Post-treatment of high-rate activated sludge effluent via zeolite adsorption and recovery of ammonium-nitrogen as alternative fertilising products.

This study investigates the potential to connect nutrient flows between wastewater treatment and agriculture through a two-stage nitrogen (N) recovery system composed of high-rate activated sludge treatment in contact stabilisation mode (HRAS/CS) and column adsorption with zeolite. The HRAS/CS process removes organic matter and suspended solids in wastewater, leaving N behind in the effluent. The N was successfully recovered with the zeolite column under different scenarios, generating N and K-rich by-products. The regeneration effluent from the zeolite column with KCl contained 60-845 mg NH4+-N/L and 1.6-14.3 g K/L, having potential for use as fertigation water. The N-saturated zeolite contained 1.5-8.4 mg N/g and 14.3-19.3 mg K/g of the product fresh weight and low contaminant content, making it potentially eligible as various fertilising products. Adsorption can thus concentrate N from HRAS/CS effluent and produce by-products with potential agricultural value while meeting chemical oxygen demand and total nitrogen discharge standards.

Polyhydroxyalkanoate (PHA) production via resource recovery from industrial waste streams: A review of techniques and perspectives.

The problem of waste generation in the form of wastewater and solid wastes has caused an urgent, yet persisting, global issue that calls for the development of sustainable treatment and resource recovery technologies. The production of value-added polyhydroxyalkanoates (PHAs) from industrial waste streams has attracted the attention of researchers and process industries because they could replace traditional plastics. PHAs are biopolymers with high degradability, with a variety of applications in the manufacturing sector (e.g. medical equipment, packaging). The aim of this review is to describe the techniques and industrial waste streams that are applied for PHA production. The different enrichment and accumulation techniques that employ mixed microbial communities and carbon recovery from industrial waste streams and various downstream processes were reviewed. PHA yields between 7.6 and 76 wt% were reported for pilot-scale PHA production; while, at the laboratory-scale, yields from PHA accumulation range between 8.6 and 56 wt%. The recent advances in the application of waste streams for PHA production could result in more widely spread PHA production at the industrial scale via its integration into biorefineries for co-generation of PHAs with other added-value products like biohydrogen and biogas.