Construction of an S-scheme electron transfer channel in Cu0/CuFe2O4 magnetic plate column reactor for the LEV degradation: New strategy of visible Photo-Fenton system application.

The complicated loading process and easy falling off of powder catalysts still restrict the wide application of Photo-Fenton technology in practical water treatment. In this study, a magnetic fixed film plate column water treatment equipment is designed as a visible Photo-Fenton reactor to remove levofloxacin (LEV). The effect of magnetic force can ensure that the catalyst is firmly fixed, and the multi-level shallow column plate structure achieves full contact and efficient reaction between the catalyst and wastewater. Simultaneously, the Cu0/CuFe2O4 (STCCF) utilizes Cu0 to construct an S-scheme electron transfer channel, which improves the separation efficiency of photo-generated carriers and provides sufficient photo-generated electrons for the reduction of Fe (Ⅲ) and Cu (Ⅱ). The pseudo-first-order reaction kinetic constant k for the degradation of LEV in the visible Photo-Fenton system is 0.0349 min-1, which is 15.9 times that of the photocatalytic system and 4.8 times that of the Fenton system. After continuous operation for 72 h, the magnetic fixed film plate column reactor can still remove more than 90 % of LEV and 82 % of COD in the secondary effluent of simulated antibiotic pharmaceutical wastewater treatment process, and the effluent is stable and meets the standard. The magnetic fixed film plate column reactor can be used for advanced treatment of antibiotic pharmaceutical wastewater. This study provides a new insight into the application of the Photo-Fenton process.

Enhanced and synergistic catalytic activation by photoexcitation driven S-scheme heterojunction hydrogel interface electric field.

The regulation of heterogeneous material properties to enhance the peroxymonosulfate (PMS) activation to degrade emerging organic pollutants remains a challenge. To solve this problem, we synthesize S-scheme heterojunction PBA/MoS2@chitosan hydrogel to achieve photoexcitation synergistic PMS activation. The constructed heterojunction photoexcited carriers undergo redox conversion with PMS through S-scheme transfer pathway driven by the directional interface electric field. Multiple synergistic pathways greatly enhance the reactive oxygen species generation, leading to a significant increase in doxycycline degradation rate. Meanwhile, the 3D polymer chain spatial structure of chitosan hydrogel is conducive to rapid PMS capture and electron transport in advanced oxidation process, reducing the use of transition metal activator and limiting the leaching of metal ions. There is reason to believe that the synergistic activation of PMS by S-scheme heterojunction regulated by photoexcitation will provide a new perspective for future material design and research on enhancing heterologous catalysis oxidation process.

Construction of composite films using carbon nanodots for blocking ultraviolet light from the Sun.

Carbon nanodots (CNDs) which demonstrate concentration-dependent emission and have a photoluminescence quantum yield of 45% were designed. Transparent CND-containing composite films (CND-films), obtained by combining the CNDs with polyvinyl alcohol in different proportions, were shown to block the UV component of sunlight. Whereas the pure PVA film could not block UV light, the ability of CND-films to block UV light could be adjusted by altering the proportion of CNDs in the film. The larger the proportion of CNDs, the greater the extent of UV blocking. CND-film containing 32 wt% CNDs completely blocked UV light (≤400 nm) from sunlight, without affecting the transmission of visible light (>800 nm). The ability of the CND-films to block the UV component of sunlight was investigated using a commercially available UV-induced color change card, which confirmed that the capacity of the CND-films to block UV light could be adjusted by altering the proportion of CNDs in the film. This study shows that CNDs with concentration-dependent long wavelength emission characteristics can be used as optical barrier units for the preparation of materials to block high-energy short wavelength light.

Seeking eye protection from biomass: Carbon dot-based optical blocking films with adjustable levels of blue light blocking.

The intensity of blue light in white light emitting diodes is typically higher than that of the green and red-light components in screen displays and lighting systems. To reduce the potential harm of in white light emitting diodes to the eyes, in this paper, we have used microcrystalline cellulose to synthesize biomass-based carbon dots (Bio-CD), which not only absorb short wavelength light to produce longer wavelength emissions, but also show concentration-dependent maximum excitation and maximum emission. The Bio-CDs were mixed with polyvinyl alcohol (PVA) to produce optical blocking films (OBF) that preferentially block blue light. OBFs have good transparency and also block blue light effectively. With OBFs containing 9.9% of Bio-CDs, the film blocked 99.6% and 98.6% of 395 nm light and 450 nm light respectively, and also blocked 93.4% and 97%, respectively, of the blue light emitted by computers and mobile phone screens. OBFs containing more than 9.9% Bio-CDs block blue light more than commercially available blue light blocking glasses. By adjusting the amount of Bio-CDs in the OBFs, it is possible to produce films with different degrees of blue light blocking to meet the requirements of different applications.

MOF-derived N-doped ZnO carbon skeleton@hierarchical Bi2MoO6 S-scheme heterojunction for photodegradation of SMX: Mechanism, pathways and DFT calculation.

Semiconductor photocatalytic degradation of pollutants is considered to be one of the promising sustainable energy routes. Nevertheless, it is challenging for photocatalysts to have excellent visible light absorption and suppress photo-generated electron-hole recombination at the same time. Here, we prepared nitrogen-doped ZnO carbon skeleton by directly calcining the metal-organic framework. Then hierarchical Bi2MoO6 nanosheets are grown in situ on its surface to synthesize S-scheme heterojunction. This special 3D layered and oxygen vacancies work together to make photo-generated electrons and holes easier to separate and migrate. Therefore, the pseudo-first-order kinetic constant of N-doped ZnO carbon skeleton@Bi2MoO6 degradation of sulfamethoxazole reaches 0.022 min-1, which is almost 10 times that of ZIF-8 derived ZnO and 27.5 times Bi2MoO6 under visible light irradiation. Meanwhile, the mechanism of driving charge transfer of S-scheme heterojunction, and the photocatalytic degradation pathway of sulfamethoxazole are also analyzed. This work will provide a new way to construct S-scheme heterojunction photocatalyst to degrade antibiotic pollutants.

Comparative study on bisphenols oxidation via TiO2 photocatalytic activation of peroxymonosulfate: Effectiveness, mechanism and pathways.

In this work, degradation of bisphenol F (BPF), bisphenol AF (BPAF) and bisphenol S (BPS) by peroxymonosulfate (PMS) with TiO2 nano-tubes arrays (TiO2NTAs) under simulated sunlight irradiation was investigated and compared for the first time. All three bisphenols exhibited appreciable degradation following the order of BPS < BPAF < BPF, and acidic conditions were more conducive to their degradation. The SO4•-, ·OH, h+ and •O2- were all identified in three bisphenols degradation processes. Among these, SO4•- and •O2- were proven to play a dominant role in BPF oxidation process, but SO4•- and h+ were confirmed as the main reactive species for BPAF and BPS removal. Owing to the different reactive species worked in different bisphenols degradation processes, the influences of inorganic anions on three bisphenols degradation were also different. By analyzing the oxidation intermediates of the three bisphenols, it was found that there were some common degradation pathways including bond-cleavage and hydroxylation of the benzene ring shared by three bisphenols. Besides, some specific degradation pathways were also identified, for example, the self-coupling was found in BPF and BPS degradation process, while the benzene ring splitting was occurred only in BPAF transformation process.

Oxygen vacancy-mediated sandwich-structural TiO2-x /ultrathin g-C3N4/TiO2-x direct Z-scheme heterojunction visible-light-driven photocatalyst for efficient removal of high toxic tetracycline antibiotics.

A surface defect sandwich-structural TiO2-x/ultrathin g-C3N4/TiO2-x direct Z-scheme heterojunction photocatalyst is successfully constructed. The results manifest the existence of oxygen vacancies, sandwich structure and direct Z-scheme heterojunction. Noticeably, TiO2-x/ultrathin g-C3N4/TiO2-x efficiently eliminates high toxic tetracycline hydrochloride by means of·O2-, h+ and·OH, whose removal rate is 87.7% during 90 min and the pseudo-first-order rate constant reaches up to 31.7 min-1 × 10-3. The extraordinary performance can be attributed to the special 3D structure, Z-scheme heterojunction expediting charge transfer and promoting the generation of active species, meanwhile the oxygen vacancies enhancing the spatial separation of photo-induced carriers. Moreover, various environmental factors are systematically explored by statistics. SO42-, NH3-N and pH exhibit an obvious impact on removal rate. Meanwhile, TiO2-x/ultrathin g-C3N4/TiO2-x could also effectually remove tetracycline hydrochloride from complex actual-wastewater and exhibit high stability. Besides, the photocatalytic mechanism and degradation path of tetracycline hydrochloride are also elucidated.

Biomass-Based Polymer Nanoparticles With Aggregation-Induced Fluorescence Emission for Cell Imaging and Detection of Fe3+ Ions.

Polymeric nanoparticles, which show aggregation-induced luminescence emission, have been successfully prepared from larch bark, a natural renewable biomass resource, in a simple, rapid ultrasonic fragmentation method. The structure, element, particle size and molecular weight distribution of larch bark extracts (LBE) were studied by FTIR, XPS, TEM, XRD and linear mode mass spectrometry, respectively. LBE was found containing large numbers of aromatic rings, displaying an average particle size of about 4.5 nm and mainly presenting tetramers proanthocyanidins. High concentration, poor solvent, low temperature and high viscosity restricted the rotation and vibration of the aromatic rings in LBE, leading to the formation of J-aggregates and enhancing the aggregation-induced fluorescence emission. LBE possessed good resistance to photobleaching under ultraviolet light (200 mW/m2). Cytotoxicity experiments for 24 h and flow cytometry experiments for 3 days proved that even the concentrations of LBE as high as 1 mg/mL displayed non-toxic to MG-63 cells. Therefore, LBE could be employed for MG-63 cell imaging, with similar nuclear staining to the DAPI. The effects of different metal ions on the fluorescence emission intensity of LBE were analyzed and exhibited that Fe3+ owned obvious fluorescence quenching effect on LBE, while other metal ions possessed little or weak effect. Furthermore, the limit of detection (LOD) of Fe3+ was evaluated as 0.17 µM.

Preparation of Biomass-Based Carbon Dots with Aggregation Luminescence Enhancement from Hydrogenated Rosin for Biological Imaging and Detection of Fe3.

Fluorescent carbon dots (CDs) have numerous important applications, but enhancing the fluorescence emission and overcoming fluorescence quenching are still big challenges. Here, fluorescence-enhanced carbon dots (named hr-CDs) were prepared from sustainable hydrogenated rosin, using a simple hydrothermal method in a water solvent. The hr-CDs were mainly composed of graphitized carbon cores with surface functional groups. With the increase in the concentration to hr-CDs aqueous solutions, the distance between the carbon cores decreased, which resulted in the formation of J aggregates and the enhanced blue fluorescence emission. Even in the solid state, the hr-CDs show fluorescence emission because the surface functional groups could prevent π-π stacking interactions between the carbon cores. The hr-CDs show excellent resistance to photobleaching under intense ultraviolet light (200 mW/cm2). Vibrations and rotations of graphitized carbon core are restricted by low temperature and high viscosity, leading to increased radiative transition and thus increase in fluorescence intensity. The pH value in the range of 3.99-9.87 and anions have little effect on the fluorescence emission of hr-CDs. The fluorescence emission of the hr-CDs was selectively quenched by Fe3+ and can thus be used to detect Fe3+. The hr-CDs also have good biocompatibility and show the same ability in cell nuclear staining as 4',6-diamidino-2-phenylindole (DAPI).