RESUMO
Most bio-inspired antireflective nanostructures are extremely vulnerable and suffer from complicated lithography-based fabrication procedures. To address the issues, we report a scalable and simple non-lithography-based approach to engineer robust antireflective structures, inspired by the longtail glasswing butterfly, in a single step. The resulting two-dimensional randomly arranged 80/130/180 nm silica colloids, partially embedded in a polymeric matrix, generate a gradual refractive index transition at the air/substrate interface to suppress light reflection. Importantly, the randomly arranged subwavelength silica colloids display even better antireflection performance for large incident angles than that of two-dimensional non-close-packed silica colloidal crystals. The biomimetic coating is of considerable technological importance in numerous practical applications.
RESUMO
Randomly arranged irregular inclined conical structure-covered dragonfly wings, distinguished from periodic conical structure-covered cicada wings, are with high optical transparency for wide viewing angles. Bioinspired by the antireflective structures, we develop a colloidal lithography approach for engineering randomly arranged irregular conical structures with shape memory polymer-based tips. The structures establish a gradual refractive index transition to suppresses optical reflection in the visible spectrum. By manipulating the configuration of structure tips through applying common solvent stimulations or contact pressures under ambient conditions, the resulting unidirectional antireflection and omnidirectional antireflection performances are able to be instantaneously and reversibly switched. The dependences of structure shape, structure inclination, structure arrangement, and structure composition on the switchable antireflection capability are also systematically investigated in this study.
Assuntos
Odonatos , Animais , Asas de AnimaisRESUMO
Randomly arranged inclined irregular nanostructure-covered blue-tailed forest hawk dragonfly wings are highly transparent for wide viewing angles. Inspired by the dragonfly wings, monolayer silica colloids are self-assembled on shape memory polymer-coated substrates and utilized as plasma etching masks to pattern disorderly arranged inclined irregular conical structures. The structures build gradual refractive index transitions at various angles of incidences, resulting in omnidirectional antireflection performance over the whole visible wavelength region. In comparison with a bare substrate, the optimized structure-covered substrate presents 10% higher optical transmission at 0° and even 41% higher optical transmission at an angle of incidence of 75°. Importantly, by manipulating the structural configuration of the shape memory polymer-based structures, the corresponding antireflection characteristics can be instantaneously and reversibly eliminated and recovered after drying out of common household liquids or applying contact pressures in ambient environments. The tunable omnidirectional antireflection coatings are prospective candidates for realizing optical modulation, which exhibits an enormous application value in smart windows, intelligent display screens, optical components, and novel optoelectronic devices.