Ultrasonic preparation of cationic cotton and its application in ultrasonic natural dyeing.

Cationization of cotton fabric was conferred by the sonicator reaction of cellulose with bromoacetyl bromide, followed by substitution of the terminal bromo groups by triethylamine. Experiments showed that the optimal volume of bromoacetyl bromide necessary to succeed the first stage was 0.4 mL. The order of weight gain for various processes indicates, ultrasound, 25 kHz> ultrasound, 40 kHz> mechanical stirring. Also, for the second stage the order of nitrogen contents indicates ultrasound, 25 kHz> ultrasound, 40 kHz> mechanical stirring. The structures of both untreated and cationic fibres were investigated by FTIR spectroscopy. Modified cotton fabric was subsequently dyed in both conventional and ultrasonic techniques with isosalipurposide dye isolated from Acacia cyanophylla yellow flowers. The effect of dye bath pH, ultrasonic power and frequency, dyeing time and temperature were studied and the order of K/S values indicates ultrasound, 25 kHz > ultrasound, 40 kHz > CH. ultrasound was also found to enhance the dye uptake and the overall fastness properties. Analysis of the sorption isotherms of isosalipurposide dye on cationic cotton fabric shows that the Languimir isotherm equation is best able to correlate the data.

Ergonomic evaluation of a situation of coexposure to solvents and noise in a printing of flexible packaging.

The purpose of this paper is to present an ergonomic evaluation of a situation of co-exposure to solvents and noise in a flexible packaging printer. We discuss how such an approach carried out in the field of printing industry work has made it possible to highlight serious shortcomings in the effectiveness of the prevention actions that are supposed to protect workers from chemicals risks and noise. The ergonomic analysis identified a strain working conditions. Indeed, some jobs expose to noise and toxic risk. Lamination operations, winding and cutting are purveyors of noise. Some physical and spatial factors contribute to amplify the toxic risk. The not wearing of personal protective equipment (PPE) by the operators maybe explained by the fact that it doesn't any possibility to do "otherwise". Indeed, operators adopt a compromise to achieve the objectives of production to the detriment of their health and safety. These constraints are causing gene and psychosocial factors. The interviews revealed a state of psychosis in the workshop, which was accentuated by the reclassification of an operator which has created a climate of panic and anxiety especially for older operators who have more than 20 years exposed to handling of toxic and more exposure to high noise level.