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We consider the diffusion of brownian particles in one-dimensional periodic potentials as a test bench for the recently proposed stochastic path integral hyperdynamics (PIHD) scheme [Chen and Horing, J. Chem. Phys. 126, 224103 (2007)]. First, we consider the case where PIHD is used to enhance the transition rate of activated rare events. To this end, we study the diffusion of a single brownian particle moving in a spatially periodic potential in the high-friction limit at low temperature. We demonstrate that the boost factor as compared to straight molecular dynamics (MD) has nontrivial behavior as a function of the bias force. Instead of growing monotonically with the bias, the boost attains an optimal maximum value due to increased error in the finite path sampling induced by the bias. We also observe that the PIHD method can be sensitive to the choice of numerical integration algorithm. As the second case, we consider parallel resampling of multiple bias force values in the case of a brownian particle in a periodic potential subject to an external ac driving force. We confirm that there is no stochastic resonance in this system. However, while the PIHD method allows one to obtain data for multiple values of the ac bias, the boost with respect to MD remains modest due to the simplicity of the equation of motion in this case.
Assuntos
Difusão , Modelos Teóricos , Fricção , Processos Estocásticos , TemperaturaRESUMO
Water droplets can jump during vapor condensation on solid benzene near its melting point. This phenomenon, which can be viewed as a kind of micro scale steam engine, is studied experimentally and numerically. The latent heat of condensation transferred at the drop three phase contact line melts the substrate during a time proportional to R (the drop radius). The wetting conditions change and a spontaneous jump of the drop results in random direction over length approximately 1.5R , a phenomenon that increases the coalescence events and accelerates the growth. Once properly rescaled by the jump length scale, the growth dynamics is, however, similar to that on a solid surface.
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Random sequential adsorption of mixed convex plus concave contour (MC) objects exhibits some distinctly different peculiar characteristics than the cases of purely convex objects. Though the substrate coverage approaches the jamming limit with time t as t;{-p} , same as that for convex objects, the law p approximately 1d_{f} , valid for convex objects with d_{f} degrees of freedom, does not hold for MC objects. Interestingly, for a fixed number of degrees of freedom, the exponent p changes with the degree of nonconvexity and bears a near perfect correlation with the same.
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Random sequential adsorption (RSA), on a two-dimensional continuum substrate, of different types of zero area objects that disallow domain formation and hence lead to jamming, is examined by simulation. In all the cases, in the asymptotic time regime, the approach of the number density rho(t) at instant t to jamming density rho(infinity) is found to exhibit power law rho(infinity)-rho(t) approximately t{-p} as that for RSA of finite area objects. These results suggest the possibility of the power law being universal for all jamming systems in RSA on a continuum substrate. A generalized analytical treatment is also proposed.
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Dynamic scaling behavior of the droplet size distribution in the coalescence regime for growth by pulsed laser deposition is studied experimentally and by computer simulation, and the same is compared with that for continuous vapor deposition. The scaling exponent for pulsed deposition is found to be (1.2 +/- 0.1), which is significantly lower as compared to that for continuous deposition (1.6 +/- 0.1). Simulations reveal that this dramatic difference can be traced to the large fraction of multiple droplet coalescence under pulsed vapor delivery. A possible role of the differing diffusion fields in the two cases is also suggested.