Enhanced photocatalytic activity of green synthesized zinc oxide nanoparticles using low-cost plant extracts.

Developing stable and highly efficient metal oxide photocatalysts remains a significant challenge in managing organic pollutants. In this study, zinc oxide nanoparticles (ZnO NPs) were successfully synthesized using various plant extracts, pomegranate (P.M), beetroot roots (B.S), and seder, along with a chemical process. The produced ZnO NPs were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), ultraviolet-visible spectroscopy (UV-Vis), Field Emission Scanning Electron Microscope (FESEM), High-Resolution Transmission Electron Microscopy (HRTEM), and Surface Area. For all prepared samples, the results indicated that the composition of the plant extract affects several characteristics of the produced particles, such as their photocatalytic properties, energy bandgap (Eg), particle size, and the ratio of the two intensity (0 0 2) and (1 0 0) crystalline planes. The particle size of the produced NPs varies between 20 and 30 nm. To examine NPs' photocatalytic activity in the presence of UV light, Methyl Orange (MO) was utilized. The Eg of  ZnO synthesized by the chemical method was 3.16 e. V, whereas it was 2.84, 2.63, and 2.59 for P.M, Seder, and B.S extracts, respectively. The most effective ZnO NPs, synthesized using Beetroots, exhibited a degradation efficiency of 87 ± 0.5% with a kinetic rate constant of 0.007 min-1. The ratio of the two intensity (0 0 2) and (1 0 0) crystalline planes was also examined to determine a specific orientation in (0 0 2) that is linked to the production of oxygen vacancies in ZnO, which enhances their photocatalytic efficiency. Furthermore, the increase in photocatalytic effectiveness can be attributed to the improved light absorption by the inter-band gap states and effective charge transfer.

Low-cost photocatalytic membrane modified with green heterojunction TiO2/ZnO nanoparticles prepared from waste.

The combination of photocatalysis and membrane procedures represents a promising approach for water treatment. This study utilized green synthesis methods to produce TiO2 nanoparticles (NPs) using Pomegranate extract and ZnO nanoparticles using Tangerine extract. These nanoparticles were then incorporated into a polyvinyl chloride (PVC) nanocomposite photocatalytic membrane. Different devices were used to examine the properties of nanocomposite membranes. The prepared membranes' morphology was examined using atomic force microscopy (AFM) and field emission scanning electron microscopy (FESEM). The hydrophilicity of the membrane surface was assessed through the measurement of contact angle, while the crystal structure and chemical bonding were analyzed using Raman and Fourier transform infrared spectroscopy (FT-IR). The study also encompassed an examination of the mechanical properties. The hydrophilicity of the modified membrane exhibited a significant improvement. Additionally, there was an observed increase in both the pure water flux and rejection values. The photocatalytic activity of the membrane was found to be enhanced when exposed to sunlight as compared to when kept in the dark. The TiO2/ZnO nanocomposites membrane exhibited the highest level of photocatalytic degradation, achieving a rejection rate of 98.7% compared to the unmodified membrane. Therefore, it was determined that the TiO2/ZnO nanocomposites membrane exhibited superior performance to the other membranes assessed. The potential utility of our research lies in its application within the water treatment industry, specifically as an effective technique for modifying PVC membranes.