment is of worldwide concern, due to the toxicity of metals and their lethal effects on aquatic organisms. The investigation of heavy metal concentrations in freshwater bodies has increased over the last decades in Greece; however, most studies have been sporadic and spatially limited. An overall assessment of the heavy metal contamination status in Greek surface water bodies is lacking. In this review, all available published data from 1999 to 2019 were collected and analysed to assess the heavy metal contamination status of the surface water bodies of Greece. Data were available for 68 water bodies and several pollution indices (e.g. Heavy Metal Pollution index, Geoaccumulation index, Moderated Pollution Index) were calculated to evaluate their surface water quality. Overall, heavy metal concentrations in water samples were below the Environmental Quality Standards (EQS) and the vast majority of water bodies were classified as good quality based on surface water pollution indices. Sediment heavy metal concentrations exceeding the Sediment Quality Guidelines (SQGs) were detected in most water bodies. Rivers Axios, Evros, Louros, Gallikos, Greveniotikos, Palea Kavala, Kompsatos, Alfeios and Evrotas, and lakes Pamvotis, Doirani and Koumoundourou were either moderately or highly contaminated. Up to date, heavy metal pollution indices used worldwide for surface waters refer to potable water. Thus, pollution indices must be developed for assessing primarily the ecological consequences of heavy metal pollution and surface water pollution status. Finally, sediment pollution guidelines must be suggested at a European or regional level.
Assuntos
Metais Pesados , Poluentes Químicos da Água , Monitoramento Ambiental , Sedimentos Geológicos , Grécia , Metais Pesados/análise , Medição de Risco , Rios , Poluentes Químicos da Água/análiseRESUMO
The potential influence of short-period (May-June 2012) dredging activities (for the installation of a submarine gas pipeline) on physical properties of the marine environment of two shallow-water sites in the Aliveri and Varnavas areas of South Euboean Gulf (Greece) has been evaluated. During the dredging operation in Varnavas, the induced dredge plume traveled up to ~ 750 m from the shoreline, featured by light attenuation coefficient (cp) maxima of 4.01-4.61 m-1 and suspended particulate matter (SPM) concentrations up to 6.01 mg L-1. After dredging the previous parameters reduced to the ambient seawater condition, ~ 0.45 m-1 and < 2.8 mg L-1 on average, respectively. Likewise in Aliveri, the dredging-associated sediment plume drifted offshore up to ~ 400 m from the shoreline, characterized by cp maxima of 2.11-4.86 m-1 and SPM concentrations up to 13.07 mg L-1. After the completion of the excavation and trenching activities, the cp and SPM values were restored to the pre-disturbance condition, ~ 0.6 m-1 and < 2.2 mg L-1 on average, respectively. The migration of the dredge plume in both dredging sites was accomplished through the formation of intermediate and benthic nepheloid layers, whose development and evolution were governed by seawater stratification and flow regime. The dredging-derived SPM levels appeared to increase within a distance of no more than 300 m from the shoreline (near-field zone). Based on data from the literature, this SPM enhancement together with the deposition of a post-dredging residual mud veneer in the near-field zone could deteriorate local marine biota, but in a reversible way.
Assuntos
Monitoramento Ambiental , Sedimentos Geológicos/química , Material Particulado/análise , Água do Mar/química , Grécia , Mar Mediterrâneo , Indústria de Petróleo e Gás/normas , Navios , Tempo , Poluentes Químicos da Água/análiseRESUMO
A multi-criteria approach was applied for the disposal into the sea of â¼1,100,000 m(3) of sediment, dredged from a coastal area in the northeastern part of the Thermaikos Gulf. This sediment (classified as muddy) is distributed vertically into two distinct Layers (A and B) with the thickness of the surficial sedimentary unit ranging from 7 to 54 cm. Its geochemistry reveals increased Cr and Ni concentrations, which may be attributed to natural enrichment through the erosion of the adjacent igneous and metamorphic rocks. In addition, a low to moderate contamination from urban-originated heavy metals, like Cu, Pb and Zn as well as from aliphatic and polycyclic hydrocarbons was identified for the upper Layer A. However, the limited proportion (5.5%) of the polluted Layer A in the total volume of the dredged material could not affect the good quality (assessed by the Sediment Quality Guidelines) of the bulk sediment. The identification of the optimum marine dumping site was based on (a) the physicochemical similarity (detected by the application of a cluster analysis) of the dredged material with the surficial deposits of potential dumping sites in the Outer Thermaikos Gulf, and (b) the consideration, based on previous studies, of various criteria related to the disposal area such as deep-water circulation, influence on living resources, impact on economical (aquaculture, fishing, navigation), recreational (fishing) and military activities.
Assuntos
Sedimentos Geológicos/química , Substâncias Perigosas/análise , Eliminação de Resíduos , Animais , Organismos Aquáticos , Análise por Conglomerados , Técnicas de Apoio para a Decisão , Grécia , Atividades Humanas , Humanos , Hidrocarbonetos/análise , Mar Mediterrâneo , Oceanografia , Oligoelementos/análiseRESUMO
Measurement of the response of acute bronchiolitis (AB) to bronchodilators relies on clinical signs and pulse oximetry. We hypothesized that Doppler ultrasonographic indices of hepatic venous flow may prove to be an objective tool in the assessment of the effect of inhaled salbutamol in infants hospitalized for AB. Previously healthy infants hospitalized for their first episode of AB were prospectively studied. Composite clinical score (CCS, retractions plus wheezing/crackles) and hemoglobin oxygen saturation (SaO(2)) were measured before, and 15-min post-salbutamol nebulization (0.15 mg/kg, minimum 1.5 mg). Peak velocities at the middle hepatic vein (PV-HV) and right renal vein (PV-RV), as well as peripheral-to-middle hepatic vein transit time (TT) of an ultrasound contrast agent were also measured by Doppler ultrasonography pre- and post-nebulization. Nineteen infants were studied. Mean CCS decreased by 0.37 (95% confidence interval [CI]: 0.08-0.66, P = 0.015) and mean SaO(2) increased by 0.68% (95%CI: 0.17-1.19, P = 0.01) post-bronchodilator treatment. Mean TT increased by 9.54 sec (95%CI: 5.95-13.13, P < 0.0001) and PV-HV increased by 16.49 cm/sec (95%CI: 9.07-23.91, P = 0.0002); PV-RV did not change. TT (r = 0.51, P = 0.009), but not PV-HV, correlated negatively with CCS. There was a strong positive correlation between pre- and post-salbutamol TT values (r = 0.92, P < 0.0001). The most likely explanation for these findings is post-salbutamol abolishment of shunting at the pulmonary capillary bed. We conclude that the peripheral-to-middle hepatic vein prolongation of TT measured by Doppler ultrasonography after salbutamol administration in infants with AB can be used as a bedside tool in the objective assessment of clinical response to medication in these patients.