1.
Photochem Photobiol
; 2023 Nov 27.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38009436
RESUMO
The irradiation of ß-enaminones, generated in situ from cyclic 1,3-diketones and activated alkenes leads to polyheterocyclic skeletons. The photoproduct chemoselectivity depends on the type of cyclic 1,3-diketones employed viz., 2-acetylcyclopentanone and 2-acetylcyclohexanone. The observed chemoselectivity was rationalized based on the Dieckmann-Kon rule.