1.
Chem Commun (Camb)
; 46(22): 3985-7, 2010 Jun 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-20407676
RESUMO
Non-oxidative coupling of methane with high selectivity into ethane (>99% among hydrocarbon) in a classical fixed-bed reactor catalysed by SiO(2)-Al(2)O(3) or gamma-Al(2)O(3) supported tungsten hydride is presented. Continuous hydrogen separation, using a Pd-Ag membrane in a fixed-bed reactor, led to methane coupling far beyond the thermodynamic equilibrium conversion.