Tunable encapsulation of sessile droplets with solid and liquid shells.

Droplet encapsulations using liquid or solid shells are of significant interest in microreactors, drug delivery, crystallization, and cell growth applications. Despite progress in droplet-related technologies, tuning micron-scale shell thickness over a large range of droplet sizes is still a major challenge. In this work, we report capillary force assisted cloaking using hydrophobic colloidal particles and liquid-infused surfaces. The technique produces uniform solid and liquid shell encapsulations over a broad range (5-200 µm shell thickness for droplet volume spanning over four orders of magnitude). Tunable liquid encapsulation is shown to reduce the evaporation rate of droplets by up to 200 times with a wide tunability in lifetime (1.5 h to 12 days). Further, we propose using the technique for single crystals and cell/spheroid culture platforms. Stimuli-responsive solid shells show hermetic encapsulation with tunable strength and dissolution time. Moreover, scalability, and versatility of the technique is demonstrated for on-chip applications.

Suppression of droplet pinch-off by early onset of interfacial instability.

HYPOTHESIS: Interfacial instabilities cause undesirable droplet breakage during impact. Such breakage affects many applications, such as printing, spraying, etc. Particle coating over a droplet can significantly change the impact process and stabilize it against breakage. This work investigates the impact dynamics of particle-coated droplets, which mostly remains unexplored. EXPERIMENTS: Particle-coated droplets of different mass loading were formed using volume addition. The prepared droplets were impacted on superhydrophobic surfaces, and their dynamics were recorded using a high-speed camera. FINDINGS: We report an intriguing phenomenon where an interfacial fingering instability helps suppress pinch-off in particle-coated droplets. This island of breakage suppression, where the droplet maintains its intactness upon impact, appears in a regime of Weber numbers where bare droplet breakage is inevitable. The onset of fingering instability in particle-coated droplets is observed at much lower impact energy, around two times less than the bare droplet. The instability is characterized and explained using the rim Bond number. The instability suppresses pinch-off because of the higher losses associated with the formation of stable fingers. Such instability can also be seen in dust/pollen-covered surfaces, making it useful in many applications related to cooling, self-cleaning, anti-icing etc.

Advances in Microscale Droplet Generation and Manipulation.

Microscale droplet generation and manipulation have widespread applications in numerous fields, from biochemical assays to printing and additive manufacturing. There are several techniques for droplet handling. Most techniques, however, can generate and work with only a limited range of droplet sizes. Furthermore, there are constraints regarding the workable variety of fluid properties (e.g., viscosity, surface tension, mass loading, etc.). Recent works have focused on developing techniques to overcome these limitations. This feature article discusses advances in this area that cover a wide range of droplet sizes from subpicoliter to microliter.