Effect of antibiotics on the performance of moving bed biofilm reactor for simultaneous removal of nitrogen, phosphorus and copper(II) from aquaculture wastewater.

Co-existence of NO3--N, antibiotics, phosphorus (P), and Cu2+ in aquaculture wastewater has been frequently detected, but simultaneous removal and relationship between enzyme and pollutants removal are far from satisfactory. In this study, simultaneous removal of NO3--N, P, antibiotics, and Cu2+ by moving bed biofilm reactor (MBBR) was established. About 95.51 ± 3.40% of NO3--N, 61.24 ± 3.51% of COD, 18.74 ± 1.05% of TP, 88% of Cu2+ were removed synchronously in stage I, and antibiotics removal in stages I-IV was 73.00 ± 1.32%, 79.53 ± 0.88%, 51.07 ± 3.99%, and 33.59 ± 2.73% for tetracycline (TEC), oxytetracycline (OTC), chlortetracycline hydrochloride (CTC), sulfamethoxazole (SMX), respectively. The removal kinetics and toxicity of MBBR effluent were examined, indicating that the first order kinetic model could better reflect the removal of NO3--N, TN, and antibiotics. Co-existence of multiple antibiotics and Cu2+ was the most toxicity to E. coli growth. Key enzyme activity, reactive oxygen species (ROS) level, and its relationship with TN removal were investigated. The results showed that enzymes activities were significantly different under the co-existence of antibiotics and Cu2+. Meanwhile, different components of biofilm were extracted and separated, and enzymatic and non-enzymatic effects of biofilm were evaluated. The results showed that 70.00%- 94.73% of Cu2+ was removed by extracellular enzyme in stages I-V, and Cu2+ removal was mainly due to the action of extracellular enzyme. Additionally, microbial community of biofilm was assessed, showing that Proteobacteria, Bacteroidetes, and Gemmatimonadetes played an important role in the removal of NO3--N, Cu2+, and antibiotics at the phylum level. Finally, chemical bonds of attached and detached biofilm were characterized by X-ray photoelectron spectroscopy (XPS), and effect of nitrogen (N) and P was proposed under the co-existence of antibiotics and Cu2+. This study provides a theoretical basis for further exploring the bioremediation of NO3--N, Cu2+, and antibiotics in aquaculture wastewater.

Novel Step Floating Islands VDMOS with Low Specific on-Resistance by TCAD Simulation.

A novel VDMOS with Step Floating Islands VDMOS (S-FLI VDMOS) is proposed for the first time in this letter, in order to optimize the breakdown voltage (BV) and the specific on-resistance (Ron,sp). The innovative terminal technology of Breakdown Point Transfer (BPT) is applied to S-FLI VDMOS, which transfers the breakdown point from the high electric field region to the low electric field region, and the S-FLI VDMOS structure uses multiple layers of charge compensation blocks to generate multiple electric field peaks in the drift region in order to optimize the electric field distribution. In the TCAD simulation, the BV of the proposed S-FLI VDMOS is improved to 326 V, which is higher than that of 281 V for the conventional Si VDMOS with the same drift region length of 15 µm, and the Ron,sp is reduced from 21.54 mΩ·cm2 for the conventional Si VDMOS to 7.77 mΩ·cm2 for the S-FLI VDMOS. Compared with the conventional Si VDMOS, the current density of the effective current conduction path is increased when the forward bias is applied to the proposed device.

Screening silica-confined single-atom catalysts for nonoxidative conversion of methane.

The development of a single-atom iron catalyst (Fe©SiO2) for the direct conversion of methane to olefins, aromatics, and hydrogen is a breakthrough in the field of nonoxidative conversion of methane (NCM). However, the optimization of the catalyst remains desirable for industrial applications. Herein, 25 transition metals, including Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Hf, Ta, W, Re, Os, Ir, Pt, and Au, are selected to replace the central Fe atom for screening out better single-atom catalysts for the NCM. Using the performance on the activation of methane, such as the adsorption energy of methane, the dissociation energy, and the barrier of methane as the screening descriptors, Mn©SiO2, Fe©SiO2, W©SiO2, and Re©SiO2 are first screened out. The remarkable performance of the four catalysts on methane activation is attributed to the unique geometric structure and the dz 2 orbitals of the central metal crossing over the Fermi level, which can benefit the interaction between methane and the catalysts. By considering the catalytic performance on the whole pathway of methane to ethylene, W©SiO2 is finally selected as the most active catalyst for the NCM, which has the lowest rate-determining barrier of 1.62 eV and the smallest free energy span (1.06 eV) of the overall catalytic cycle.

Electrically generated optical waveguide in a lithium-niobate thin film.

This paper reports an electrically generated optical waveguide for the transverse-magnetic wave. The waveguide is formed in a z-cut single-crystal lithium-niobate (LN) thin film by the electro-optic effect, where the extraordinary refractive index (RI) of the LN film is increased by a voltage applied to patterned electrodes that define the waveguide geometry. Such a waveguide can be made to exist or disappear by turning on or off the applied voltage. A straight waveguide and an S-bend waveguide with an RI contrast of ∼0.004 are generated at a voltage of 200 V. The propagation loss of the generated waveguide measured at the wavelength 532 nm is 1.8 dB/cm. Electrically generated optical waveguides could fulfill useful functions in photonic integrated circuits, such as reconfigurable cross connect and switching that require wavelength-independent and mode-independent operation.

Unravelling the Enigma of Nonoxidative Conversion of Methane on Iron Single-Atom Catalysts.

The direct, nonoxidative conversion of methane on a silica-confined single-atom iron catalyst is a landmark discovery in catalysis, but the proposed gas-phase reaction mechanism is still open to discussion. Here, we report a surface reaction mechanism by computational modeling and simulations. The activation of methane occurs at the single iron site, whereas the dissociated methyl disfavors desorption into gas phase under the reactive conditions. In contrast, the dissociated methyl prefers transferring to adjacent carbon sites of the active center (Fe1 ©SiC2 ), followed by C-C coupling and hydrogen transfer to produce the main product (ethylene) via a key -CH-CH2 intermediate. We find a quasi Mars-van Krevelen (quasi-MvK) surface reaction mechanism involving extracting and refilling the surface carbon atoms for the nonoxidative conversion of methane on Fe1 ©SiO2 and this surface process is identified to be more plausible than the alternative gas-phase reaction mechanism.

Optofluidic Tunable Lenses for In-Plane Light Manipulation.

Optofluidics incorporates optics and microfluidics together to construct novel devices for microsystems, providing flexible reconfigurability and high compatibility. Among many novel devices, a prominent one is the in-plane optofluidic lens. It manipulates the light in the plane of the substrate, upon which the liquid sample is held. Benefiting from the compatibility, the in-plane optofluidic lenses can be incorporated into a single chip without complicated manual alignment and promises high integration density. In term of the tunability, the in-plane liquid lenses can be either tuned by adjusting the fluidic interface using numerous microfluidic techniques, or by modulating the refractive index of the liquid using temperature, electric field and concentration. In this paper, the in-plane liquid lenses will be reviewed in the aspects of operation mechanisms and recent development. In addition, their applications in lab-on-a-chip systems are also discussed.

Dielectrophoresis-actuated liquid lenses with dual air/liquid interfaces tuned from biconcave to biconvex.

This paper reports an electrically reconfigurable optofluidic lens with two air-liquid (silicone oil) interfaces actuated by dielectrophoretic (DEP) force. Initially, a symmetric biconcave air-liquid lens is formed by the surface tension in a microfluidic chip. Then, the DEP force deforms the air-liquid interfaces from biconcave to biconvex, tuning the focal length from -0.5 mm to infinite to +0.5 mm. The wide tunability of the focal length results from the large refractive index difference (∼0.4 at the air-liquid interface), which is only 0.1 in previous liquid-liquid lenses. In the experiment, the lens achieves an ƒ number of 0.91 while consuming only 6.7 nJ per circle. Some asymmetric working states, such as concave-convex and plano-convex lenses, have also been demonstrated. Compared with continuous liquid flow-sustained lenses, this stationary liquid lens holds promise of better compatibility and higher scalability. Its wide tunability, low power consumption and easy operation make it suitable for light manipulation in microfluidic networks.

Dielectrophoresis-actuated in-plane optofluidic lens with tunability of focal length from negative to positive.

This paper reports a tunable in-plane optofluidic lens by continuously tuning a silicone oil-air interface from concave to convex using the dielectrophoresis (DEP) force. Two parallel glasses are bonded firmly on two sides by NOA 81(Norland Optical Adhesive 81) spacers, forming an open microfluidic channel. An ITO (indium tin oxide) strip and another unpatterned ITO layer are deposited on two glasses as the top and bottom electrodes. Initially, a capillary concave liquid-air interface is formed at the end of the open channel. Then the DEP force is enabled to continuously deform the interface (lens) from concave to convex. In the experiment, the focal length gradually decreases from about -1 mm to infinite and then from infinite to around + 1 mm when the driving voltage is increased from 0 V to 260 V. Particularly, the longitudinal spherical aberration (LSA) is effectively suppressed to have LSA < 0.04 when the lens is operated in the focusing state. This work is the first study of in-plane tunable lenses using the DEP force and possesses special merits as compared to the other reported tunable lenses that are formed by pumping different liquids or by temperature gradient, such as wide tunability, no need for continuous supply of liquids, low power consumption (~81 nJ per switching) due to the capacitor-type driving, and the use of only one type of liquid. Besides, its low aberration makes it favorable for light manipulation in microfluidic networks.

Review on optofluidic microreactors for artificial photosynthesis.

Artificial photosynthesis (APS) mimics natural photosynthesis (NPS) to store solar energy in chemical compounds for applications such as water splitting, CO2 fixation and coenzyme regeneration. NPS is naturally an optofluidic system since the cells (typical size 10 to 100 µm) of green plants, algae, and cyanobacteria enable light capture, biochemical and enzymatic reactions and the related material transport in a microscale, aqueous environment. The long history of evolution has equipped NPS with the remarkable merits of a large surface-area-to-volume ratio, fast small molecule diffusion and precise control of mass transfer. APS is expected to share many of the same advantages of NPS and could even provide more functionality if optofluidic technology is introduced. Recently, many studies have reported on optofluidic APS systems, but there is still a lack of an in-depth review. This article will start with a brief introduction of the physical mechanisms and will then review recent progresses in water splitting, CO2 fixation and coenzyme regeneration in optofluidic APS systems, followed by discussions on pending problems for real applications.

Planar polarization-routing optical cross-connects using nematic liquid crystal waveguides.

This paper presents the device design and performance analysis of a novel design of planar optical cross-connect (OXC) using nematic liquid crystal (NLC) waveguides. It employs N × N switching matrix in cross-bar fabric. In each unit cell, the input light is set in either the transverse electric (TE) mode or the transverse magnetic (TM) mode by electrically reorienting the NLC in the waveguide. The light then enters a passive waveguide and is routed to different paths depending on the polarization state (TE/TM mode). A sample device of 8 × 8 OXC is analyzed for performance estimation, which predicts a maximum on-chip insertion loss of 3 dB, an average cross-talk of -40 dB, ~1 ms switching time, and 2 mm × 2 mm footprint. The proposed OXC is unique in the switching mechanism of polarization-dependent routing and allows non-blocking switching with high compactness and broad bandwidth. It is potential for optical circuit switching in data centers and optical communication networks.

The Influence of Fiber Cross-Section on Fabric Far-Infrared Properties.

Far-infrared radiation (FIR) possesses various promising properties that are beneficial to an individuals' health. Exploring the interaction between fiber shapes and FIR performance is thought to be a significant means to develop highly-efficient FIR textile products. In this study, a non-additive triangular polyamide (PA) fiber showed excellent FIR properties in both theoretical simulation and experimental verification aspects. The triangular PA fiber affords a higher probability to facilitate large optical path difference, improving both FIR absorption and emission. Textiles woven with the specific triangular PA fiber achieved a remarkable emissivity of 91.85% and temperature difference of 2.11 Celsius, which is obviously superior to the reference circular fiber (86.72%, 1.52 Celsius). Considering the low cost, environmental stability, facile fabrication, as well as being environmentally friendly, this non-additive triangular PA fiber has great potential for high-performance and cost-effective FIR textiles in the future.

Electrically controlled polarization rotator using nematic liquid crystal.

Here we report a planar polarization rotator using a nematic liquid crystal waveguide, which is subject to a gradient electric field in parallel to the waveguide substrate plane. The fabricated polydimethylsiloxane (PDMS) device has demonstrated the electrically-controlled polarization rotation at a switching time of 70 ms and a propagation loss of 9 dB/cm at 532 nm. The unique features such as planar form, electric control, and soft material allows integration into planar lightwave circuits and flexible photonics.

Rough gold films as broadband absorbers for plasmonic enhancement of TiO2 photocurrent over 400-800 nm.

Recent years have witnessed an increasing interest in highly-efficient absorbers of visible light for the conversion of solar energy into electrochemical energy. This study presents a TiO2-Au bilayer that consists of a rough Au film under a TiO2 film, which aims to enhance the photocurrent of TiO2 over the whole visible region and may be the first attempt to use rough Au films to sensitize TiO2. Experiments show that the bilayer structure gives the optimal optical and photoelectrochemical performance when the TiO2 layer is 30 nm thick and the Au film is 100 nm, measuring the absorption 80-90% over 400-800 nm and the photocurrent intensity of 15 µA·cm(-2), much better than those of the TiO2-AuNP hybrid (i.e., Au nanoparticle covered by the TiO2 film) and the bare TiO2 film. The superior properties of the TiO2-Au bilayer can be attributed to the rough Au film as the plasmonic visible-light sensitizer and the photoactive TiO2 film as the electron accepter. As the Au film is fully covered by the TiO2 film, the TiO2-Au bilayer avoids the photocorrosion and leakage of Au materials and is expected to be stable for long-term operation, making it an excellent photoelectrode for the conversion of solar energy into electrochemical energy in the applications of water splitting, photocatalysis and photosynthesis.

High-precision system identification method for a deformable mirror in wavefront control.

Based on a mathematic model, the relation between the accuracy of the influence matrix and the performance of the wavefront correction is established. Based on the least squares method, a two-step system identification is proposed to improve the accuracy of the influence matrix, where the measurement noise can be suppressed and the nonlinearity of the deformable mirror can be compensated. The validity of the two-step system identification method is tested in the experiment, where improvements in wavefront correction precision as well as closed-loop control efficiency were observed.

Research on the particular temperature-induced surface shape of a National Ignition Facility deformable mirror.

We investigate the changes in the shape of a deformable mirror used at the National Ignition Facility caused by differences in temperature between the working environment and the mounting temperature of the mirror. In general, the temperature-induced profile change of the mirror is dominated by a few low-order aberrations, which mainly result in defocus. However, after these low-order distortions are corrected, there remain special, higher-order, surface distortions caused by the particular arrangement, construction, and mounting of the mirror actuators. This work analyzes these special aberrations, and their dependence on the particular actuator design, using the finite element method. Experiments are carried out to verify the computational results, and finally, design considerations to help minimize the temperature-induced high-order aberrations are suggested.

Weighted Fried reconstructor and spatial-frequency response optimization of Shack-Hartmann wavefront sensing.

Two modified Fried wavefront reconstructors are proposed, both based on an enhanced geometry that combines and balances those of Fried and Hudgin with an additional weight. The optimal weights for both of them are derived with the analytical frequency response functions, which can provide near-unity spatial frequency response over broad bandwidth to the Shack-Hartmann wavefront sensing system. Comparisons between the proposed reconstructors and the classical ones are presented in the frequency domain, and simulations have further confirmed the frequency characteristic and the reconstruction performance of the new reconstructors. It is expected that the optimized reconstructors can help improve the performance of adaptive optics systems for high-power laser wavefront control and other relevant optical systems that require high-accuracy wavefront sensing.