Chemical Composition, Sources, and Health Risk Assessment of PM2.5 and PM10 in Urban Sites of Bangkok, Thailand.

Of late, air pollution in Asia has increased, particularly in built-up areas due to rapid industrialization and urbanization. The present study sets out to examine the impact that pollution can have on the health of people living in the inner city of Bangkok, Thailand. Consequently, in 2021, fine particulate matter (PM2.5) and coarse particulate matter (PM10) chemical composition and sources are evaluated at three locations in Bangkok. To identify the possible sources of such particulates, therefore, the principal component analysis (PCA) technique is duly carried out. As determined via PCA, the major sources of air pollution in Bangkok are local emission sources and sea salt. The most significant local sources of PM2.5 and PM10 in Bangkok include primary combustion, such as vehicle emissions, coal combustion, biomass burning, secondary aerosol formation, industrial emissions, and dust sources. Except for the hazard quotient (HQ) of Ni and Mn of PM2.5 for adults, the HQ values of As, Cd, Cr, Mn, and Ni of both PM2.5 and PM10 were below the safe level (HQ = 1) for adults and children. This indicates that exposure to these metals would have non-carcinogenic health effects. Except for the carcinogenic risk (HI) value of Cr of PM2.5 and PM10, which can cause cancer in adults, at Bangna and Din Daeng, the HI values of Cd, Ni, As, and Pb of PM2.5 and PM10 are below the limit set by the U.S. Environmental Protection Agency (U.S. EPA). Ni and Mn pose non-carcinogenic risks, whereas Cr poses carcinogenic risks to adults via inhalation, a serious threat to the residents of Bangkok.

Structure, dissolution, and plant uptake of ferrous/zinc phosphates.

Development of slow release fertilizers by tuning dissolution kinetics can reduce the environmental impact of (micro) nutrients added to crops. Mixed metal compounds may have different dissolution kinetics and plant uptake than single metal compounds. In this study, mixed Fe(II)/Zn(II) phosphates (0-100 at% Zn) were prepared by aqueous precipitation and their structural characteristics and dissolution kinetics in a sand column were measured as model for divalent metal and phosphate release in soil. Three minerals were identified, namely vivianite (Fe3(PO4)2·8H2O) at 0-20 at% Zn, phosphophyllite (Zn2Fe(PO4)2·4H2O) at 20-79 at% Zn, and hopeite (Zn3(PO4)2·4H2O) at 79-100 at% Zn. The Fe-rich materials had high SSA of 42-64 m2 g-1, which decreased to ≤4 m2 g-1 for ≥79 at% Zn. The Fe K-edge and Zn K-edge XANES spectroscopy measurements show that the samples had comparable local structure and contained 13-72% of Fe as Fe(III) due to partial oxidation. In the sand column, Zn(II) and Fe(II) phosphates dissolved near-congruently at steady state (>7 h), whereas mixed Fe(II)/Zn(II) phosphates showed preferential release of Zn over P and Fe, likely due to reprecipitation of Fe. Pot experiments demonstrate that Zn from Fe(II)/Zn(II) phosphates is absorbed by bird's eye chili plants (C. annuum), in agreement with the preferential dissolution of Zn(II). These results may provide insight into the dissolution of other divalent metals, which not only aids in the growth of plants and resulting foodstuff but ultimately leads to reductions in environmental contamination.

Effect of a pH-controlled co-precipitation process on rhodamine B adsorption of MnFe2O4 nanoparticles.

We investigated the effect of a pH-controlled co-precipitation process on the adsorption behavior of manganese ferrite (MnFe2O4) nanoparticles as well as their structural and magnetic properties. The pH of prepared MnFe2O4 nanoparticles is typically an important factor affecting the adsorption capacity of an adsorbent. In this study, MnFe2O4 nanoparticles were prepared using a co-precipitation method at four different pH values of 9.0, 9.5, 10.0, and 10.5. The adsorption behaviors on rhodamine B (RhB) by MnFe2O4 nanoparticles prepared at different pH values were investigated. It was found that, via a pH-controlled process, MnFe2O4 nanoparticles prepared at pH 10.5 showed the highest RhB removal efficiency. The results indicated that the large pore size and surface charge of MnFe2O4 nanoparticles improved the adsorption capacities for RhB. Kinetic data were fitted to a pseudo-second order kinetic model and revealed that equilibrium was reached within 60 min. The isotherm data showed that the Langmuir maximum adsorption capacity of the MnFe2O4 nanoparticles prepared at pH 10.5 for RhB was 9.30 mg g-1.

Composite Photocatalysts Containing BiVO4 for Degradation of Cationic Dyes.

The creation of composite structures is a commonly employed approach towards enhanced photocatalytic performance, with one of the key rationales for doing this being to separate photoexcited charges, affording them longer lifetimes in which to react with adsorbed species. Here we examine three composite photocatalysts using either WO3, TiO2 or CeO2 with BiVO4 for the degradation of model dyes Methylene Blue and Rhodamine B. Each of these materials (WO3, TiO2 or CeO2) has a different band edge energy offset with respect to BiVO4, allowing for a systematic comparison of these different arrangements. It is seen that while these offsets can afford beneficial charge transfer (CT) processes, they can also result in the deactivation of certain reactions. We also observed the importance of localized dye concentrations, resulting from a strong affinity between it and the surface, in attaining high overall photocatalytic performance, a factor not often acknowledged. It is hoped in the future that these observations will assist in the judicious selection of semiconductors for use as composite photocatalysts.

Enhancement of Cr(VI) Ion Removal Using Nanochitosan Coated on Bituminous Activated Carbon.

Bituminous activated carbon (AC) has been widely used as a sorbent for adsorption of non-polar species, but its performance for removal of ionic species such as heavy metals has not been as efficient. In this study, AC was modified with chitosan nanoparticles (CN) using facile methods of dip coating and wet impregnation. The CN-coated AC demonstrated an increase in Cr(VI) removal efficiency in both kinetics and adsorption capacity. The adsorption capacity of the CN-coated AC (mg/g) was more than twice that of the uncoated AC (36.36 mg/g), or pure chitosan (32.57 mg/g). The sizes of the synthesized CN (160-2,000 nm) can be controlled by varying the concentration of the chitosan/reagents used. The adsorption isotherms are better described using the Freundlich rather than the Langmuir model and are in agreement with the heterogeneity of the surfaces. Adsorption kinetics followed that of the pseudo-second-order kinetics, suggesting chemisorption as a rate limiting step.

Determination of silver nanoparticle release from antibacterial fabrics into artificial sweat.

Silver nanoparticles have been used in numerous commercial products, including textiles, to prevent bacterial growth. Meanwhile, there is increasing concern that exposure to these nanoparticles may cause potential adverse effects on humans as well as the environment. This study determined the quantity of silver released from commercially claimed nanosilver and laboratory-prepared silver coated fabrics into various formulations of artificial sweat, each made according to AATCC, ISO and EN standards. For each fabric sample, the initial amount of silver and the antibacterial properties against the model Gram-positive (S. aureus) and Gram-negative (E. coli) bacteria on each fabric was investigated. The results showed that silver was not detected in some commercial fabrics. Furthermore, antibacterial properties of the fabrics varied, ranging from 0% to greater than 99%. After incubation of the fabrics in artificial sweat, silver was released from the different fabrics to varying extents, ranging from 0 mg/kg to about 322 mg/kg of fabric weight. The quantity of silver released from the different fabrics was likely to be dependent on the amount of silver coating, the fabric quality and the artificial sweat formulations including its pH. This study is the unprecedented report on the release of silver nanoparticles from antibacterial fabrics into artificial sweat. This information might be useful to evaluate the potential human risk associated with the use of textiles containing silver nanoparticles.

Antibacterial effect of apatite-coated titanium dioxide for textiles applications.

An antibacterial activity of apatite-coated titanium dioxide (TiO2) against four types of bacteria (Staphylococcus aureus, Escherichia coli, methicillin-resistant Staphylococcus aureus (MRSA), and Micrococcus luteus) was investigated. Its antibacterial performance was observed under black light, visible light, and dark conditions. The number of viable bacteria decreased with irradiation time and became most prominent at 24 hours. Distortion of bacterial cells by the nanoparticles was demonstrated by scanning electron microscopy. Apatite-coated TiO2 was fixed on cotton textiles by dip-coat technique, and the antimicrobial properties of corresponding fabrics were then investigated. The effect of irradiation source on antimicrobial activity of coated cotton fabrics was examined, wherein black-light irradiation demonstrated higher antibacterial activity than either visible-light irradiation or dark conditions. Microbial populations of coated cotton fabrics decreased with increasing irradiation intensity. Coated cotton fabrics have been shown to be nontoxic to human dermal fibroblasts. Our findings suggest that the presence of apatite-coated TiO2 shows antibacterial activity in the presence of black light or visible light, suggesting its potential use in reducing the risk of microorganism transmission for textile applications.