Environmental Effects on Strength and Failure Strain Distributions of Sheep Wool Fibers.

Sheep wool is an eco-friendly, renewable, and totally recyclable material increasingly used in textiles, filters, insulation, and building materials. Recently, wool fibers have become good alternatives for reinforcement of polymer composites and filaments for 3D printing. Wool fibers are susceptible to environmental degradation that could shorten their lifetime and limit applications. This study reports on the mechanical properties of sheep wool fibers under the impact of humid air and UV irradiation. The results of single fiber tensile tests showed a noticeable gauge length effect on the fibers' strength and failure strain. Long (50 mm) fibers possessed about 40% lower characteristics than short (10 mm) fibers. Environmental aging decreased the elastic modulus and strength of the fibers. Moisture-saturated fibers possessed up to 43% lower characteristics, while UV aging resulted in up to a twofold reduction of the strength. The most severe degradation effect is observed under the coupled influence of UVs and moisture. The two-parameter Weibull distribution was applied for the fiber strength and failure strain statistical assessment. The model well predicted the gauge length effects. Moisture-saturated and UV-aged fibers were characterized by less extensive strength dependences on the fiber length. The strength and failure strain distributions of aged fibers were horizontally shifted to lower values. The results will contribute to be reliable predictions of the environmental durability of sheep wool fibers and will extend their use in technical applications.

Biomarkers, matrices and analytical methods targeting human exposure to chemicals selected for a European human biomonitoring initiative.

The major purpose of human biomonitoring is the mapping and assessment of human exposure to chemicals. The European initiative HBM4EU has prioritized seven substance groups and two metals relevant for human exposure: Phthalates and substitutes (1,2-cyclohexane dicarboxylic acid diisononyl ester, DINCH), bisphenols, per- and polyfluoroalkyl substances (PFASs), halogenated and organophosphorous flame retardants (HFRs and OPFRs), polycyclic aromatic hydrocarbons (PAHs), arylamines, cadmium and chromium. As a first step towards comparable European-wide data, the most suitable biomarkers, human matrices and analytical methods for each substance group or metal were selected from the scientific literature, based on a set of selection criteria. The biomarkers included parent compounds of PFASs and HFRs in serum, of bisphenols and arylamines in urine, metabolites of phthalates, DINCH, OPFRs and PAHs in urine as well as metals in blood and urine, with a preference to measure Cr in erythrocytes representing Cr (VI) exposure. High performance liquid chromatography-tandem mass spectrometry (LC-MS/MS) was the method of choice for bisphenols, PFASs, the HFR hexabromocyclododecane (HBCDD), phenolic HFRs as well as the metabolites of phthalates, DINCH, OPFRs and PAHs in urine. Gas chromatographic (GC) methods were selected for the remaining compounds, e.g. GC-low resolution MS with electron capture negative ionization (ECNI) for HFRs. Both GC-MS and LC-MS/MS were suitable for arylamines. New developments towards increased applications of GC-MS/MS may offer alternatives to GC-MS or LC-MS/MS approaches, e.g. for bisphenols. The metals were best determined by inductively coupled plasma (ICP)-MS, with the particular challenge of avoiding interferences in the Cd determination in urine. The evaluation process revealed research needs towards higher sensitivity and non-invasive sampling as well as a need for more stringent quality assurance/quality control applications and assessments.