Frequency Detection for String Instruments Using 1D-2D Non-Contact Mode Triboelectric Sensors.

The proliferation of small electronic devices has significantly increased the demand for self-powered sensors. This study introduces a triboelectric frequency sensor (TFS) that combines the frequency-responsive characteristics of triboelectric nanogenerators with a simple one-dimensional structure for sustainable vibration measurement. This sensor is specifically designed to aid in the tuning of string instruments, capable of detecting frequency responses up to 330 Hz generated by string vibrations. Structural optimization was achieved by setting a non-contact mode with a gap distance of 3 mm and utilizing perfluoroalkoxy alkane (PFA) as the contact dielectric material. The TFS exhibits dynamic response characteristics by varying the vibrating frequency and the tension of the string, facilitated by a custom-built testing setup. Frequency data captured by the sensor can be visualized on a monitor through the integration of a microcontroller unit (MCU) and dedicated coding. The practical applicability and effectiveness of this sensor in real-world scenarios are demonstrated experimentally. This innovation represents a significant step forward in the development of self-sustaining sensing technologies for precision instrument tuning.

Shear Thickening Fluid and Sponge-Hybrid Triboelectric Nanogenerator for a Motion Sensor Array-Based Lying State Detection System.

Issues of size and power consumption in IoT devices can be addressed through triboelectricity-driven energy harvesting technology, which generates electrical signals without external power sources or batteries. This technology significantly reduces the complexity of devices, enhances installation flexibility, and minimizes power consumption. By utilizing shear thickening fluid (STF), which exhibits variable viscosity upon external impact, the sensitivity of triboelectric nanogenerator (TENG)-based sensors can be adjusted. For this study, the highest electrical outputs of STF and sponge-hybrid TENG (SSH-TENG) devices under various input forces and frequencies were generated with an open-circuit voltage (VOC) of 98 V and a short-circuit current (ISC) of 4.5 µA. The maximum power density was confirmed to be 0.853 mW/m2 at a load resistance of 30 MΩ. Additionally, a lying state detection system for use in medical settings was implemented using SSH-TENG as a hybrid triboelectric motion sensor (HTMS). Each unit of a 3 × 2 HTMS array, connected to a half-wave rectifier and 1 MΩ parallel resistor, was interfaced with an MCU. Real-time detection of the patient's condition through the HTMS array could enable the early identification of hazardous situations and alerts. The proposed HTMS continuously monitors the patient's movements, promptly identifying areas prone to pressure ulcers, thus effectively contributing to pressure ulcer prevention.

A Robust Triboelectric Impact Sensor with Carbon Dioxide Precursor-Based Calcium Carbonate Layer for Slap Match Application.

As an urgent international challenge, the sudden change in climate due to global warming needs to be addressed in the near future. This can be achieved through a reduction in fossil fuel utilization and through carbon sequestration, which reduces the concentration of CO2 in the atmosphere. In this study, a self-sustainable impact sensor is proposed through implementing a triboelectric nanogenerator with a CaCO3 contact layer fabricated via a CO2 absorption method. The triboelectric polarity of CaCO3 with the location between the polyimide and the paper and the effects of varying the crystal structure are investigated first. The impact sensing characteristics are then confirmed at various input frequencies and under applied forces. Further, the high mechanical strength and strong adherence of CaCO3 on the surface of the device are demonstrated through enhanced durability compared to the unmodified device. For the intended application, the as-fabricated sensor is used to detect the turning state of the paper Ddakji in a slap match game using a supervised learning algorithm based on a support vector machine presenting a high classification accuracy of 95.8%. The robust CaCO3-based triboelectric device can provide an eco-friendly advantage due to its self-powered characteristics for impact sensing and carbon sequestration.

Switchless Oscillating Charge Pump-Based Triboelectric Nanogenerator and an Additional Electromagnetic Generator for Harvesting Vertical Vibration Energy.

According to energy crisis and increasing number of small electronics, energy harvesting is one of the most promising technologies for scavenging several types of wasted energy. Especially, with regard to vibrational energy harvesting, triboelectric nanogenerators and electromagnetic generators stand out due to their working mechanisms. Here, an oscillating charge pump-based hybrid generator with two triboelectric nanogenerators and an electromagnetic generator using a switching-free characteristic was fabricated with material optimization. To enhance the electrical output of the triboelectric nanogenerator, a concept of charge pumping with simply connecting an additional charge pump device and the nanostructure formation process on the contact metal layer were adopted. The electrical outputs were characterized as an output current of 9.17 µA with a current density of 83.2 mA m-3 in the triboelectric nanogenerator. The power density of the triboelectric nanogenerator reached 4.45 W m-3 with a 40 MΩ resistor. The electromagnetic generator showed an output current density of 0.91 A m-2. Moreover, with the cuboid structure, the device can sense the collision force with different angular displacements from 5 to 30°. The proposed hybrid generator with a simple structure can be applied to sensing applications with the one-point-fixed state.

Film-Sponge-Coupled Triboelectric Nanogenerator with Enhanced Contact Area Based on Direct Ultraviolet Laser Ablation.

Triboelectric nanogenerators (TENGs) recently have emerged as applicable and eco-friendly harvesting devices. Numerous studies have been actively conducted to fabricate a flexible and robust TENG with high-output performance. Herein, a film-sponge-coupled TENG (FS-TENG) is proposed using direct ultraviolet laser ablation, as a method for surface modification of a polyimide (PI) film. This state-of-the-art method has advantages of accuracy as well as time efficiency in creating the pattern on the surface; thus, the pre-designed patterns can be precisely constructed within only a minute. In the laser-ablated PI film, the structural design and chemical modification on the surface are investigated related to the triboelectric output performance. Thereafter, a sponge is fabricated based on non-woven polyamide and silicone rubber, which can fully contact with the micro-/nano-scaled structure on the surface of the PI film. After an optimization, the FS-TENG exhibits 48.19 V of open-circuit voltage and 1.243 µA of short-circuit current, which shows approximately 3 times enhanced electric performance compared to the FS-TENG using a pristine PI film. The FS-TENG device demonstrates its robustness through both mechanical stress and flexible stress by showing less than 5% degradation after 50,000 cycles. On the basis of the high flexibility and stability of the FS-TENG, a self-powered scoreboard is successfully developed for lighting a scoreboard in a soccer field. This feasible lighting system can be operated by harvesting the kinetic energy of a soccer player without an additional power source. The novel FS-TENG, thus, provides remarkable potential for a self-powered indoor harvesting system.

3D Printed Double Roller-Based Triboelectric Nanogenerator for Blue Energy Harvesting.

The ocean covers 70% of the earth's surface and is one of the largest uncultivated resources still available for harvesting energy. The triboelectric energy harvesting technology has the potential to effectively convert the ocean's "blue energy" into electricity. A half-cylinder structure including rollers floating on the water has already been used, in which the pendulum motion of the rollers is driven by the waveform. For the stable motion of the rollers, the printed surface of the device was treated with acetone for attaining hydrophilicity. The electrical outputs with the proposed device were enhanced by increasing the contact surface area by simply implementing the double roller structure with double side-covered electrodes. With the optimized structure, the maximum power density reached a value of 69.34 µW m-2 at a load resistance of 200 MΩ with the device's high output durability. Finally, the fabricated device was also applied to the artificial water waves to demonstrate the possibility of using this device in the ocean. By simply modifying the electrode structure and adding a roller, this device demonstrated the ability to generate over 160% of electrical output with the same covered area of the ocean by the triboelectric nanogenerators (TENGs) and potential ocean application.

Large-Scale Lever-Based Triboelectric Nanogenerator for Sensing Lateral Vibration and Wrist or Finger Bending for Controlling Shooting Game.

With advances in internet of things technology and fossil fuel depletion, energy harvesting has emerged rapidly as a means of supplying small electronics with electricity. As a method of enhancing the electrical output of the triboelectric nanogenerator, specialized for harvesting mechanical energy, structural modification to amplify the input force is receiving attention due to the limited input energy level. In this research, a lever structure was employed for delivering the amplified input force to a triboelectric nanogenerator. With structural optimization of a 2.5 cm : 5 cm distance ratio of the first and second parts using two lever structures, the highest electrical outputs were achieved: a VOC of 51.03 V, current density of 3.34 mA m-2, and power density of 73.5 mW m-2 at 12 MΩ in the second part. As applications of this triboelectric generator, a vertical vibration sensor and a wearable reloading trigger in a gun shooting game were demonstrated. The possibility for a wearable finger bending sensor with low-level input was checked using a minimized device. Enhanced low-detection limit with amplified input force from the structural advantage of this lever-based triboelectric nanogenerator device can expand its applicability to the mechanical trigger for wearable electronics.

Air-gap embedded triboelectric nanogenerator via surface modification of non-contact layer using sandpapers.

With the increased number of small electronics and demand for their energy source, renewable energy sources have received much attention. Above all, a triboelectric nanogenerator (TENG) based on the combination of contact electrification and electrostatic induction has been researched as a method of converting mechanical energy into electricity. In order to increase the electrical output of TENGs with raising the surface charge density, a lot of researchers have focused on the fabrication methods to employ micro-/nano-structures onto a contact surface of the TENG, but have been facing several issues regarding the degradation of the output performance from the iterative operation process. Hence, it is highly required to introduce an approach to enhancing the performance of TENG, while minimally degrading the output power during the long-term operation. In this paper, an air-gap embedded TENG (AE-TENG), which contains a microstructure on the non-contact surface by means of a sandpaper, is proposed. These small air-gaps between the spin-coated polydimethylsiloxane and the non-contact surface can significantly boost the total surface charge density of the dielectric layer. Thus, the electrical output performance of the AE-TENG is enhanced without any surface engineering on the contact surface. Furthermore, the effect of the air-gap induced surface charges on the electric potential is systematically analyzed by not only experimentally electrical outputs, but theoretical and computational modeling based on the V-Q-x relationship and simulation software tool. This air-gap induced triboelectric effect opens a new perspective of the development of electrical outputs by providing a structural/theoretical understanding for TENGs.

Performance-Enhanced Triboelectric Nanogenerator Based on the Double-Layered Electrode Effect.

Recently, studies on enhancing the performance of triboelectric nanogenerators (TENGs) by forming nanostructures at the contacting interface have been actively reported. In this study, a double-layered bottom electrode TENG (DE-TENG) was successfully fabricated using a metal deposition layer after the water-assisted oxidation (WAO) process. As previously reported, the WAO process for the enhancement of electrical performance increases the effective contact area with an inherent surface oxidation layer (Al2O3). As a new approach for modifying deficiencies in the WAO process, a metal deposition onto the oxidation layer was successfully developed with increased device output performance by restoring the surface conductivity. The proposed metal-dielectric-metal sandwich-structured DE-TENG generated approximately twice the electrical output generated by the WAO process alone (WAO-TENG). This dramatically improved electrical output was proven by a theoretical demonstration based on a double capacitance structure. In addition, the double capacitance structure was confirmed with the aid of a field emission scanning electron microscope. The optimal point at which the DE-TENG generates the highest electrical outputs was observed at a specific Cu layer sputtering time. The exceptional durability of the DE-TENG was proved by the 1 h endurance test under various relative humidity conditions. The potential of a self-powered force sensor using this DE-TENG is demonstrated, having a comparably high sensitivity of 0.82 V/N. Considering its structure, increased electrical energy, easy fabrication, and its durability, this novel DE-TENG is a promising candidate for the self-powered energy harvesting technology in our near future.

Omnidirectional Triboelectric Nanogenerator Operated by Weak Wind Towards a Self-Powered Anemoscope.

Wind is a great sustainable energy source for harvesting due to its abundant characteristic. Typically, large space, loud noise, and heavy equipment are essential for a general wind power plant and it is solely operated by big-scale wind. However, wind energy can be efficiently harvested by utilizing the triboelectric nanogenerator due to its abundance, ubiquity, and environmentally friendliness. Furthermore, a few previously reported wind-driven triboelectric nanogenerators, which have the bulk fluttering layer by wind, still show difficulty in generating electricity under the conditions of weak wind because of the static friction arisen from the inherent structure. In this case, the output performance is deteriorated as well as the generator cannot operate completely. In this work, a wind-driven triboelectric nanogenerator (wind-TENG) based on the fluttering of the PTFE strips is proposed to solve the aforementioned problems. At the minimum operating wind pressure of 0.05 MPa, this wind-driven TENG delivers the open-circuit voltage of 3.5 V, short-circuit current of 300 nA, and the associated output power density of 0.64 mW/m2 at the external load resistance of 5 MΩ. Such conditions can be used to light up seven LEDs. Moreover, this wind-TENG has been utilized as a direction sensor which can sense the direction at which the wind is applied. This work thus provides the potential application of the wind-TENG as both self-driven electronics and a self-powered sensor system for detecting the direction under environmental wind.

Dynamic Analysis to Enhance the Performance of a Rotating-Disk-Based Triboelectric Nanogenerator by Injected Gas.

A rotating-disk-based triboelectric nanogenerator (TENG) generating electrical energy from wind usually includes a propeller. TENGs are widely used because their high frequency of rotation allows them to generate a relatively high output current. Deep analysis of the gas flow in a TENG is essential to improve its energy conversion efficiency. However, previous studies have isolated the propeller and the TENG as separate entities that harvest wind energy and generate electrical energy, respectively. Most studies focused on each entity because considering both the dynamics and the TENG operation together is an intricate process. This paper introduces a dynamic analysis of the gas flow by dividing it into four vertical and horizontal directions and carrying out a COMSOL simulation to verify the pressure on the propeller and the flow of the gas. The electrical outputs are measured while varying the height and angle of the inlet and the number of wings on the propeller. After optimization, the P-TENG generated a high output power density of 283.95 mW/m2, which can light up 205 light-emitting diodes and drive a commercial small electronic appliance. In addition, optimizing the P-TENG through a variety of analyses allowed it to provide sustainable power to a self-powered wireless sensor system.

Self-Power Dynamic Sensor Based on Triboelectrification for Tilt of Direction and Angle.

With the great development of the Internet of Things (IoT), the use of sensors have increased rapidly because of the importance in the connection between machines and people. A huge number of IoT sensors consume vast amounts of electrical power for stable operation and they are also used for a wide range of applications. Therefore, sensors need to operate independently, sustainably, and wirelessly to improve their capabilities. In this paper, we propose an orientation and the tilt triboelectric sensor (OT-TES) as a self-powered active sensor, which can simultaneously sense the tilting direction and angle by using the two classical principles of triboelectrification and electrostatic induction. The OT-TES device consists of a rectangular acrylic box containing polytetrafluoroethylene (PTFE) balls moved by gravity. The output voltage and current were 2 V and 20 nA, respectively, with a PTFE ball and Al electrode. The multi-channel system was adopted for measuring the degree and direction of tilt by integrating the results of measured electrical signals from the eight electrodes. This OT-TES can be attached on the equipment for drones or divers to measure their stability. As a result, this proposed device is expected to expand the field of TES, as a sensor for sky and the underwater.

Norisoprenoids and hepatoprotective flavone glycosides from the aerial parts of Beta vulgaris var. cicla.

(+)-Dehydrovomifoliol (1), 3-hydroxy-5alpha,6alpha-epoxy-beta-ionone (2), vitexin 7-O-beta-D-glucopyranoside (3), and vitexin 2''-O-beta-D-glucopyranoside (4) were isolated as new constituents from the aerial parts of Beta vulgaris var. cicla. Compounds 3 and 4 demonstrated hepatoprotective activity with values of 65.8 and 56.1%, respectively, in primary cultured rat hepatocytes with CCl4-induced cell toxicity, compared to controls. This was comparable to that of silibinin (69.8 %) which was used as a positive control.