Spin-liquid-like state in a spin-1/2 square-lattice antiferromagnet perovskite induced by d10-d0 cation mixing.

A quantum spin liquid state has long been predicted to arise in spin-1/2 Heisenberg square-lattice antiferromagnets at the boundary region between Néel (nearest-neighbor interaction dominates) and columnar (next-nearest-neighbor interaction dominates) antiferromagnetic order. However, there are no known compounds in this region. Here we use d10-d0 cation mixing to tune the magnetic interactions on the square lattice while simultaneously introducing disorder. We find spin-liquid-like behavior in the double perovskite Sr2Cu(Te0.5W0.5)O6, where the isostructural end phases Sr2CuTeO6 and Sr2CuWO6 are Néel and columnar type antiferromagnets, respectively. We show that magnetism in Sr2Cu(Te0.5W0.5)O6 is entirely dynamic down to 19 mK. Additionally, we observe at low temperatures for Sr2Cu(Te0.5W0.5)O6-similar to several spin liquid candidates-a plateau in muon spin relaxation rate and a strong T-linear dependence in specific heat. Our observations for Sr2Cu(Te0.5W0.5)O6 highlight the role of disorder in addition to magnetic frustration in spin liquid physics.

Size dependent structural and magnetic properties of FeO-Fe3O4 nanoparticles.

The magnetic properties of monodisperse FeO-Fe3O4 nanoparticles with different mean sizes and volume fractions of FeO synthesized via decomposition of iron oleate were correlated to their crystallographic and phase compositional features by exploiting high resolution transmission electron microscopy, X-ray diffraction, Mössbauer spectroscopy and field and zero field cooled magnetization measurements. A model describing the phase transformation from a pure Fe3O4 phase to a mixture of Fe3O4, FeO and interfacial FeO-Fe3O4 phases as the particle size increases was established. The reduced magnetic moment in FeO-Fe3O4 nanoparticles was attributed to the presence of differently oriented Fe3O4 crystalline domains in the outer layers and paramagnetic FeO phase. The exchange bias energy, dominating magnetization reversal mechanism and superparamagnetic blocking temperature in FeO-Fe3O4 nanoparticles depend strongly on the relative volume fractions of FeO and the interfacial phase.

Highly stable monodisperse PEGylated iron oxide nanoparticle aqueous suspensions: a nontoxic tracer for homogeneous magnetic bioassays.

Uniformly sized and shaped iron oxide nanoparticles with a mean size of 25 nm were synthesized via decomposition of iron-oleate. High resolution transmission electron microscopy and Mössbauer spectroscopy investigations revealed that the particles are spheres primarily composed of Fe3O4 with a small fraction of FeO. From Mössbauer and static magnetization measurements, it was deduced that the particles are superparamagnetic at room temperature. The hydrophobic particles were successfully transferred into water via PEGylation using nitrodopamine as an anchoring group. IR spectroscopy and thermogravimetric analysis showed the success and efficiency of the phase transfer reaction. After PEGylation, the particles retained monodispersity and their magnetic core remained intact as proven by photon cross-correlation spectroscopy, ac susceptibility, and transmission electron microscopy. The particle aqueous suspensions revealed excellent water stability over a month of monitoring and also against temperature up to 40 °C. The particles exhibited a moderate cytotoxic effect on in vitro cultured bone marrow-derived macrophages and no release of inflammatory or anti-inflammatory cytokines. The PEGylated particles were functionalized with Herceptin antibodies via a conjugation chemistry, their response to a rotating magnetic field was studied using a fluxgate-based setup and was compared with the one recorded for hydrophobic and PEGylated particles. The particle phase lag rose after labeling with Herceptin, indicating the successful conjugation of Herceptin antibodies to the particles.

Magnetism of the chromium thio-spinels Fe1-xCuxCr2S4 studied using muon spin rotation and relaxation.

Powder samples of Fe1-xCuxCr2S4 with x = 0,0.2,0.5,0.8 were studied, between 5 and 300 K. The results reveal that for x < 1, the magnetic order in the series is more varied than the simple collinear ferrimagnetic structure traditionally assumed to exist everywhere from the Curie point to T â†’ 0. In FeCr2S4 several ordered magnetic phases are present, with the ground state likely to have an incommensurate cone-like helical structure. Fe0.8Cu0.2Cr2S4 is the compound for which simple collinear ferrimagnetism is best developed. In Fe0.5Cu0.5Cr2S4 the ferrimagnetic spin structure is not stable, causing spin reorientation around 90 K. In Fe0.2Cu0.8Cr2S4 the ferrimagnetic structure is at low temperatures considerably distorted locally, but with rising temperature this disorder shows a rapid reduction, coupled to increased spin fluctuation rates. In summary, the present data show that the changes induced by the replacement of Fe by Cu have more profound influences on the magnetic properties of the Fe1-xCuxCr2S4 compounds than merely a shift of Curie temperature, saturation magnetization and internal field magnitude.

Low temperature incommensurately modulated and noncollinear spin structure in FeCr2S4.

FeCr(2)S(4) orders magnetically at T(N)≈ 170 K. According to neutron diffraction, the ordered state down to 4.2 K is a simple collinear ferrimagnet maintaining the cubic spinel structure. Later studies, however, claimed trigonal distortions below ∼ 60 K coupled to the formation of a spin glass type ground state. To obtain further insight, muon spin rotation/relaxation (µSR) spectroscopy was carried out between 5 and 200 K together with new (57)Fe Mössbauer measurements. Below ∼ 50 K, our data point to the formation of an incommensurately modulated noncollinear spin arrangement like a helical spin structure. Above 50 K, the spectra are compatible with collinear ferrimagnetism, albeit with a substantial spin disorder on the scale of a few lattice constants. These spin lattice distortions become very large at 150 K and the magnetic state is now better characterized as consisting of rapidly fluctuating short-range ordered spins. The Néel transition is of second order, but ill defined, extending over a range of ∼ 10 K. The Mössbauer data around 10 K confirm the onset of orbital freezing and are also compatible with the noncollinear order of iron. The absence of a major change in the quadrupole interaction around 50 K renders the distortion of crystal symmetry to be small.

The electronic phase diagram of the LaO(1-x)F(x)FeAs superconductor.

The competition of magnetic order and superconductivity is a key element in the physics of all unconventional superconductors, for example in high-transition-temperature cuprates, heavy fermions and organic superconductors. Here superconductivity is often found close to a quantum critical point where long-range antiferromagnetic order is gradually suppressed as a function of a control parameter, for example charge-carrier doping or pressure. It is believed that dynamic spin fluctuations associated with this quantum critical behaviour are crucial for the mechanism of superconductivity. Recently, high-temperature superconductivity has been discovered in iron pnictides, providing a new class of unconventional superconductors. Similar to other unconventional superconductors, the parent compounds of the pnictides show a magnetic ground state and superconductivity is induced on charge-carrier doping. In this Letter the structural and electronic phase diagram is investigated by means of X-ray scattering, muon spin relaxation and Mössbauer spectroscopy on the series LaO(1-x)F(x)FeAs. We find a discontinuous first-order-like change of the Néel temperature, the superconducting transition temperature and the respective order parameters. Our results strongly question the relevance of quantum critical behaviour in iron pnictides and prove a strong coupling of the structural orthorhombic distortion and the magnetic order both disappearing at the phase boundary to the superconducting state.

Field-induced coupled superconductivity and spin density wave order in the heavy fermion compound CeCoIn5.

The high-field superconducting state in CeCoIn(5) has been studied by transverse field muon spin rotation measurements with an applied field parallel to the crystallographic c axis close to the upper critical field mu(0)H(c2) = 4.97 T. At magnetic fields mu(0)H > or = 4.8 T the muon Knight shift is enhanced and the superconducting transition changes from second order towards first order as predicted for Pauli-limited superconductors. The field and temperature dependence of the transverse muon spin relaxation rate sigma reveal paramagnetic spin fluctuations in the field regime from 2 T < or = mu(0)H < 4.8 T. In the normal state close to H(c2) correlated spin fluctuations as described by the self-consistent renormalization theory are observed. The results support the formation of a mode-coupled superconducting and antiferromagnetically ordered phase in CeCoIn(5) for H directed parallel to the c axis.

Commensurate spin density wave in LaFeAsO: a local probe study.

We present a detailed study on the magnetic order in the undoped mother compound LaFeAsO of the recently discovered Fe-based superconductor LaFeAsO1-xFx. In particular, we present local probe measurements of the magnetic properties of LaFeAsO by means of 57Fe Mössbauer spectroscopy and muon-spin relaxation in zero external field along with magnetization and resistivity studies. These experiments prove a commensurate static magnetic order with a strongly reduced ordered moment of 0.25(5)muB at the iron site below T(N)=138 K, well separated from a structural phase transition at T(S)=156 K. The temperature dependence of the sublattice magnetization is determined and compared to theory. Using a four-band spin density wave model both, the size of the order parameter and the quick saturation below T(N) are reproduced.

Giant spin canting in the S=1/2 antiferromagnetic chain [CuPM(NO3)2(H2O)2]n observed by 13C-NMR.

We present a combined experimental and theoretical study on copper pyrimidine dinitrate [CuPM(NO3)2(H2O)2]n, a one-dimensional S=1/2 antiferromagnet with alternating local symmetry. From the local susceptibility measured by NMR at the three inequivalent carbon sites in the pyrimidine molecule we deduce a giant spin canting, i.e., an additional staggered magnetization perpendicular to the applied external field at low temperatures. The magnitude of the transverse magnetization, the spin canting of (52+/-4) degrees at 10 K and 9.3 T, and its temperature dependence are in excellent agreement with exact diagonalization calculations.

Metallic ground state and glassy transport in single crystalline URh2Ge2: enhancement of disorder effects in a strongly correlated electron system.

We present a detailed study of the electronic transport properties on a single crystalline specimen of the moderately disordered heavy-fermion system URh2Ge2. For this material, we find glassy electronic transport in a single crystalline compound. We derive the temperature dependence of the electrical conductivity and establish metallicity by means of optical conductivity and Hall effect measurements. The overall behavior of the electronic transport properties closely resembles that of metallic glasses, with at low temperatures an additional minor spin disorder contribution. We argue that this glassy electronic behavior in a crystalline compound reflects the enhancement of disorder effects as a consequence of strong electronic correlations.

Observation of the conduction electron spin polarization in the Ag spacer of a Fe/Fg/Fe trilayer.

The spatially oscillating electron spin polarization in the Ag spacer of a 4 nm Fe/20 nmAg/4 nm Fe(001) epitaxial trilayer has been determined by means of low energy muon spin rotation. It oscillates with the same period as the interlayer exchange coupling, but shows a much weaker attenuation at large distances x from the interface. The measured magnetization profile from the inner 14 nm of the spacer is described by an oscillating polarization decaying as x(-0.8(1)). This unusual behavior may arise from a full confinement of electron states within the spacer.