Nonlinear Optical Properties and All Optical Switching of Curcumin Derivatives.

In this work OR1(E1,6E) -1,7-bis (4-propyloxy phenyl) hepta-1,6-diene-3,5 dione compound is synthesized. The compound has been characterized via computational technique by studying the molecule's electronic structures through calculating its HOMO and LUMO energies, and its band gap energy (EHOMO-ELUMO). The nonlinear refractive index (NLRI) of the solution of OR1 compound in DMF solvent is determined using diffraction patterns (DPs) which resulted when a continuous wave laser beam of wavelength 473 nm traversed the compound solution in a glass cell of 1 mm thickness. By counting the number of rings under maximum beam input power, the NLRI of value 10- 6 cm2/W resulted. The NLRI is calculated once more via the Z-scan technique and a value of 0.25 × 10- 7 cm2/W is obtained. The vertical convection current in the OR1 compound solution appears to be responsible for the asymmetries noticed in the DPs. The temporal variation of each DP is noticed together with the evolution of DPs against beam input power. DPs are numerically simulated based on the Fresnel-Kirchhoff integral with good accord compared to the experimental findings. Dynamic and static all-optical switching in the OR1 compound using two laser beams (473 and 532 nm) is tested successfully.

Photocatalytic activity and photoelectrochemical properties of Ag/ZnO core/shell nanorods under low-intensity white light irradiation.

Zinc oxide (ZnO) nanorod thin films were prepared by CBD onto glass and FTO/glass substrates. Silver (Ag) nanoparticles were synthesized on the surface of the prepared ZnO nanorod thin films using electrochemical methods. The scanning electron microscopy images of the Ag/ZnO/glass core/shell nanostructure confirmed that the average particles size is 20 nm while it was 41 nm for Ag NPs that synthesized onto ZnO/FTO NRs. The photocatalytic activity of the prepared Ag/ZnO core/shell nanostructure was studied by analyzing the degradation of methylene blue (MB) dye under visible light. Various pH values (6 and 10) and exposure time (30-240) min were controlled to investigate the photocatalytic activity of as-prepared Ag/ZnO core/shell nanostructure and that annealed at 200 °C and 300 °C for 1 h. It was observed that when the pH was 6, the degradation rate increased with the annealing temperature and irradiation time reaching 51% at the annealing temperature of 300 °C and exposure time of 240 min. In other hands, when the pH was 10, and the sample was annealed at 200 °C, it showed a good degradation rate of 100% at the irradiation time of 90 min. By contrast, the sample annealed at 300 °C required 180 min to degrade the MB dye completely. The photoelectrochemical cell measurement based on photocurrent density revealed a slight response to light. Cycle voltammetry (CV) measurement was conducted, and the CV curves of the Ag/ZnO core/shell electrodes indicated nonfaradaic and pseudocapacitance behavior. The electrodes showed nearly rectangular CV curves, which indicated the dominance of the nonfaradaic capacitance behavior. The specific capacitance of the electrodes remained at approximately 99%. Mott-Schottky analysis revealed that the semiconductor was an n-type with dependence on flat band potential V FB deviation in the negative direction.

Phase-mismatch dependence of the four-wave mixing effect in semiconductor optical amplifiers.

The phase-mismatch effect due to polarization-dependent mode confinement factor has been shown to be not a crucial problem in semiconductor optical amplifiers (SOAs) and is usually not accounted for. The phase-mismatch four-wave mixing (FWM) process in SOA devices is experimentally reported. The results reveal a sinc-like behavior in the intensity of FWM conjugate as a function of wavelength separation between transverse electric (TE)/transverse magnetic (TM) pumps due to induced confinement factors difference. Efficient FWM occurred for a detuning shift of about 500 GHz, limited by phase-mismatch conditions and determined by coherence length required for low and high frequencies to complete a full phase-match cycle. Phase-match FWM with an infinity coherence length can be fulfilled by proper alignments of co-polarized TE/TM modes of input waves with respect to the birefringent axes of the device structure.

Wide-uniform triple Brillouin frequency spacing multi-wavelength fiber laser assisted by a distributed Raman amplifier.

In this paper, we demonstrate a wide-uniform and hybrid multi-wavelength fiber laser source with triple Brillouin-shift wavelength spacing. The hybrid gains include the combination of erbium-ytterbium-doped fiber and distributed Raman amplifiers. For optimum performances, the Brillouin pump wavelength is set at 1532 nm with power at -20 dBm, erbium-ytterbium-doped fiber amplifier at 950 mW and Raman pump power at 900 mW. The highest channel count is obtained in this kind of laser design, where around 164 Stokes lines are produced within 10 dB spectral flatness. The corresponding bandwidth is 40 nm, where the average optical signal-to-noise ratio is maintained at 36 dB estimation. The outstanding total power stability indicates 0.74 dB fluctuation over a 45-minute duration. This merits the practicality for various applications especially in optical communication system and sensing. Furthermore, a reasonable wide tuning range of 36 nm is realized, beginning from 1532 nm, which is only restricted by the accessible hybrid gain bandwidth.

Enhanced flatness of 20 GHz channel spacing multiwavelength Brillouin-Raman fiber laser with sub-millimeter air gap.

We discover the technique of controlling the flatness in signal amplitude of a multiwavelength Brillouin-Raman fiber laser by employing an air-gap outside of the cavity. The structure that is adjustable within sub-millimeter length behaves as flexible optical feedback that provides modifiable portions of multiple Fresnel reflectivities. This is the main benchmark that allows the efficient management of gain competition between self-lasing modes and Brillouin Stokes waves that is vital for self-flattening initiation. When setting the Brillouin pump wavelength at 1529 nm and the air-gap distance to 0.4 mm, 296 Stokes lines are produced with a channel spacing of 0.158 nm. The lasing bandwidth is 46.60 nm that covers from 1529.16 to 1575.76 nm wavelength. In this case at Raman power of 950 mW, the intense Brillouin pump power of 2 dBm saturates the cascaded higher-orders lasing lines. As a result, the overall peak power discrepancy is maintained at just 1.8 dB where an average optical-signal-to-noise ratio of 20 dB is realized. To date, this is the widest bandwidth with the flattest spectrum attained in multiwavelength fiber lasers that incorporate a single Raman pump unit.

Pump distribution effect in dual-wavelength Raman-erbium random distributed feedback fiber laser.

This work demonstrates a simple dual-wavelength random distributed feedback fiber laser via excitation of the Raman-erbium hybrid gain by a single pump source. Lasing wavelengths at 1568 nm and 1595 nm with 48.48 dBm maximum OSNR were generated without the need for physical reflectors. Enhancements were performed using pump power distribution and a seeded feedback to reduce the peak disparity to only 0.16 dB. The long cavity hybrid random laser with its balanced and broadly spaced dual-wavelength output offers immense potential for long distance dual laser applications.

Dual-wavelength, mode-locked erbium-doped fiber laser employing a graphene/polymethyl-methacrylate saturable absorber.

Mode-locked fiber laser incorporating a saturable absorber is an attractive configuration due to its stability and simple structure. In this work, we demonstrate a dual-wavelength passively mode-locked erbium-doped fiber laser employing a graphene/polymethyl-methacrylate saturable absorber. A laser resonator is developed based on dual cavity architecture with unidirectional signal oscillation, which is connected by a fiber branch sharing a common gain medium and saturable absorber. Dual wavelength mode-locked fiber lasers are observed at approximately 1530 and 1560 nm with 22.6 mW pump power threshold. Soliton pulse circulates in the laser cavity with pulse duration of 900 and 940 fs at shorter and longer wavelengths, respectively. This work presents a viable option in developing a low threshold mode-locked laser source with closely spaced dual wavelength femtosecond pulses in the C-band wavelength region.

Flat amplitude and wide multiwavelength Brillouin/erbium fiber laser based on Fresnel reflection in a micro-air cavity design.

In this report, we demonstrate a wide multiwavelength Brillouin-erbium fiber laser (MBEFL) with improved flatness that integrates a micro-air cavity. This air-gap introduces a cavity loss to overcome the gain saturation as well as providing efficient pump recycling scheme through Fresnel back-reflection. In addition, the efficient four-wave mixing in the highly nonlinear fiber contributes to the self-flattening of the output spectra. During operation, the optimized pumping values are set at 13 dBm Brillouin power and 600 mW erbium-ytterbium doped fiber amplifier when the air-gap length is fixed at 10 µm. A total of 180 Stokes lines are produced with a channel spacing of 0.08 nm. The flat lasing bandwith is 14 nm that consists of 1557 to 1571 nm wavelengths within 3-dB span. The average optical signal-to-noise ratio is 18 dB, having high peak power of -8 dBm. To our knowledge, this is the best result attained in MBEFLs with respect to the spectral flatness. In fact, the power stability of 0.76 dB order over 45 minute durations merits it applications in optical fiber sensing and communications.

Wide bandwidth and flat multiwavelength Brillouin-erbium fiber laser.

A wide bandwidth and flat multiwavelength Brillouin-erbium fiber laser is demonstrated experimentally. In the proposed laser setup, the combination of a Brillouin mirror with feedback and a ring cavity with four-wave mixing assistance is realized. The efficiency of Brillouin Stokes lines generation is enhanced by the feedback-based Brillouin mirror structure. The effect of four-wave mixing in highly nonlinear fiber increases the generation of Brillouin Stokes lines in a wider bandwidth. The laser lines over 16 nm bandwidth (i.e 200 channels) within 4.65 dB power difference are obtained. The generated laser lines span from 1534 to 1550 nm with wavelength spacing of 0.08 nm and optical signal-to-noise ratio of at least 15 dB. The laser can also be freely tuned over 32 nm and is stable with power fluctuations of 0.7 dB over 1 hour duration.

Wavelength-tunable single longitudinal mode fiber optical parametric oscillator.

We demonstrate a ring cavity single longitudinal mode fiber optical parametric oscillator using a passive sub-ring cavity and an unpumped erbium doped fiber configured with an external fiber mirror for single mode selection. The unpumped erbium doped fiber uses its saturable absorption characteristic to generate a self-induced narrowband filter when two counter-propagating waves interfere inside the fiber. A single longitudinal mode laser is obtained with a linewidth of 17.35 kHz at a pump power of 31.2 dBm. A 3.8 nm tuning range from 1536.5 nm to 1540.3 nm is achieved with a signal-to-noise ratio of about 60 dB. The power stability of the single longitudinal mode laser is 2.07 dB over a period of 30 minutes.

Modified plastic optical fiber with CNT and graphene oxide nanostructured coatings for ethanol liquid sensing.

A high sensitivity and simple ethanol sensor based on an un-cladded multimode plastic optical fiber (UCPOF) coated with carbon nanotubes (CNTs) for the detection of different concentrations of ethanol in de-ionized water is developed and demonstrated. The UCPOF probe is fabricated by chemically removing the fiber cladding and integrated with CNT as a sensing layer. The effect of surface morphology on the sensor performance is investigated by characterizing another UCPOF coated with GO nanomaterial. The developed fibers are coated with CNTs and GO using drop casting technique. Energy dispersive X-ray spectroscopy (EDX), atomic-force microscopy (AFM) and scanning electron microscope (SEM) are used to investigate the element and morphology of the synthesized nanomaterials. The experimental results indicated that the absorbance spectrum of the CNT-based UCPOF sensor increases linearly with a higher sensitivity of 0.68/vol% and magnitude change of 95.4% as compared to 0.19/vol% and 56.3%, respectively, for the GO-based sensor. The UCPOF coated with CNT exhibits faster response and recovery than that of GO. The sensor shows high selectivity to ethanol amongst a range of diluted organic VOCs. The superior sensing performance of the developed fiber sensor indicates its high efficiency for ethanol detection in various industrial applications.

Comparison in the quality of distractors in three and four options type of multiple choice questions.

INTRODUCTION: The number of distractors needed for high quality multiple choice questions (MCQs) will be determined by many factors. These include firstly whether English language is their mother tongue or a foreign language; secondly whether the instructors who construct the questions are experts or not; thirdly the time spent on constructing the options is also an important factor. It has been observed by Tarrant et al that more time is often spent on constructing questions than on tailoring sound, reliable, and valid distractors. OBJECTIVES: Firstly, to investigate the effects of reducing the number of options on psychometric properties of the item. Secondly, to determine the frequency of functioning distractors among three or four options in the MCQs examination of the dermatology course in University of Bahri, College of Medicine. MATERIALS AND METHODS: This is an experimental study which was performed by means of a dermatology exam, MCQs type. Forty MCQs, with one correct answer for each question were constructed. Two sets of this exam paper were prepared: in the first one, four options were given, including one key answer and three distractors. In the second set, one of the three distractors was deleted randomly, and the sequence of the questions was kept in the same order. Any distracter chosen by less than 5% of the students was regarded as non-functioning. Kuder-Richardson Formula 20 (Kr-20) measures the internal consistency and reliability of an examination with an acceptable range 0.8-1.0. Chi square test was used to compare the distractors in the two exams. RESULTS: A significant difference was observed in discrimination and difficulty indexes for both sets of MCQs. More distractors were non-functional for set one (of four options), but slightly more reliable. The reliability (Kr-20) was slightly higher for set one (of four options). The average marks in option three and four were 34.163 and 33.140, respectively. CONCLUSION: Compared to set 1 (four options), set 2 (of three options) was more discriminating and associated with low difficulty index but its reliability was low.

Effects of Raman pump power distribution on output spectrum in a multi-wavelength BRFL: publisher's note.

This publisher's note amends the author list and Acknowledgments of a recent publication [Opt. Express23, 25570 (2015)].

Effects of Raman pump power distribution on output spectrum in a multi-wavelength BRFL.

This paper aims to investigate changes in multi-wavelength Brillouin-Raman fiber laser (MBRFL) spectra characteristics that are influenced by variation of Raman pump power distribution along the two fiber-entry points. This is carried out by incorporating a Raman pump source with a set of couplers with various ratios. In this arrangement, the optimization of pumping ratio is properly carried out to achieve high number of lasing lines with 20 GHz spacing which yield the highest peak power discrepancy between odd- and even-order lasing lines and an excellent Stokes optical signal-to-noise ratio (S-OSNR). Employment of 50/50 coupler offers 212 flat amplitude channels with an average 27.5 dB S-OSNR and -10 dBm Stokes peak power when the Brillouin pump wavelength is set at 1543 nm. Achievements such flat and wide bandwidth MBRFL spectrum with 20 GHz spacing and excellent S-OSNR utilizing just a single pump source is significant in terms of simplicity and flexibility.

Room temperature ammonia sensing using tapered multimode fiber coated with polyaniline nanofibers.

We demonstrate an ammonia sensor composed of a tapered multimode fiber coated with polyaniline nanofibers that operates at room temperature (26°C). The optical properties of the polyaniline layer changes when it is exposed to ammonia, leading to a change in the absorption of evanescent field. The fiber sensor was tested by exposing it to ammonia at different concentrations and the absorbance is measured using a spectrophotometer system. Measured response and recovery times are about 2.27 minutes and 9.73 minutes, respectively. The sensor sensitivity can be controlled by adjusting the tapered fiber diameter and the highest sensitivity is achieved when the diameter is reduced to 20 µm.

Extended nonlinear parametric process in anomalously pumped linear cavity oscillator.

We demonstrate a linear cavity fiber optical parametric oscillator with extended pump-signal separation of 14.3 THz (116 nm). The signal laser is provided by a pair of 1675nm fiber Bragg gratings and a tunable idler from 1456.12 nm to 1462.48 nm is generated by detuning the pump wavelength in the anomalous dispersion regime of a highly nonlinear fiber. At such large pump-signal separation, we are still able to record a parametric conversion efficiency of more than -35 dB and idler optical signal-to-noise-ratio of 50 dB on average. The stability of the lasing signal and idler is examined and result shows both signal and idler peak power fluctuation is less than 1 dB over a period of 30 minutes.

Single mode tapered fiber-optic interferometer based refractive index sensor and its application to protein sensing.

We demonstrate refractive index sensors based on single mode tapered fiber and its application as a biosensor. We utilize this tapered fiber optic biosensor, operating at 1550 nm, for the detection of protein (gelatin) concentration in water. The sensor is based on the spectroscopy of mode coupling based on core modes-fiber cladding modes excited by the fundamental core mode of an optical fiber when it transitions into tapered regions from untapered regions. The changes are determined from the wavelength shift of the transmission spectrum. The proposed fiber sensor has sensitivity of refractive index around 1500 nm/RIU and for protein concentration detection, its highest sensitivity is 2.42141 nm/%W/V.

Brillouin slow light: substantial optical delay in the second-order Brillouin gain spectrum.

We experimentally demonstrate optical delay in the second-order Brillouin gain spectrum by incorporating a double Brillouin-frequency shifter into the system. By coinciding the seed signal with the second-order Brillouin gain spectrum, it was found that the seed signal experienced significantly larger delay as compared to the Brillouin slow light generated from the first-order Brillouin spectrum. At a Brillouin gain of 17 dB, the delay was found to be at maximum of 60 ns. This widens the window of promising opportunities into the deployment of all optical tunable delay into the existing optical signal processing.

20 GHz spacing multi-wavelength generation of Brillouin-Raman fiber laser in a hybrid linear cavity.

We demonstrate a tunable multi-wavelength Brillouin-Raman fiber laser with 20 GHz wavelength spacing. The setup is arranged in a linear cavity by employing 7.2 and 11 km dispersion compensating fibers (DCF) in addition to a 30 cm Bismuth-oxide erbium doped fiber. In this experiment, for the purpose of increasing the Stokes lines, it is necessary to optimize Raman pump power and Brillouin pump power together with its corresponding wavelengths. At the specific Brillouin pump wavelength, it is found that the longer length of 11 km DCF with optimized parameters results in larger number of Stokes combs and optical signal to noise ratios (OSNRs). In this case, a total of 195 Brillouin Stokes combs are produced across 28 nm bandwidth at Brillouin pump power of -2 dBm and Raman pump power of 1000 mW. In addition, all Brillouin Stokes signals exhibit an average OSNR of 26 dB.

Synthesis, spectroscopic studies, molecular modeling and antimicrobial activity of binuclear Co(II) and Cu(II) complexes of 4,6-diacetylresorcinol.

Reactions of 4,6-diacetylresorcinol with different cobalt(II) and copper(II) salts viz., OAc(-), Cl(-), NO3(-) and SO4(2-), yielded a new series of binuclear metal complexes. Reactions of the ligand with these metal ions in the presence of a secondary ligand (L') [O,O-donor; acetylacetone, N,O-donor; 8-hydroxyquinoline or N,N-donor; 1,10-phenanthroline and N,N,N',N'-tetramethylethylenediamine] in 1:2:2 (L:M:L') molar ratio yielded mixed-ligand complexes with different molar ratios. The metal complexes were characterized by elemental and thermal analyses, IR, electronic, ESR and mass spectra as well as conductivity and magnetic susceptibility measurements. The analytical and spectroscopic data suggested that the H2L ligand behaves as a neutral, monobasic or dibasic tetradentate ligand, depending on the type of the anion and secondary ligand used, through the two phenolic and two carbonyl groups. Electronic spectra, magnetic and conductivity measurements showed that all complexes are octahedral with non-electrolytic nature. The profile of ESR spectra of copper(II) complexes suggested the octahedral geometry and the spin Hamiltonian parameters of the complexes were calculated and discussed. Molecular orbital calculations were performed for metal complexes using Hyperchem 7.52 program on the bases of PM3 level and the results correlated with the experimental data. The free ligand and some of its metal complexes showed antimicrobial activity towards some of Gram-positive and Gram-negative bacteria, yeast (Candida albicans) and fungus (Aspergillus fumigatus).