Heavy metals and PAHs in mussels on the Serbian market and consumer exposure.

The goal of the study was to investigate the concentration of heavy metals and polycyclic aromatic hydrocarbons (PAHs) in 84 samples of mussels, collected from supermarkets and fish markets in Serbia. Lead, cadmium, mercury and arsenic concentrations were determined using an inductive coupled plasma mass spectrometry method. Sixteen PAHs were determined using a gas chromatography-mass spectrometry method. Heavy metals in the mussels were in the range (mg/kg) of 0.01-0.74 for lead, 0.01-0.38 for cadmium, 0.01-0.15 for mercury and 1.12-5.87 for arsenic. Metals and PAHs levels in all analysed samples were under the legal European and Serbian legislation limits. The provisional tolerable intake values were calculated on the base of the obtainable values of heavy metals. Mussels are considered to be safe for human consumption. However, one should take care of the amount and frequency of mussel consumption, primarily due to consumer's cadmium and mercury burden.

Polycyclic aromatic hydrocarbons in traditionally smoked Slavonska kobasica.

The traditional smoking procedure, which is the use of open fire, can lead to the formation of PAHs in sausages. The aim of this paper was to assess the types and concentrations of 16 PAHs in 30 samples of Slavonska kobasica, a traditional smoked sausage. In general, some samples showed high values of anthracene and acenaphthylene. In one sample, acenaphthylene reached the value of 1050 µg/kg and in another 1491 µg/kg anthracene was measured. Cancerogenic benzo(a)pyrene content was little above the maximum limit of 5 µg/kg in four samples, but mainly remained below the limit of quantification. PAH4 (i.c. benzo(a)anthracene, chrysene, benzo(b)fluoranthene and benzo(a)pyrene) were above the maximum limit of 30 µg/kg in three samples. Generally, it can be noted from the results that samples with high PAH4 and benzo(a)pyrene concentrations also have high PAH16 concentrations.

Heavy metals and PAHs in canned fish supplies on the Serbian market.

The aim of this study was to determine the level of heavy metals and polycyclic aromatic hydrocarbons (PAHs) in 57 samples of canned tuna, 25 samples of canned sardines, and 16 samples of canned smoked sprouts, collected from supermarkets in Serbia. Heavy metal levels (lead, cadmium, mercury, arsenic, iron, copper, and zinc) were determined using an inductive coupled plasma mass spectrometry method. Sixteen analysed PAHs were determined using a gas chromatography-mass spectrometry method. The trace elements in canned fish were in the range (mg kg-1) of 0.01-0.28 for lead, 0.003-0.08 for cadmium, 0.007-0.64 for mercury, 0.17-3.73 for arsenic, 3.88-52.2 for iron, 0.2-5.95 for copper, and 1.35-44.5 for zinc. Total PAH levels reached 17.67 µg kg-1 in canned tuna and 15.12 µg kg-1 in sardines, whereas in smoked sprouts it amounted to 57.19 µg kg-1. Some of the samples contained cadmium, arsenic, copper, and benzo(a)pyrene above the limits as set by the European and Serbian legislation.

Organochlorine pesticides in canned tuna and sardines on the Serbian market.

The aim of this study was to determine the level of organochlorine (OC) pesticides in 57 samples of canned tuna and 31 samples of canned sardines in vegetable oil, collected from supermarkets in Serbia. OC pesticides α-HCH, ß-HCH, δ-HCH, dichlorodiphenyltrichloroethane (DDT), DDE, DDD, dielderin, endosulfane I, endosulfane II, endosulan sulfate, endrin, endrin ketone, heptachlor, heptachlor epoxide, lindane, aldrin, metoxichlor, cis-chlordane and trans-chlordane were determined using a GS-MS method. The highest concentrations (µg kg-1, arithmetic means) in canned tuna were for δ-HCH (60.6 ± 97.0) and p, p´-DDT (55.0 ± 25.1), while the corresponding values in canned sardines were for δ-HCH (90.7 ± 102.7) and endosulfane II (78.0 ± 145.9). Mean level for the sum of endosulfans was above the maximum limit in canned sardines (85.0 µg kg-1). Also, dieldrin (39.7 µg kg-1) was measured above the ML.