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Chembiochem ; 23(15): e202200168, 2022 08 03.
Artigo em Inglês | MEDLINE | ID: mdl-35675170

RESUMO

We analyzed the effect of modified nucleotides within gapmer antisense oligonucleotides on RNase H mediated gene silencing. Additionally, short hairpins were introduced into antisense oligonucleotides as structural motifs, and their influence on biological and physicochemical properties of pre-structured gapmers was investigated for the first time. The results indicate that two LNA residues in specified positions of the gap flanking regions are sufficient and favorable for efficient knock-down of the ß-actin gene. Furthermore, the introduction of other modified nucleotides, i. e. glycyl-amino-LNA-T, 2'-O-propagyluridine, polyamine functionalized uridine, and UNA, in specified positions, also increases the inhibition of ß-actin expression. Importantly, the presence of hairpins within the gapmers improves their silencing properties.


Assuntos
Actinas , Oligonucleotídeos Antissenso , Expressão Gênica , Nucleotídeos , Oligonucleotídeos Antissenso/química , Ribonuclease H/genética , Ribonuclease H/metabolismo
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