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1.
ACS Omega ; 7(42): 38094-38104, 2022 Oct 25.
Artigo em Inglês | MEDLINE | ID: mdl-36312388

RESUMO

In this paper, a terahertz (THz) metamaterial absorber (MTMA), incorporating surface Pythagorean tree fractal resonators, was designed and experimentally fabricated on the flexible substrate of polyethylene terephthalate. The design presented two peaks with strong absorption of more than 97% at 0.49 and 0.69 THz. The dual-band absorption peaks were seen to be shifted with the change in the refractive index of the surrounding medium, with a corresponding sensitivity of 0.0968 and 0.1182 THz/RIU. The spectral shift of the reflection resonance dip was utilized as an assessment index to evaluate the sensing performance of the new structure, and it was found to be 2.08 and 2.98 for the two resonance peaks, respectively. It was observed that the proposed structure acted as an epsilon negative material at the first resonance and as a mu negative material at the second resonance. Further investigations on the electric field, magnetic field, and surface current distributions were carried out to elaborate on the absorption characteristics at various resonance frequencies. The proposed sensor is a highly sensitive MTMA which can be used to investigate the interaction of matter with THz waves.

2.
Materials (Basel) ; 15(18)2022 Sep 13.
Artigo em Inglês | MEDLINE | ID: mdl-36143675

RESUMO

A new design of a triple band perfect metamaterial absorber based on Pythagorean fractal geometry is proposed and analyzed for terahertz sensing applications. The proposed design showed an enhanced sensing performance and achieved three intensive peaks at 33.93, 36.27, and 38.39 THz, corresponding to the absorptivity of 98.5%, 99.3%, and 99.6%, respectively. Due to the symmetrical nature of the recommended design, the structure exhibited the characteristics of independency on the incident wave angles. Furthermore, a parametric study was performed to show the effects of the change in substrate type, resonator material, and substrate thickness on the absorption spectrum. At a fixed analyte thickness (0.5 µm), the resonance frequency of the design was found to be sensitive to the refractive index of the surrounding medium. The proposed design presented three ultra-sensitive responses of 1730, 1590, and 2050 GHz/RIU with the figure of merit (FoM) of 3.20, 1.54, and 4.28, respectively, when the refractive index was changed from 1.0 to 1.4. Additionally, the metamaterial sensor showed a sensitivity of 1230, 2270, and 1580 GHz/µm at the three resonance frequencies, respectively, when it was utilized for the detection of thickness variation at a fixed analyte refractive index (RI) of 1.4. As long as the RI of the biomedical samples is between 1.3 and 1.4, the proposed sensor can be used for biomedical applications.

3.
J Fluoresc ; 32(1): 203-213, 2022 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-34694548

RESUMO

In this work, the optoelectronic parameters of natural dyes extracted from beetroot, red cabbage, walnut leaves, and henna were comprehensively investigated, namely the optical energy gap (Eg), extinction coefficient (k), refractive index (n), dielectric constant ([Formula: see text], and optical conductivity ([Formula: see text]. Results showed a high refractive index, dielectric constant and optical conductivity ([Formula: see text] and [Formula: see text]) for the dye extracted from red cabbage, while minimum values of [Formula: see text] and [Formula: see text] were obtained for the henna dye. The transition type of the optical absorption of the dyes was found to be a direct allowed transition, which is taken place between the bonding and antibonding molecular energy levels. The reported results herein are essential in revealing the viability of these natural dyes for potential applications in organic electronics, including organic photovoltaics, photodiodes, and sensors.


Assuntos
Beta vulgaris/química , Brassica/química , Corantes/isolamento & purificação , Eletrônica/métodos , Juglans/química , Lawsonia (Planta)/química
4.
BMC Chem ; 15(1): 25, 2021 Apr 21.
Artigo em Inglês | MEDLINE | ID: mdl-33883016

RESUMO

BACKGROUND: The design of new polymers able to filter the electromagnetic spectrum and absorb distinctly in the UV and high-energy part of visible spectrum is crucial for the development of semi-transparent solar cells. Herein, we report on the synthesis and spectroscopic, electrochemical, and photophysical characteristics of three new polymers, namely (i) Poly(triamterene-co-terephthalate), (ii) Poly[triamterene-co- 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine-p,p'-disulfonamide], and (iii) Poly(5-hydroxyindole-2-carboxylate) that might show promise as materials for semi-transparent solar cells. RESULTS: The energy band gap, refractive index, dielectric constant, and optical conductivity of the electron donor polymer, poly(triamterene-co-terephthalate), were determined to be 2.92 eV, 1.56, 2.44 and 2.43 × 104 S cm-1, respectively. The synthesized electron acceptor polymers showed a relatively high refractive index, dielectric constant, and optical conductivity. The presence of a direct allowed transition was confirmed between intermolecular energy bands of the polymers. CONCLUSIONS: The polymers showed relatively high energy gap and deep HOMO levels, making them strong absorbers of photons in the UV region and high energy part of the visible region. The synthesized donor and acceptors performed well relative to P3HT and fullerenes due to the close match of the HOMO and LUMO levels. With further development, the polymers could be viable for use as the active layers of semi-transparent solar cells.

5.
PLoS One ; 16(1): e0246039, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-33507983

RESUMO

The selection and classification of genes is essential for the identification of related genes to a specific disease. Developing a user-friendly application with combined statistical rigor and machine learning functionality to help the biomedical researchers and end users is of great importance. In this work, a novel stand-alone application, which is based on graphical user interface (GUI), is developed to perform the full functionality of gene selection and classification in high dimensional datasets. The so-called HDG-select application is validated on eleven high dimensional datasets of the format CSV and GEO soft. The proposed tool uses the efficient algorithm of combined filter-GBPSO-SVM and it was made freely available to users. It was found that the proposed HDG-select outperformed other tools reported in literature and presented a competitive performance, accessibility, and functionality.


Assuntos
Bases de Dados Genéticas , Aprendizado de Máquina , Software , Algoritmos , Perfilação da Expressão Gênica , Humanos , Interface Usuário-Computador
6.
PLoS One ; 15(5): e0232460, 2020.
Artigo em Inglês | MEDLINE | ID: mdl-32392253

RESUMO

In this work, a novel sensor based on printed circuit board (PCB) microstrip rectangular patch antenna is proposed to detect different ratios of ethanol alcohol in wines and isopropyl alcohol in disinfectants. The proposed sensor was designed by finite integration technique (FIT) based high-frequency electromagnetic solver (CST) and was fabricated by Proto Mat E33 machine. To implement the numerical investigations, dielectric properties of the samples were first measured by a dielectric probe kit then uploaded into the simulation program. Results showed a linear shifting in the resonant frequency of the sensor when the dielectric constant of the samples were changed due to different concentrations of ethanol alcohol and isopropyl alcohol. A good agreement was observed between the calculated and measured results, emphasizing the usability of dielectric behavior as an input sensing agent. It was concluded that the proposed sensor is viable for multipurpose chemical sensing applications.


Assuntos
Micro-Ondas , Tecnologia sem Fio/instrumentação , 2-Propanol/química , Desinfetantes/química , Radiação Eletromagnética , Engenharia , Desenho de Equipamento , Etanol/química , Vinho/análise
7.
Sensors (Basel) ; 20(3)2020 Feb 10.
Artigo em Inglês | MEDLINE | ID: mdl-32050710

RESUMO

In this paper, a new metamaterials-based hypersensitized liquid sensor integrating omega-shaped resonator with microstrip transmission line is proposed. Microwave transmission responses to industrial energy-based liquids are investigated intensively from both numerical and experimental point of view. Simulation results concerning three-dimensional electromagnetic fields have shown that the transmission coefficient of the resonator could be monitored by the magnetic coupling between the transmission line and omega resonator. This sensor structure has been examined by methanol-water and ethanol-water mixtures. Moreover, the designed sensor is demonstrated to be very sensitive for identifying clean and waste transformer oils. A linear response characteristic of shifting the resonance frequency upon the increment of chemical contents/concentrations or changing the oil condition is observed. In addition to the high agreement of transmission coefficients (S21) between simulations and experiments, obvious resonant-frequency shift of transmission spectrum is recognized for typical pure chemical liquids (i.e., PEG 300, isopropyl alcohol, PEG1500, ammonia, and water), giving rise to identify the type and concentration of the chemical liquids. The novelty of the work is to utilize Q factor and minimum value of S21 as sensing agent in the proposed structure, which are seen to be well compatible at different frequencies ranging from 1-20 GHz. This metamaterial integrated transmission line-based sensor is considered to be promising candidate for precise detection of fluidics and for applications in the field of medicine and chemistry.

8.
Materials (Basel) ; 13(1)2019 Dec 30.
Artigo em Inglês | MEDLINE | ID: mdl-31905854

RESUMO

A broadband coplanar waveguide (CPW)-fed monopole antenna based on conventional CPW-fed integration with an organic solar cell (OSC) of 100% insolation is suggested for Ku band satellite communication. The proposed configuration was designed to allow for 100% insolation of the OSC, thereby improving the performance of the antenna. The device structure was fabricated using a Leiterplatten-Kopierfrasen (LPKF) prototyping Printed circuit board (PCB) machine, while a vector network analyzer was utilized to measure the return loss. The simulated results demonstrated that the proposed antenna was able to cover an interesting operating frequency band from 11.7 to 12.22 GHz, which is in compliance with the International Telecommunication Union (ITU). Consequently, a 3 GHz broadband in the Ku band was achieved, along with an enhancement in the realized gain of about 6.30 dB. The simulation and experimental results showed good agreement, whereby the proposed structure could be specifically useful for fixed-satellite-services (FSS) operating over the frequency range from the 11.7 to 12.22 GHz (downlink) band.

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