Fabrication of Multifunctional Tents Using Canvas Fabric.

Herein, this study was compiled to investigate a suitable solution for the fabrication and development of the multifunctional defense tent from previously reported research. The military always needs to protect their soldiers and equipment from detection. The advancement of infrared detection technology emphasizes the significance of infrared camouflage materials, reducing thermal emissions for various applications. Objects emit infrared radiation detectable by devices, making military targets easily identifiable. Infrared camouflage mitigates detection by lowering an object's infrared radiation, achieved by methods such as reducing surface temperature, which is crucial in designing military tents with infrared (IR) camouflage, considering water repellency and antibacterial features. Water repellency, as well as antimicrobial properties, in army tents is also important as they have to survive in different situations. All these problems should be addressed with the required properties; therefore, the authors try to introduce a new method from which multifunctional tents can be produced through economical, multifunctional, and sustainable materials that have IR protection, water repellency, ultraviolet (UV) protection, air filtration and permeability, and antimicrobial properties. There is still no tent that performs multiple functions at a time, even those functions that do not correlate with each other such as water repellency, IR protection, antimicrobial, and air permeability. So, a multifunctional tent could be the solution to all these problems having all the properties discussed above. In this study based on the literature review, authors concluded a method for the required tent for canvas fabric coated with zinc sulfide (ZnS), graphene oxide (GO), and zinc oxide (ZnO), or these materials should be incorporated in fiber formation because fiber composition has more impact. These multifunctional tents will be very beneficial due to their multifunctions like weather resistance, durability, and long life. These would help the army in their missions by concealing their soldiers and equipment from detection by cameras and providing filtered air inside the tent in case of gases or explosions. The proposed method will help to fulfill the stated and implied needs of customers.

Sustainable bioactive food packaging based on electrospun zein-polycaprolactone nanofibers integrated with aster yomena extract loaded halloysite nanotubes.

Compostable zein-polycaprolactone (PZ) electrospun nanofiber integrated with different concentrations of Aster yomena extract loaded halloysite nanotubes (A. yomena-HNT) as bioactive nanofibrous food packaging is reported. SEM micrographs reveal heterogeneous nanofibers. A. yomena extract used in the study showed weak antioxidant activity with AAI and TEAC values of 0.229 and 0.346. In vitro, release profile over 7 days of A. yomena indicates a controlled, sustained, and prolonged release. The prepared nanofibers were effective against both gram-positive and gram-negative bacteria. The prepared composite nanofibers were rendered biocompatible and nontoxic when subjected to WST-1 and LDH assay after incubating with NIH 3T3 mouse fibroblast cell line. PZ-15 nanofiber packaging showed the best postharvest quality preservation in Black mulberry fruits after 4 days of storage at 25 °C and 85 % Rh. Moreover, the in vitro decomposition test reveals that the fabricated nanofibers decompose in the soil and do not pose as a threat to the environment.

Eggshell membrane as a novel and green platform for the preparation of highly efficient and reversible curcumin-based colorimetric sensor for the monitoring of chicken freshness.

Herein, for the very first time, we report a paper-like biomass, eggshell membrane (ESM), as a suitable platform for the fabrication of a colorimetric sensor (E-Cot). Green ethanolic extract, curcumin (CUR), was used as a sensing material to coat with the ESM. The present E-Cot effectively changed its color (yellow to red) in the real-time monitoring for chicken spoilage. The E-Cot exhibits barrier properties due to its inherent semi-permeability characteristics. Interestingly, the E-Cot showed a significant change in total color difference value (ΔE, 0 days - 0.0-39.6, after 1 day - 39.6-42.1, after 2 days - 42.1-53.6, after 3 days- 53.6-60.1, and after 4 days - 60.1-66.3, detectable by the naked eye) in the real-time monitoring for chicken freshness. In addition, the present E-Cot smart colorimetric sensor is reversible with a change in pH, and the sensor can be reused. Further, the hydrophobic nature of the E-Cot was confirmed by water contact angle analysis (WCA, contact angle of 101.21 ± 8.39). Good antibacterial, barrier, and optical properties of the present E-Cot were also found. Owing to the advantages such as green, efficient, cost-effective, biodegradable, reusable, sustainable, and simple preparation, we believe that the present E-Cot would be a more attractive candidate.

"Micro-to-nano": Reengineering of jute for constructing cellulose nanofibers as a next-generation biomaterial.

Micro-to-nano transformation can make a material unique. This research uses jute microfiber to extract Holo and Alpha forms of cellulose, which are later attempted to electrospun into superfine nanofibers (NFs). Initial investigation of morphological, physicochemical, crystallographic, and thermal properties confirmed successful synthesis of Holo and Alpha-cellulose (H/A-cellulose). Afterwards, the electrospinnable concentration of H/A-cellulose was optimized and their bead-free ultrafine NFs in the range of 109-145 nm were fabricated. FTIR analysis confirmed the source composition in Holo and Alpha CNF with the partial formation of trifluoroacetyl esters. Alpha CNF exhibited better structural integrity despite the crystallinity and thermal stability deteriorated in both Holo and Alpha CNF. Both Holo and Alpha CNF exhibited adequate mechanical performance and liquid uptake properties. Alpha CNF showed better morphological stability in organic solvents and slower biodegradation than Holo CNF. Subsequent investigation revealed that both Holo and Alpha CNF didn't exhibit cytotoxic effects on COS-7 cells and above 90 % of cells were viable in contact with both CNF. Significant proliferation and attachment of COS-7 cells were noticed within 7 days of incubation with the prepared CNF. Our findings revealed that jute-extracted cellulose can be a viable and potential source for constructing cellulose-based advanced nano-biomaterials.

Fast Energy Storage of SnS2 Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium-Ion Batteries.

The development of conversion-typed anodes with ultrafast charging and large energy storage is quite challenging due to the sluggish ions/electrons transfer kinetics in bulk materials and fracture of the active materials. Herein, the design of porous carbon nanofibers/SnS2 composite (SnS2 @N-HPCNFs) for high-rate energy storage, where the ultrathin SnS2 nanosheets are nanoconfined in N-doped carbon nanofibers with tunable void spaces, is reported. The highly interconnected carbon nanofibers in three-dimensional (3D) architecture provide a fast electron transfer pathway and alleviate the volume expansion of SnS2 , while their hierarchical porous structure facilitates rapid ion diffusion. Specifically, the anode delivers a remarkable specific capacity of 1935.50 mAh g-1 at 0.1 C and excellent rate capability up to 30 C with a specific capacity of 289.60 mAh g-1 . Meanwhile, at a high rate of 20 C, the electrode displays a high capacity retention of 84% after 3000 cycles and a long cycle life of 10 000 cycles. This work provides a deep insight into the construction of electrodes with high ionic/electronic conductivity for fast-charging energy storage devices.

Electrospun composite nanofibers of deoxyribonucleic acid and polylactic acid for skincare applications.

The development of useful biomaterials has resulted in significant advances in various fields of science and technology. The demand for new biomaterial designs and manufacturing techniques continues to grow, with the goal of building a sustainable society. In this study, two types of DNA-cationic surfactant complexes were synthesized using commercially available deoxyribonucleic acid from herring sperm DNA (hsDNA, <50 bp) and deoxyribonucleic acid from salmon testes DNA (stDNA, ~2000 bp). The DNA-surfactant complexes were blended with a polylactic acid (PLA) biopolymer and electrospun to obtain nanofibers, and then copper nanoparticles were synthesized on nanofibrous webs. Scanning electron microscopic images showed that all nanofibers possessed uniform morphology. Interestingly, different diameters were observed depending on the base pairs in the DNA complex. Transmission electron microscopy showed uniform growth of copper nanoparticles on the nanofibers. Fourier-transform infrared spectroscopy spectra confirmed the uniform blending of both types of DNA complexes in PLA. Both stDNA- and hsDNA-derived nanofibers showed greater biocompatibility than native PLA nanofibers. Furthermore, they exerted significant antibacterial activity in the presence of copper nanoparticles. This study demonstrates that DNA is a potentially useful material to generate electrospun nanofibrous webs for use in biomedical sciences and technologies.

A Review on Electrospun Nanofiber Composites for an Efficient Electrochemical Sensor Applications.

The present review article discusses the elementary concepts of the sensor mechanism and various types of materials used for sensor applications. The electrospinning method is the most comfortable method to prepare the device-like structure by means of forming from the fiber structure. Though there are various materials available for sensors, the important factor is to incorporate the functional group on the surface of the materials. The post-modification sanction enhances the efficiency of the sensor materials. This article also describes the various types of materials applied to chemical and biosensor applications. The chemical sensor parts include acetone, ethanol, ammonia, and CO2, H2O2, and NO2 molecules; meanwhile, the biosensor takes on glucose, uric acid, and cholesterol molecules. The above materials have to be sensed for a healthier lifestyle for humans and other living organisms. The prescribed review articles give a detailed report on the Electrospun materials for sensor applications.

The Effect of Polymeric Nanofibers Used for 3D-Printed Scaffolds on Cellular Activity in Tissue Engineering: A Review.

Promising scaffolds for developing advanced tissue engineering architectures have emerged in recent years through the use of nanofibers and 3D printing technologies. Despite this, structural integrity and cell proliferation are highlighted as fundamental challenges for design scaffolds and future prospects. As a biomimetic scaffold, the nanofiber-reinforced hydrogels demonstrated a better compressive modulus and cell growth. Our review focuses on recent promising advances in the development of 3D-printed hydrogels containing polymeric nanofibers that can improve cell-material interaction in biomedical applications. Moreover, an effort has been made to induce studies with diverse types of scaffolds for various cells. Additionally, we discuss the challenges and future prospects of 3D-bioprinted reinforced hydrogels with nanofibers in the medical field, as well as high-performance bioinks.

Fabrication of Electrospun PVA/Zein/Gelatin Based Active Packaging for Quality Maintenance of Different Food Items.

In this research, electrospun PVA/Zein/Gelatin based tri-component active food packaging has been fabricated to enhance the shelf life of food by assuring the food quality (freshness, taste, brittleness, color, etc.) for longer. Electrospinning imparts good morphological properties along with breathability in nanofibrous mats. Electrospun active food packaging has been characterized to investigate the morphological, thermal, mechanical, chemical, antibacterial and antioxidant properties. Results of all tests indicated that the PVA/Zein/Gelatin nanofiber sheet possessed good morphology, thermal stability, mechanical strength, good antibacterial properties along with excellent antioxidant properties, which makes it the most suitable food packaging for increasing the shelf life of different food items like sweet potatoes, potatoes and kimchi. Shelf life of sweet potatoes and potatoes was observed for a period of 50 days, and shelf life of the kimchi was observed for a period of 30 days. It was concluded that nanofibrous food packaging may enhance the shelf life of fruit and vegetables because of their better breathability and antioxidant properties.

Lignin-facilitated growth of Ag/CuNPs on surface-activated polyacryloamidoxime nanofibers for superior antibacterial activity with improved biocompatibility.

INTRODUCTION: Nanofibers are one of the role-playing innovations of nanotechnology. Their high surface-to-volume ratio allows them to be actively functionalized with a wide range of materials for a variety of applications. The functionalization of nanofibers with different metal nanoparticles (NPs) has been studied widely to fabricate antibacterial substrates to battle antibiotic-resistant bacteria. However, metal NPs show cytotoxicity to living cells, thereby restricting their application in biomedicine. OBJECTIVES: To minimize the cytotoxicity of NPs, biomacromolecule lignin was employed as both a reducing and capping agent to green synthesize silver (Ag) and copper (Cu) NPs on the surface of highly activated polyacryloamidoxime nanofibers. The activation of polyacrylonitrile (PAN) nanofibers via amidoximation was employed for enhanced loading of NPs to achieve superior antibacterial activity. METHODOLOGY: At first, electrospun PAN nanofibers (PANNM) were activated to produce polyacryloamidoxime nanofibers (AO-PANNM) by immersing PANNM in a solution of Hydroxylamine hydrochloride (HH) and Na2CO3 under controlled conditions. Later, Ag and Cu ions were loaded by immersing AO-PANNM in different molar concentrations of AgNO3 and CuSO4 solutions in a stepwise manner. The reduction of Ag and Cu ions into NPs to fabricate bimetal-coated PANNM (BM-PANNM) was carried out via alkali lignin at 37 °C for 3 h in a shaking incubator with ultrasonication every 1 h. RESULTS: AO-APNNM and BM-PANNM hold their nano-morphology except for some changes in fiber orientation. XRD analysis demonstrated the formation of Ag and CuNPs as evident from their respective spectral band. Maximum 8.46 ± 0.14 wt% and 0.98 ± 0.04 wt% Ag and Cu species were loaded on AO-PANNM, respectively as revealed by ICP spectrometric analysis. The hydrophobic PANNM turned into super hydrophilic, having WCA of 14 ± 3.32° after amidoximation which further reduced to 0° for BM-PANNM. However, the swelling ratio of PANNM reduced from 13.19 ± 0.18 g/g to 3.72 ± 0.20 g/g for AO-PANNM. Even at the third cycle test against S. aureus strains, 0.1Ag/Cu-PANNM, 0.3Ag/Cu-PANNM, and 0.5Ag/Cu-PANNM displayed bacterial reduction of 71.3 ± 1.64 %, 75.2 ± 1.91 %, and 77.24 ± 1.25 %, respectively. On 3rd cycle test against E. coli, above 82 % bacterial reduction was noticed for all BM-PANNM. Amidoximation increased COS-7 cell viability up to 82 %. The cell viability of 0.1Ag/Cu-PANNM, 0.3Ag/Cu-PANNM, and 0.5Ag/Cu-PANNM was found to be ∼68 %, ∼62, and 54 %, respectively. In LDH assay, almost no release of LDH was detected, suggesting the compatibility of the cell membrane in contact with BM-PANNM. The improved biocompatibility of BM-PANNM even at higher loading (%) of NPs must be ascribed to the controlled release of metal species in the early stage, antioxidant, and biocompatible lignin capping of NPs. CONCLUSIONS: BM-PANNM displayed superior antibacterial activity against E. coli and S. aureus bacterial strains and acceptable biocompatibility of COS-7 cells even at higher loading (%) of Ag/CuNPs. Our findings suggest that BM-PANNM can be used as a potential antibacterial wound dressing and other antibacterial applications where sustained antibacterial activity is needed.

PVA/Inulin-Based Sustainable Films Reinforced with Pickering Emulsion of Niaouli Essential Oil for Potential Wound Healing Applications.

In this study, sustainable water-based films were produced via the solvent-casting method. Petroleum-free-based polyvinyl alcohol (PVA) and carbohydrate-based inulin (INL) were used as matrices. Vegetable-waste pumpkin powder was used in the study because of its sustainability and antibacterial properties. Pickering emulsions were prepared using ß-cyclodextrin. The influence of the different ratios of the ß-cyclodextrin/niaouli essential oil (ß-CD/NEO) inclusion complex (such as 1:1, 1:3, and 1:5) on the morphological (SEM), thermal (TGA), physical (FT-IR), wettability (contact angle), and mechanical (tensile test) characteristics of PVA/inulin films were investigated. Moreover, the antibacterial activities against the Gram (-) (Escherichia coli and Pseudomonas aeruginosa) and Gram (+) (Staphylococcus aureus) bacteria of the obtained films were studied. From the morphological analysis, good emulsion stability and porosity were obtained in the Pickering films with the highest oil content, while instability was observed in the Pickering films with the lowest concentration of oil content. Thermal and spectroscopic analysis indicated there was no significant difference between the Pickering emulsion films and neat films. With the addition of Pickering emulsions, the tensile stress values decreased from 7.3 ± 1.9 MPa to 3.3 ± 0.2. According to the antibacterial efficiency results, films containing pumpkin powder and Pickering emulsion films containing both pumpkin powder and a ratio of 1:1 (ß-CD/NEO) did not have an antibacterial effect, while Pickering emulsion films with a ratio of (ß-CD/NEO) 1:3 and 1:5 showed an antibacterial effect against Escherichia coli, with a zone diameter of 12 cm and 17 cm, respectively. Among the samples, the films with ratio of (ß-CD/NEO) 1:5 had the highest antioxidant capacity, as assessed by DPPH radical scavenging at 12 h intervals. Further, none of the samples showed any cytotoxic effects the according to LDH and WST-1 cytotoxicity analysis for the NIH3T3 cell line. Ultimately, it is expected that these films are completely bio-based and may be potential candidates for use in wound healing applications.

Synthesized bioactive lignin nanoparticles/polycaprolactone nanofibers: A novel nanobiocomposite for bone tissue engineering.

The use of artificial biomaterial with enhanced bioactivity for osteostimulation is a major research concern at present days. In this research, antibacterial and osteostimulative core-shell lignin nanoparticles (LgNP) were synthesized from alkali lignin using tetrahydrofuran (THF) as solvent via a simultaneous pH and solvent shifting technology. Later, LgNP-loaded polycaprolactone (PCL) composite nanofibers were fabricated via the electrospinning technique. The addition of LgNP significantly increased the diameter of the nanofibers, ranging from 400 to 2200 nm. The addition of LgNP reduced the mechanical performance, crystallinity, and porosity of the nanofibers while improving surface wetting and swelling properties of the inherently hydrophobic PCL polymer. The prepared nanofibers showed excellent bactericidal efficacy against major bone infectious Gram-positive Staphylococcus aureus bacterial strains. The incorporation of LgNP imparted superior antioxidant activity and boosted the biodegradation process of the nanofibers. The deposition of biomineral apatite with platelet-like clustered protrusions having a Ca/P ratio of 1.67 was observed while incubating the scaffold in simulated body fluid. Based on the results of the LDH and WST-1 assay, it was demonstrated that the composite nanofibers are non-toxic to pre-osteoblastic cell line (MC3T3-E1) when they are placed in direct contact with the LgNP/PCL scaffold nanofibers. The MC3T3-E1 cells exhibited excellent proliferation and attachment on the prepared composite scaffold via filopodial and lamellipodial expansion with cell-secreted Ca deposition. According to the alkaline phosphatase activity test, LgNP/PCL nanofiber scaffolds significantly improved osteogenic differentiation of MC3T3-E1 cells compared to neat PCL nanofibers. Overall, our findings suggest that LgNP/PCL nanofiber scaffold could be a promising functional biomaterial for bone tissue engineering.

Antibacterial Activity of Molybdenum Oxide-Polyacrylonitrile Composite Membrane with Fast Silver Ion Reduction.

The development of hybrid composite antibacterial agents for wound dressing has garnered significant attention due to their remarkable antibacterial efficacy and their potential to mitigate microbial resistance. In this study, we present an approach to designing and fabricating wound dressing membranes, utilizing molybdenum oxide-polyacrylonitrile (MoO3/PAN) hybrid composites through electrospinning. Subsequently, we enhanced the membrane's effectiveness by introducing silver (Ag@MoO3/PAN) into the matrix via a rapid (within one min) green synthesis method under UV irradiation. Initially, we discuss the morphological characteristics and structural attributes of the resulting membranes. Subsequent investigations explore the antibacterial mechanisms of both MoO3 and Ag+, revealing that the incorporation of silver substantially enhanced antibacterial activity. Additionally, we elucidate the surface properties, noting that the introduction of silver increases the surface area of the composite membrane by 25.89% compared with the pristine MoO3/PAN membrane. Furthermore, we observe a 9% reduction in the water contact angle (WCA) for the Ag@MoO3/PAN membrane, indicating improved hydrophilicity. Finally, we analyze the release behavior of the Ag@MoO3/PAN membrane. Our findings demonstrate an initial burst release within the first 7 h, followed by a controlled and sustained release pattern over a period of 7 days.

Electrospun Composite Nanofibers for Functional Applications.

of the Special Issue: [...].

Regenerated Silk Nanofibers for Robust and Cyclic Adsorption-Desorption on Anionic Dyes.

In recent years, adsorption-based membranes have been widely investigated to remove and separate textile pollutants. However, cyclic adsorption-desorption to reuse a single adsorbent and clear scientific evidence for the adsorption-desorption mechanism remains challenging. Herein, silk nanofibers were used to assess the adsorption potential for the typical anionic dyes from an aqueous medium, and they show great potential toward the removal of acid dyes from the aqueous solution with an adsorption rate of ∼98% in a 1 min interaction. Further, we measured the filtration proficiency of a silk nanofiber membrane in order to propose a continuous mechanism for the removal of acid blue dye, and a complete rejection was observed with a maximum permeability rate of ∼360 ± 5 L·m-2·h-1. The Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy studies demonstrate that this fast adsorption occurs due to multiple interactions between the dye molecule and the adsorbent substrate. The as-prepared material also shows remarkable results in desorption. A 50-time cycle exhibits complete adsorption and desorption ability, which not only facilitates high removal aptitude but also produces less solid waste than other conventional adsorbents. Additionally, fluorescent 2-bromo-2-methyl-propionic acid (abbreviated as EtOxPY)-silk nanofibers can facilitate to illustrate a clear adsorption and desorption mechanism. Therefore, the above-prescribed results make electrospun silk nanofibers a suitable choice for removing anionic dyes in real-time applications.

Impact of Novel Varietal and Regional Differences on Cotton Fiber Quality Characteristics.

Modernization and the global fashion market demand continuous improvements in upland cotton cultivars (Gossypium hirustum L.) to meet these improved fiber characteristics (fiber length, fiber strength, micronaire) requirements. Researchers have centered their efforts on improved fiber quality; however, the efforts are not immediately supporting the textile sector. The daily mean and temperature amplitude fluctuation affect cotton yield and fiber characteristics. This study analyzed four newly developed cotton varieties in two cotton regions for fiber characteristics' variations. It was observed that cotton fiber quality characteristics (fiber length, uniformity, strength, and micronaire) are impacted in diverse ways. Fiber quality is mainly affected by the genotype and environmental conditions, e.g., weather conditions, irrigation management, fertilization, and cultural practices. The Khanewal region had shown better fiber characteristics than the Multan region, whereas cotton variety CIM-785 had better fiber characteristics in both regions.

Electrospun PVA/CuONPs/Bitter Gourd Nanofibers with Improved Cytocompatibility and Antibacterial Properties: Application as Antibacterial Wound Dressing.

Antibacterial and cyto-compatible tricomponent composite electrospun nanofibers comprised of polyvinyl alcohol (PVA), copper II oxide nanoparticles (CuONPs), and Momordica charantia (bitter gourd, MC) extract were examined for their potential application as an effective wound dressing. Metallic nanoparticles have a wide range of applications in biomedical engineering because of their excellent antibacterial properties; however, metallic NPs have some toxic effects as well. The green synthesis of nanoparticles is undergoing development with the goal of avoiding toxicity. The aim of adding Momordica charantia extract was to reduce the toxic effects of copper oxide nanoparticles as well as to impart antioxidant properties to electrospun nanofibers. Weight ratios of PVA and MC extract were kept constant while the concentration of copper oxide was optimized to obtain good antibacterial properties with reduced toxicity. Samples were characterized for their morphological properties, chemical interactions, crystalline structures, elemental analyses, antibacterial activity, cell adhesion, and toxicity. All samples were found to have uniform morphology without any bead formation, while an increase in diameters was observed as the CuO concentration was increased in nanofibers. All samples exhibited antibacterial properties; however, the sample with CuO concentration of 0.6% exhibited better antibacterial activity. It was also observed that nanofibrous mats exhibited excellent cytocompatibility with fibroblast (NIH3T3) cells. The mechanical properties of nanofibers were slightly improved due to the addition of nanoparticles. By considering the excellent results of nanofibrous mats, they can therefore be recommended for wound dressing applications.

Performance Evaluation of Jute/Glass-Fiber-Reinforced Polybutylene Succinate (PBS) Hybrid Composites with Different Layering Configurations.

The hybridization of natural and synthetic fibers leads to composites' optimum mechanical properties. In this study, an attempt was made to study the effect of the stacking sequence on PBS-based Glass-Jute (GJ) hybrid composites. Six types of hybrid composite, each containing five different layers of jute and glass fabric, were manufactured by the compression molding method. Mechanical properties, such as tensile, flexural, and impact resistance were studied and analyzed in detail. The surface characterization of the composites was performed through scanning electron microscopic images. The moisture absorption properties were also investigated by immersing the composites in distilled water for one week at ambient temperature. The TGA test was conducted to study their thermal properties. The experimental results showed that the stacking sequence of the fiber layers has a significant effect on the overall performance of GJ hybrid composites. Among the hybrid GJ composites, composites with glass fiber layers on their outer surfaces showed optimum mechanical, thermal, and water resistance properties.

Extraction of Natural Dye from Aerial Parts of Argy Wormwood Based on Optimized Taguchi Approach and Functional Finishing of Cotton Fabric.

The aerial parts of the Argy Worm Wood (AWW) plant have been used in different Chinese foods as a colorant and a taste enhancer for a long time. Despite its application as a food colorant, it has rarely been considered for the coloration of textiles. Keeping in mind the variation in color strength due to the change in phytochemical contents by seasonal change and other variables, the extraction of AWW aerial parts was optimized using the Taguchi method. Optimization was performed on the basis of total phytochemical contents (phenols, flavonoids, and tannins) in the extracted solutions. For this purpose, two different solvent systems, namely sodium hydroxide/water (NaOH/water) and ethanol/water (EtOH/water), were applied through a simple aqueous extraction method at varying levels of solvent concentration, and extraction temperature and duration. Maximum phytochemicals yield of 21.96% was obtained using NaOH/water system with 9 g/L NaOH/water at 85 °C for 20 min and 25.5% with 75% aqueous ethanol at 85 °C for 40 min. Optimized extracts were characterized by UV-Vis and FTIR spectrophotometry, which showed the presence of multiple phytochemicals in the extracts. The dyeing temperature and time were also optimized. Dyed cotton fabrics showed medium to high colorfastness to washing and excellent antibacterial and UV radiation absorption properties. The effect of pre-mordanting with salts of iron and copper was also studied on the color fastness properties. Cotton fabrics dyed with two different solvent system extracts displayed various shades of brown with NaOH/water, and green with aqueous ethanol with and without pre-mordanting. The present study provides the textile industry with a promising source of functional bio-colorant and a value-adding approach for the AWW plant industry.

Preparation of a Cage-Type Polyglycolic Acid/Collagen Nanofiber Blend with Improved Surface Wettability and Handling Properties for Potential Biomedical Applications.

Electrospun biobased polymeric nanofiber blends are widely used as biomaterials for different applications, such as tissue engineering and cell adhesion; however, their surface wettability and handling require further improvements for their practical utilization in the assistance of surgical operations. Therefore, Polyglycolic acid (PGA) and collagen-based nanofibers with three different ratios (40:60, 50:50 and 60:40) were prepared using the electrospinning method, and their surface wettability was improved using ozonation and plasma (nitrogen) treatment. The effect on the wettability and the morphology of pristine and blended PGA and collagen nanofibers was assessed using the WCA test and SEM, respectively. It was observed that PGA/collagen with the ratio 60:40 was the optimal blend, which resulted in nanofibers with easy handling and bead-free morphology that could maintain their structural integrity even after the surface treatments, imparting hydrophilicity on the surface, which can be advantageous for cell adhesion applications. Additionally, a cage-type collector was used during the electrospinning process to provide better handling properties to (PGA/collagen 60:40) blend. The resultant nanofiber mat was then incorporated with activated poly (α,ß-malic acid) to improve its surface hydrophilicity. The chemical composition of PGA/collagen 60:40 was assessed using FTIR spectroscopy, supported by Raman spectroscopy.