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Inspired by the previous machine-learning study that the number of hydrogen-bonding acceptor (NHBA) is important index for the hole mobility of organic semiconductors, seven dithienobenzothiazole (DBT) derivatives 1a-g (NHBA = 5) were designed and synthesized by one-step functionalization from a common precursor. X-ray single-crystal structural analyses confirmed that the molecular arrangements of 1b (the diethyl and ethylthienyl derivative) and 1c (the di(n-propyl) and n-propylthienyl derivative) in the crystal are classified into brickwork structures with multidirectional intermolecular charge-transfer integrals, as a result of incorporation of multiple hydrogen-bond acceptors. The solution-processed top-gate bottom-contact devices of 1b and 1c had hole mobilities of 0.16 and 0.029 cm2 V-1s-1, respectively.
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The incorporation of tricoordinate boron into conjugated systems is of current interest in the field of organic electronics. In this study, a tricoordinate boron-embedded thiophene-based bistricyclic aromatic ene (BAE) was synthesized as a new boron-containing conjugated system. The combination of tricoordinate boron and fused thiophene rings imposed the twisted conformation in the BAE structure, resulting in the narrow energy absorption with the low-lying LUMO. Preliminary studies on the application of the highly electron-deficient boron-embedded BAE to organic field-effect transistors (OFETs) were also performed, revealing its moderately high electron mobility.
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Electronic transport measurement using modulated photocurrent (MPC) spectroscopy is demonstrated herein in working organic photovoltaics (OPVs) before and after AM1.5G irradiation. OPVs with bulk heterojunction (BHJ) using prototypical donor and acceptor materials, poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1-2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl] = hieno [3-4-b]thiophenediyl]] (PTB7) and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM), were fabricated. The OPVs had inverted structures (BHJs are formed on transparent conductive oxide substrates). The photovoltaic performance of PTB7:PC71BM OPVs was characterized and the best power conversion efficiency was obtained at PTB7 content of 40 wt%. Electron and hole mobility were determined with MPC spectroscopy in PTB7:PC71BM OPVs and were well balanced at PTB7 content of 40 wt%. Degradation of the photovoltaic performance of PTB7:PC71BM OPVs with PTB7 content of 40 wt% caused by AM1.5G irradiation was studied. MPC spectroscopy showed that the well-balanced mobility was not affected by AM1.5G irradiation. The degradation of OPVs was not due to changes in the electronic transport properties, but mainly to the reduced short circuit current (Jsc) and fill factor (FF). The origin of this reduction is discussed.
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Carrier drift mobility is an important physical constant in the charge transport process of organic solar cells (OSCs). Although time-of-flight and space-charge-limited current techniques have been frequently utilized for mobility measurements, the validity of a new method using modulation photocurrent spectroscopy is discussed in this contribution. The advantages of this method are its applicability to working OSCs with optimized device structures and the simultaneous determination of the electron and hole mobilities. These features make it possible to study the relation between the mobility balance and the solar cell characteristics, such as the power conversion efficiency, using only a single working OSC; hence, it is not necessary to fabricate electron-only and hole-only devices for mobility measurements. After carrying out numerical simulations to examine the validity of this method for mobility determination, the dependence of the mobility balance on the mixing ratio of the electron-donor and -acceptor materials is presented.
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Solvent-based deposition techniques for fabrication of organic field-effect transistors (OFETs) generally require orthogonal solvents for deposition of a conjugated polymer layer on a polymer gate insulator layer. Here, we found significantly reduced dissolution rate of the polymeric film in the same solvent after casting a homegeneous polymerization solution of para-bis(3-aminopropyl)hexaisobutyl-substituted T8 cage (1) with terephthalaldehyde. The limited dissolution rate in the solvent provided enough chance for fabrication of a regioregular poly(3-hexylthiophene-2,5-diyl) (P3HT) layer on the present polymer films without using an orthogonal solvent. The rheological properties indicate that physical interaction between the polymer chains provides the significantly reduced dissolution rate after the deposition onto a substrate without any cross-linking treatments.
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Wearable, flexible healthcare devices, which can monitor health data to predict and diagnose disease in advance, benefit society. Toward this future, various flexible and stretchable sensors as well as other components are demonstrated by arranging materials, structures, and processes. Although there are many sensor demonstrations, the fundamental characteristics such as the dependence of a temperature sensor on film thickness and the impact of adhesive for an electrocardiogram (ECG) sensor are yet to be explored in detail. In this study, the effect of film thickness for skin temperature measurements, adhesive force, and reliability of gel-less ECG sensors as well as an integrated real-time demonstration is reported. Depending on the ambient conditions, film thickness strongly affects the precision of skin temperature measurements, resulting in a thin flexible film suitable for a temperature sensor in wearable device applications. Furthermore, by arranging the material composition, stable gel-less sticky ECG electrodes are realized. Finally, real-time simultaneous skin temperature and ECG signal recordings are demonstrated by attaching an optimized device onto a volunteer's chest.
Assuntos
Eletrocardiografia/instrumentação , Temperatura Cutânea/fisiologia , Adesivo Transdérmico , Dispositivos Eletrônicos Vestíveis , Impedância Elétrica , Géis , Nanotubos de Carbono/química , Polietilenotereftalatos/químicaRESUMO
The structural and photoluminescence (PL) properties of thin films of poly(3-hexylthophene) (P3HT) with molecular weights (MWs) of 3000 and 13,300 have been investigated. Although high MW P3HT always self-organizes into one packing structure (form I), low MW P3HT forms two different packing structures (forms I and II) depending on the fabrication conditions. In this work, several fabrication techniques have been examined to obtain form II samples with little inclusion of a form I component. It is found that drop-cast thin films of low MW P3HT (form II) exhibit a PL spectrum that is different from that of form I and does not contain the form I component. The PL spectrum can thus be attributed to form II. The differences in PL properties between forms I and II can be understood in terms of weakened interchain interactions due to the longer interchain distance in form II.
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The standard technique to separately and simultaneously determine the carrier concentration per unit volume (N, cm-3 ) and the mobility (µ) of doped inorganic single crystals is to measure the Hall effect. However, this technique has not been reported for bulk-doped organic single crystals. Here, the Hall effect in bulk-doped single-crystal organic semiconductors is measured. A key feature of this work is the ultraslow co-deposition technique, which reaches as low as 10-9 nm s-1 and enables us to dope homoepitaxial organic single crystals with acceptors at extremely low concentrations of 1 ppm. Both the hole concentration per unit volume (N, cm-3 ) and the Hall mobility (µH ) of bulk-doped rubrene single crystals, which have a band-like nature, are systematically observed. It is found that these rubrene single crystals have (i) a high ionization rate and (ii) scattering effects because of lattice disturbances, which are peculiar to this organic single crystal.
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The photoluminescence properties of a thermally activated delayed fluorescence emitter, 1,2-bis(carbazol-9-yl)-4,5-dicyanobenzene (2CzPN), doped in a host matrix consisting of 1,3-bis(9-carbazolyl)benzene and a polar inert molecule, camphoric anhydride (CA), in various concentrations have been investigated. It is found that the addition of CA stabilizes only the lowest singlet excited state (S1) of 2CzPN without changing the energy level of the lowest triplet excited state (T1), leading to a reduction in the energy gap between S1 and T1. The maximum reduction of energy gap achieved in this work has been determined to be around 65 meV from the shift of the fluorescence spectrum and the temperature dependence of the photoluminescence decay rate.
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Carrier transport in solution-processed organic thin-film transistors (OTFTs) based on dioctylbenzothienobenzothiophene (C8-BTBT) has been investigated in a wide temperature range from 296 to 10 K. The field-effect mobility shows thermally activated behavior whose activation energy becomes smaller with decreasing temperature. The temperature dependence of field-effect mobility found in C8-BTBT is similar to that of others materials: organic semiconducting polymers, amorphous oxide semiconductors and hydrogenated amorphous silicon. These results indicate that hopping transport between isoenergetic localized states becomes dominated in a low temperature regime in these materials.
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We present a simple technique for patterning Au top electrodes in vertical molecular junction devices that have the conductive polymer, poly(3,4-ethylene dioxythiophene)-poly(4-styrene sulfonate) ( PEDOT: PSS), as a contact layer between the self-assembled monolayer and the Au top electrode. In this method, a thermally curable photoresist of SU-8 is used to define the areas where the top electrodes are formed. The hydrophobicity and low surface energy of the cured SU-8 facilitates selective deposition of PEDOT: PSS onto the defined top electrode areas of the device through solution dewetting, and also enables the physical peeling of the Au top electrodes deposited on the SU-8 layers using an adhesion tape. Through this approach, vertical molecular junctions with patterned Au top electrodes can be fabricated without employing the shadow mask evaporation process used in the conventional approach. We processed vertical molecular tunneling devices based on self-assembled alkanedithiol monolayers with an active area of 100 µm2.
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An analytical expression for impedance spectra in the case of double injection (both electrons and holes are injected into an organic semiconductor thin film) has been derived from the basic transport equations (the current density equation, the continuity equation and the Possion's equation). Capacitance-frequency characteristics calculated from the analytical expression have been examined at different recombination constants and different values of mobility balance defined by a ratio of electron mobility to hole mobility. Negative capacitance appears when the recombination constant is lower than the Langevin recombination constant and when the value of the mobility balance approaches unity. These results are consistent with the numerical results obtained by a device simulator (Atlas, Silvaco).
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The power conversion efficiencies (PCEs) as a function of band gap energies and the lowest unoccupied molecular orbital (LUMO) levels of donor materials are studied in bulk-heterojunction organic solar cells (OSCs) fabricated from donor materials and fullerene acceptors. The PCEs of [6,6]-pheynl-C61-butyric acid methyl ester (PC61BM) and [6,6]-pheynl-C71-butyric acid methyl ester (PC71 BM) based OSCs blended with donor materials under the Air Mass 1.5 (AM1.5) spectrum are calculated. In the calculation, the short circuit current densities are determined by band gap energies of donor materials and the open circuit voltages are derived from the difference between the highest occupied molecular orbital (HOMO) levels of donor materials and LUMO levels of PC61BM and PC71 BM. The calculation is in good agreement with the experiments. The PCEs under a fluorescent lamp are also calculated. The calculated PCEs of PC71 BM based OSCs under a fluorescent lamp are higher than those under the AM1.5 spectrum by a factor of 2. The PCEs of thieno [3,4-b] thiophene and benzodithiophene (PTB7):PC71BM based OSCs are studied under the AM1.5 spectrum and a fluorescent lamp spectrum and are consistent with the calculation.
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The degradation of bilayer organic light-emitting diodes (OLEDs) with a device structure of N,N'-di(1-naphthyl)-N,N'-diphenylbenzidine (α-NPD) (hole transport layer) and tris-(8-hydroxyquinolate)aluminum (Alq3) (emissive layer and electron transport layer) has been studied by impedance spectroscopy and device simulation. Two modulus peaks are found in the modulus spectra of the OLEDs below the electroluminescence threshold. After aging of the OLEDs, the intensity of electroluminescence is degraded and the modulus peak due to the Alq3 layer is shifted to lower frequency, indicating that the resistance of the Alq3 layer is increased. Device simulation reveals that the increase in the resistance of the Alq3 layer is due to the decrease in the electron mobility in the Alq3 layer.
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A new conjugated donor-acceptor (D-A) polymer pDSBT2-BT containing bi(disilano-bisthiophene) and benzothiadiazole as donor and acceptor units, respectively, was prepared. The polymer showed a broad UV-vis absorption band at λmax = 599 nm in chlorobenzene. The absorption band was shifted to λmax = 629 nm when the polymer was measured as a film, indicating enhanced interchain interactions of the polymer. Bulk hetero-junction polymer solar cells (BHJ-PSCs) were fabricated using pDSBT2-BT and PC71BM as host and guest materials, respectively. Optimization of cell fabrication conditions provided a maximal power conversion efficiency of 3.3% and the following cell parameters: Voc = 0.86 V, Jsc = 7.56 mA/cm², and FF = 0.51. Although the efficiency still leaves much to be desired, these data underscore the potential of pDSBT2-BT as a high-voltage polymer solar cell material.
Assuntos
Polímeros/síntese química , Energia Solar , Tiadiazóis/síntese química , Tiofenos/síntese química , Fontes de Energia Elétrica , Estrutura Molecular , Polímeros/química , Luz Solar , Tiadiazóis/química , Tiofenos/químicaRESUMO
Chemical modification of graphene quantum dots (GQDs) can influence their physical and chemical properties; hence, the investigation of the effect of organic functional groups on GQDs is of importance for developing GQD-organic hybrid materials. Three peripherally functionalised GQDs having a third-generation dendritic wedge (GQD-2), long alkyl chains (GQD-3) and a polyhedral oligomeric silsesquioxane group (GQD-4) were prepared by the Cu(I) -catalysed Huisgen cycloaddition reaction of GQD-1 with organic azides. Cyclic voltammetry indicated that reduction occurred on the surfaces of GQD-1-4 and on the five-membered imide rings at the periphery, and this suggested that the functional groups distort the periphery by steric interactions between neighbouring functional groups. The HOMO-LUMO bandgaps of GQD-1-4 were estimated to be approximately 2â eV, and their low-lying LUMO levels (<-3.9â eV) were lower than that of phenyl-C61 -butyric acid methyl ester, an n-type organic semiconductor. The solubility of GQD-1-4 in organic solvents depends on the functional groups present. The functional groups likely cover the surfaces and periphery of the GQDs, and thus increase their affinity for solvent and avoid precipitation. Similar to GQD-2, both GQD-3 and GQD-4 emitted white light upon excitation at 360â nm. Size-exclusion chromatography demonstrated that white-light emission originates from the coexistence of differently sized GQDs that have different photoluminescence emission wavelengths.
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The p-type organic semiconductor (OSC) material tetrathieno[2,3-a:3',2'-c:2â³,3â³-f:3â´,2â´-h]naphthalene (2TTN) and its alkyl-substituted derivatives C(n)-2TTNs (n = 6, 8, and 10) have been developed based on the results of theoretical calculation-inspired investigation. A hole mobility for amorphous C(n)-2TTNs (10(-2)-10(-3) cm(2) V(-1) s(-1)) was accurately predicted by using a novel statistical method in which the geometric mean of the mobilities for many individual small molecular flocks in an amorphous solid was obtained by using molecular mechanical molecular dynamics simulations and quantum chemical calculations. The simulation also suggests that upon increasing the length of alkyl chains in C(n)-2TTNs the mobilities become smaller as a consequence of a decrease in transfer integral values. C(n)-2TTNs are synthesized in a microflow reactor through photoreactions of the corresponding precursors. C(n)-2TTNs are then utilized in the fabrication of organic field-effect transistors (OFETs). Although spin-coated thin films of C(n)-2TTNs are crystalline, the hole mobilities (10(-2)-10(-3) cm(2) V(-1) s(-1)) of trial OFETs decrease upon elongation of the alkyl chains. This finding parallels the results of theoretical simulation. The simulation method for amorphous solids developed in this effort should become a useful tool in studies aimed at designing new OSC materials.
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Luminescent thin films composed of thermostable lanthanide coordination polymers on glass electrodes were prepared using a novel combination of micelle reactions and electrochemical deposition techniques. The micelle-encapsulated luminescent polymers were obtained by the polymerization of [Eu(hfa)3 ] (hfa=hexafluoroacetylacetonate) with bridging phosphine oxide ligands in micelles using a redox-active ferrocenyl-containing surfactant in water. Films were electrochemically deposited on indium tin oxide coated glass electrodes by potentiostatic polarization of micelle-encapsulated EuIII coordination polymers. The luminescence properties of the electrochemically deposited films were characterized by measuring their emission spectra, emission lifetimes and emission quantum yields.
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A soluble precursor of dinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thiophene (DNTT) is developed for high-performance printed organic thin-film transistors (OTFTs). The DNTT precursor enables excellent thin-film formation and can induce specific phase separations when blended with inert polymers. The DNTT OTFTs processed from the precursor/polymer blend exhibit field-effect mobilities of up to 1.1 cm(2) V(-1) s(-1) and excellent durability against air exposure and thermal stress.
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The aim of this study was to clarify the influence of shear modulus on the analytical accuracy in peri-implant jaw bone simulation. A 3D finite element (FE) model was prepared based on micro-CT data obtained from images of a jawbone containing implants. A precise model that closely reproduced the trabecular architecture, and equivalent models that gave shear modulus values taking the trabecular architecture into account, were prepared. Displacement norms during loading were calculated, and the displacement error was evaluated. The model that gave shear modulus values taking the trabecular architecture into account showed an analytical error of around 10-20% in the cancellous bone region, while in the model that used incorrect shear modulus, the analytical error exceeded 40% in certain regions. The shear modulus should be evaluated precisely in addition to the Young modulus when considering the mechanics of peri-implant trabecular bone structure.