Wetting Transparency of Single-Layer Graphene on Liquid Substrates.

Graphene's wetting transparency offers promising avenues for creating multifunctional devices by allowing real-time wettability control on liquid substrates via the flow of different liquids beneath graphene. Despite its potential, direct measurement of floating graphene's wettability remains a challenge, hindering the exploration of these applications. The current study develops an experimental methodology to assess the wetting transparency of single-layer graphene (SLG) on liquid substrates. By employing contact angle measurements and Neumann's Triangle model, the challenge of evaluating the wettability of floating free-suspended single-layer graphene is addressed. The research reveals that for successful contact angle measurements, the testing and substrate liquids must be immiscible. Using diiodomethane as the testing liquid and ammonium persulfate solution as liquid substrate, the study demonstrates the near-complete wetting transparency of graphene. Furthermore, it successfully showcases the feasibility of real-time wettability control using graphene on liquid substrates. This work not only advances the understanding of graphene's interaction with liquid interfaces but also suggests a new avenue for the development of multifunctional materials and devices by exploiting the unique wetting transparency of graphene.

Characterization of environmental airborne hydrocarbon contaminants by surface-enhanced Raman scattering.

This paper explores the unintentional contamination of Surface-Enhanced Raman Scattering (SERS) substrates by ambient hydrocarbon contaminants and their contribution to SERS spectra. Previous studies have identified amorphous carbon as a potential complicating factor in data analysis in SERS experiments, although its origin has been elusive. Our work showed that ambient hydrocarbon contamination and its decomposition products can be detected by SERS on a gold substrate. We propose that ambient air itself is a source of amorphous carbon contamination on SERS substrates. This understanding is crucial for the correct interpretation of SERS data and highlights the need for careful consideration of potential environmental contaminants in SERS analysis.

Understanding the Intrinsic Water Wettability of Hexagonal Boron Nitride.

The water wettability of hexagonal boron nitride (hBN) has attracted a lot of research interest in the past 15 years. Experimentally, the static water contact angle (WCA) has been widely utilized to characterize the intrinsic water wettability of hBN. In the current study, we have investigated the effect of airborne hydrocarbons and defects on both static and dynamic WCAs of hBN. Our results showed that the static WCA is impacted by defects, which suggests that previously reported static WCAs do not characterize the intrinsic water wettability of hBN since the state-of-the-art hBN samples always have relatively high defect density. Instead, we found that the advancing WCA of freshly exfoliated hBN is not affected by the defects and airborne hydrocarbons. As a result, the advancing WCA on freshly exfoliated hBN, determined to be 79 ± 3°, best represents the intrinsic water wettability of hBN. A qualitative model has been proposed to describe the effect of airborne hydrocarbons and defects on the static and dynamic WCA of hBN, which is well supported by the experimental results. The finding here has important implications for the water wettability of 2D materials.