Enhanced biodegradation of 2, 4-dichlorophenol in packed bed biofilm reactor by impregnation of polyurethane foam with Fe3O4 nanoparticles: Bio-kinetics, process optimization, performance evaluation and toxicity assessment.

In this work, an effort has been made to enhance the efficacy of biological process for the effective degradation of 2, 4-dichlorophenol (2, 4-DCP) from wastewater. The polyurethane foam was modified with Fe3O4 nanoparticles and combined with polyvinyl alcohol, sodium alginate, and bacterial consortium for biodegradation of 2, 4-DCP in a packed bed biofilm reactor. The maximum removal efficiency of 2, 4-DCP chemical oxygen demand, and total organic carbon were found to be 92.51 ± 0.83 %, 86.85 ± 1.32, and 91.78 ± 1.24 %, respectively, in 4 days and 100 mg L-1 of 2, 4-DCP concentration at an influent loading rate of 2 mg L-1h-1 and hydraulic retention time of 50 h. Packed bed biofilm reactor was effective for up to four cycles to remove 2, 4-DCP. Growth inhibition kinetics were evaluated using the Edward model, yielding maximum growth rate of 0.45 day-1, inhibition constant of 110.6 mg L-1, and saturation constant of 62.3 mg L-1.

Degradation of p-cresol in the presence of UV light driven in an integrated system containing photocatalytic and packed bed biofilm reactor.

Integratingphotocatalysisand biodegradation has shown great potential in wastewater treatment technology. In this study, the degradation of p-cresol in water has been investigated through an integrated system comprising of photocatalytic and packed bed biofilm reactor (PBBR). In the photocatalytic reactor, the biodegradability index (BOD5/COD, BOD5/TOC) of the p-cresol solution was first shown to increase (from 0.098±0.023 to 0.59±0.089 for BOD5/COD and from 0.27±0.030 to 1.74±0.03 for BOD5/TOC). The pseudo-first-order rate constant (kap) was found to be 0.011 min-1. The % removal of the integrated system was found to be 98.43±1.31% at an initial concentration of 700 mg L-1 and residence time of 120 h, which was significantly higher than the PBBR operated alone (34.82±2.62%) under optimized conditions (pH 7.0 and T = 32±2 °C). Using an integrated approach, the efficient removal of p-cresol opens novel future perspectives for catalytic degradation using chemical oxidation.