Schrödinger's red pixel by quasi-bound-states-in-the-continuum.

While structural colors are ubiquitous in nature, saturated reds are mysteriously absent. This long-standing problem of achieving Schrödinger's red demands sharp transitions from "stopband" to a high-reflectance "passband" with total suppression of higher-order resonances at blue/green wavelengths. Current approaches based on nanoantennas are insufficient to satisfy all conditions simultaneously. Here, we designed Si nanoantennas to support two partially overlapping quasi-bound-states-in-the-continuum modes with a gradient descent algorithm to achieve sharp spectral edges at red wavelengths. Meanwhile, high-order modes at blue/green wavelengths are suppressed via engineering the substrate-induced diffraction channels and the absorption of amorphous Si. This design produces possibly the most saturated and brightest reds with ~80% reflectance, exceeding the red vertex in sRGB and even the cadmium red pigment. Its nature of being sensitive to polarization and illumination angle could be potentially used for information encryption, and this proposed paradigm could be generalized to other Schrödinger's color pixels.

Reversible Tuning of Mie Resonances in the Visible Spectrum.

Dielectric optical nanoantennas are promising as fundamental building blocks in next generation color displays, metasurface holograms, and wavefront shaping optical devices. Due to the high refractive index of the nanoantenna material, they support geometry-dependent Mie resonances in the visible spectrum. Although phase change materials, such as the germanium-antimony-tellurium alloys, and post-transition metal oxides, such as ITO, have been used to tune antennas in the near-infrared spectrum, reversibly tuning the response of dielectric antennas in the visible spectrum remains challenging. In this paper, we designed and experimentally demonstrated dielectric nanodisc arrays exhibiting reversible tunability of Mie resonances in the visible spectrum. We achieved tunability by exploiting phase transitions in Sb2S3 nanodiscs. Mie resonances within the nanodisc give rise to structural colors in the reflection mode. Crystallization and laser-induced amorphization of these Sb2S3 resonators allow the colors to be switched back and forth. These tunable Sb2S3 nanoantenna arrays could enable the next generation of high-resolution color displays, holographic displays, and miniature LiDAR systems.

Investigation of SARS-CoV-2 inactivation using UV-C LEDs in public environments via ray-tracing simulation.

This paper proposes an investigating SARS-CoV-2 inactivation on surfaces with UV-C LED irradiation using our in-house-developed ray-tracing simulator. The results are benchmarked with experiments and Zemax OpticStudio commercial software simulation to demonstrate our simulator's easy accessibility and high reliability. The tool can input the radiant profile of the flexible LED source and accurately yield the irradiance distribution emitted from an LED-based system in 3D environments. The UV-C operating space can be divided into the safe, buffer, and germicidal zones for setting up a UV-C LED system. Based on the published measurement data, the level of SARS-CoV-2 inactivation has been defined as a function of UV-C irradiation. A realistic case of public space, i.e., a food court in Singapore, has been numerically investigated to demonstrate the relative impact of environmental UV-C attenuation on the SARS-CoV-2 inactivation. We optimise a specific UV-C LED germicidal system and its corresponding exposure time according to the simulation results. These ray-tracing-based simulations provide a useful guideline for safe deployment and efficient design for germicidal UV-C LED technology.

Multiphoton Upconversion Enhanced by Deep Subwavelength Near-Field Confinement.

Efficient generation of anti-Stokes emission within nanometric volumes enables the design of ultracompact, miniaturized photonic devices for a host of applications. Many subwavelength crystals, such as metal nanoparticles and two-dimensional layered semiconductors, have been coupled with plasmonic nanostructures for augmented anti-Stokes luminescence through multiple-harmonic generation. However, their upconversion process remains inefficient due to their intrinsic low absorption coefficients. Here, we demonstrate on-chip, site-specific integration of lanthanide-activated nanocrystals within gold nanotrenches of sub-25 nm gaps via bottom-up self-assembly. Coupling of upconversion nanoparticles to subwavelength gap-plasmon modes boosts 3.7-fold spontaneous emission rates and enhances upconversion by a factor of 100 000. Numerical investigations reveal that the gap-mode nanocavity confines incident excitation radiation into nanometric photonic hotspots with extremely high field intensity, accelerating multiphoton upconversion processes. The ability to design lateral gap-plasmon modes for enhanced frequency conversion may hold the potential to develop on-chip, background-free molecular sensors and low-threshold upconversion lasers.

Rotation-Selective Moiré Magnification of Structural Color Pattern Arrays.

When a microlens array is aligned and overlaid on an array of patterns with similar periodicity, a highly magnified image of the patterns is observed. This effect, known as moiré magnification, is used to reveal micropatterns that are unresolvable by the naked eye. These patterns are typically limited by print resolution to single color patterns. Here, we demonstrate the potential to selectively reveal more than one set of color patterns. By rotating a microlens array relative to a print containing three overlapping arrays of structural color patterns in 10° steps, each pattern array can be distinctly revealed with minimal crosstalk. This rotation-selective effect of moiré magnification is not seen in conventional microscopy. An advantage is that the moiré images are observable by the naked eye under incoherent illumination. We leverage nanoscale three-dimensional printing by using the two-photon lithography process to produce structural color pattern arrays in a single lithographic step with precisely aligned color pixels. We believe that this work can have applications in precise rotational-alignment tools, covert security documents, and information multiplexing devices.

On the correlation of absorption cross-section with plasmonic color generation.

Through numerical simulations, we investigate the correlation between the absorption cross-section and the color saturation of plasmonic nanostructures of varying density. Understanding this correlation, enables the prediction of an optimal nanostructure separation, or combinations of different nanostructure sizes for plasmonic color printing applications. Here, we use metal-insulator-metal (MIM) aluminum nanostructures that support gap-plasmons. Large absorption cross-sections were observed that exceed twelve times the physical cross-section of the nanostructure disks. We derive a set of equations to determine the optimal separation for a periodic array using the absorption cross-section of an individual structure to realize saturated colors. Using the optimum pitch and enabled by the large absorption cross-sections of our structures, we employ color mixing strategies to realize a wider color gamut. The simulated color gamut exceeds the sRGB gamut for some colors, and includes dark tones. Color mixing using structures with large absorption cross-sections is a practical approach to generate a broad range of colors, in comparison to fabricating structures with continuously varying sizes.