Effective removal of acetamiprid and eosin Y by adsorption on pristine and modified MIL-101(Fe).

In this work, the efficacy of two metal-organic frameworks (MIL-101(Fe) and NH2-MIL-101(Fe)) in eliminating acetamiprid (ATP) insecticide and eosin Y (EY) dye from aqueous solution is tested. An analysis was conducted on the developed nanocomposite's optical, morphological, and structural characteristics. The adsorption isotherm, kinetics, thermodynamics, reusability, and mechanisms for ATP and EY dye removal were assessed. NH2-MIL-101(Fe) adsorbed 76% and 90% of ATP pesticide and EY dye, respectively after 10 to 15 min in optimum conditions. For both adsorbents, with regard to explaining the isotherm data, the Langmuir model offered the most accurate description. Moreover, the adsorption of ATP and EY dye is described by the pseudo-second-order kinetic model. The maximum adsorption capacities of ATP and EY dye on MIL-101(Fe) were 57.6 and 48.9 mg/g compared to 70.5 and 97.8 mg/g using NH2-MIL-101(Fe). The greatest amount of ATP and EY dye clearance was obtained at a neutral medium for both adsorbents. The results of this investigation demonstrate the effectiveness of MIL-101(Fe) and NH2-MIL-101(Fe) as effective substances in the adsorption process for removing pesticides and dyes from aqueous solution.

Novel mint-stalks derived biochar for the adsorption of methylene blue dye: Effect of operating parameters, adsorption mechanism, kinetics, isotherms, and thermodynamics.

The pyrolysis of mint stalks and lemon peels was performed to synthesize mint-stalks (MBC) and lemon-peels (LBC) derived biochars for adsorbing methylene blue (MB). The preparation, characterization, and application of MBC in adsorption have not been reported in the literature. MBC showed higher surface area and carbon content than that of LBC. The removal ratios of MB were 87.5% and 60% within 90 min for MBC and LBC, respectively at pH 7, temperature of 30oC, adsorbent dose of 0.5 g/L, and MB concentration of 5 mg/L. The optimal MBC dose was 1 g/L achieving a removal efficiency of 93.6% at pH 7, temperature of 30oC, contact time of 90 min, and initial dye concentration of 5.0 mg/L. The adsorption efficiency decreased from 98.6% to 31.33% by raising the dye concentration from 3.0 mg/L to 30 mg/L. Further, the increase of adsorbent dose to 10 g/L could achieve 94.2%, 90.3%, 87.6%, and 84.1% removal efficiencies of MB in the case of initial concentrations of 200 mg/L, 300 mg/L, 400 mg/L, and 500 mg/L, respectively. MBC showed high stability in adsorbing MB under five cycles, and the performed analyses after adsorption reaffirmed the stability of MBC. The adsorption mechanism indicated that the adsorption of MB molecules on the biochar's surface was mainly because of the electrostatic interaction, hydrogen bonding, and π-π stacking. Pseudo-second-order and Langmuir models could efficiently describe the adsorption of MB on the prepared biochar. The adsorption process is endothermic and spontaneous based on the adsorption thermodynamics. The proposed adsorption system is promising and can be implemented on a bigger scale. Moreover, the prepared biochar can be implemented in other applications such as photocatalysis, periodate, and persulfate activation-based advanced oxidation processes.

Degradation of levofloxacin using electro coagulation residuals-alginate beads as a novel heterogeneous electro-fenton composite.

The presence of levofloxacin (LEV) in aqueous solutions can pose health risks to humans, have adverse effects on aquatic organisms and ecosystems, and contribute to the development of antibiotic-resistant bacteria. This study aims to investigate the feasibility of using electrocoagulation residuals (ECRs) as a heterogeneous catalyst in the electro-Fenton process for degrading LEV. By combining electrocoagulation residuals with sodium alginate, ECRs-alginate beads were synthesized as a heterogeneous electro-Fenton composite. The response surface method was employed to investigate the optimization and influence of various operating parameters such as the initial concentration of LEV (10-50 mg/L), voltage (15-35 V), pH (3-9), and catalyst dose (1-9 g/L). The successful incorporation of iron and other metals into the ECRs-alginate beads was confirmed by characterization tests such as EDX and FTIR. By conducting a batch reaction under optimal conditions (initial LEV concentration = 20 mg/L, pH = 4.5, voltage = 30V, and catalyst dose = 7 g/L), a remarkable degradation of 99% for LEV was achieved. Additionally, under these optimal conditions, a high removal efficiency of 92.3% for total organic carbon (TOC) could be attained within 120 min and these findings are remarkable compared to previous studies. The results further indicated that the degradation of levofloxacin (LEV) could be accurately quantified by utilizing the first-order kinetic reaction with a 0.03 min-1 rate constant. The synthesized beads offered notable advantages in terms of being eco-friendly, simple to use, highly efficient, and easily recoverable from the liquid medium after use.

Photo-thermal activation of persulfate for the efficient degradation of synthetic and real industrial wastewaters: System optimization and cost estimation.

The photo-thermal activation of persulfate (PS) was carried out to degrade various pollutants such as reactive blue-222 (RB-222) dye, sulfamethazine, and atrazine. Optimizing the operating parameters showed that using 0.90 g/L of PS at pH 7, temperature of 90 °C, initial dye concentration of 21.60 mg/L, and reaction time of 120 min could attain a removal efficiency of 99.30%. The degradation mechanism was explored indicating that hydroxyl and sulfate radicals were the prevailing reactive species. The degradation percentages of 10 mg/L of sulfamethazine and atrazine were 83.30% and 70.60%, respectively, whereas the mineralization ratio was 63.50% in the case of real textile wastewater under the optimal conditions at a reaction time of 120 min. The treatment cost per 1 m3 of real wastewater was appraised to be 1.13 $/m3 which assured the inexpensiveness of the proposed treatment system. This study presents an effective and low-cost treatment system that can be implemented on an industrial scale.

Effective photocatalytic degradation of amoxicillin using MIL-53(Al)/ZnO composite.

A promising hierarchical nanocomposite of MIL-53(Al)/ZnO was synthesized as a visible-light-driven photocatalyst to investigate the degradation of amoxicillin (AMX). MIL-53(Al)/ZnO ultrafine nanoparticles were obtained by preparing Zn-free MIL-53Al and employing it as a reactive template under hydrothermal and chemical conditions. The synthesized nanocomposite (MIL-53(Al)/ZnO) has a low content of Al > 1.5% with significantly different characterizations of the parent compounds elucidated by various analyses such as SEM, TEM, XRD, EDX, and UV-Vis. The effect of operational parameters (catalyst dose (0.2-1.0 g/L), solution pH (3-11), and initial AMX concentration (10-90 mg/L)) on the AMX removal efficiency was studied and optimized by the response surface methodology. A reasonable goodness-of-fit between the expected and experimental values was confirmed with correlation coefficient (R2) equal to 0.96. Under the optimal values, i.e., initial AMX concentration = 10 mg/L, solution pH ~ 4.5, and catalyst dose = 1.0 g/L, 100% AMX removal was achieved after reaction time = 60 min. The degradation mechanism and oxidation pathway were vigorously examined. The AMX degradation ratios slightly decreased after five consecutive cycles (from 78.19 to 62.05%), revealing the high reusability of MIL-53(Al)/ZnO. The AMX removal ratio was improved with enhancers in order ([Formula: see text]> H2O2 > S2O8-2). The results proved that 94.12 and 98.23% reduction of COD were obtained after 60 and 75 min, respectively. The amortization and operating costs were estimated at 3.3 $/m3 for a large-scale photocatalytic system.

Reuse of adsorption residuals for enhancing removal of ciprofloxacin from wastewater.

Costs of water treatment can be reduced significantly if the spent adsorbents can be reused or regenerated. In this study, two residuals of iron adsorbed onto low-cost activated carbon (Fe-MCAC and Fe-MLAC) are reused as new adsorbents for the removal of ciprofloxacin (CIP) from pharmaceuticals wastewater. The residuals were characterized by SEM, XRD, FTIR, Raman spectra and N2-adsorption desorption. The adsorption mechanisms, performance, kinetics, isotherm, thermodynamic and reusability of residuals for CIP removal were evaluated. The isotherm data were well defined by the Freundlich model for both adsorbents (residuals). Moreover, the CIP adsorption follows the pseudo-second-order kinetic model. The maximum adsorption capacity of CIP on Fe-MCAC and Fe-MLAC was 476.19 and 416.67 mg/g, respectively. The maximum removal of CIP was obtained at pH 7 for both new adsorbents. The optimum contact time was found to be 30 and 60 min for Fe-MCAC and Fe-MLAC, respectively. The values of free energy change and enthalpy change for adsorption of CIP indicated the spontaneous, endothermic nature of the adsorption. In addition, the adsorption process was assisted by increasing randomness due to the value of entropy change. Therefore, the residuals of iron adsorption onto activated carbons could be reused as new low-cost adsorbents for antibiotics removal from wastewater.

Fast adsorption of phosphate (PO4 -) from wastewater using glauconite.

In this study, the removal of phosphate (PO4 -) from wastewater using glauconite was investigated. Glauconite was characterized by N2 adsorption-desorption isotherm, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, and Fourier transform infrared (FTIR) spectroscopy. The effects of contact time, pH, initial phosphate concentrations, adsorbent dose, and temperature were investigated by batch experiments. The isotherms, kinetics and thermodynamics for phosphate removal were studied. The results showed that glauconite had a rough surface and abundant pores. The determined Brunauer-Emmett-Teller (BET) surface area was 55 m2/g with a pore radius of 1.99 nm and the pore volume was 0.032 cm3/g. FTIR analysis revealed that the abundance of various functional groups on the surface of glauconite may play an important role for the adsorption process. The optimum pH was 11 with complete removal of phosphate in a short time (nearly 1 min). The experimental data fitted very well with the Langmuir isotherm (R2 = 0.999) with a maximum adsorption capacity of 32.26 mg/g at 50 °C. Adsorption kinetic data were best fitted with the pseudo-second-order kinetic model (R2 = 0.999). Thermodynamic study confirmed the spontaneous, endothermic and irreversible adsorption process. Therefore, glauconite is a promising natural low-cost adsorbent for phosphate removal from wastewater.