Long-term evaluation of activated carbon as an adsorbent for biogas desulfurization.

In this study, granular activated carbon (GAC) was used as an adsorbent for biogas desulfurization. Biogas containing 932-2,350 ppm of H2S was collected from an anaerobic digester to treat the wastewater from a dairy farm with about 200 cows. An adsorption test was performed by introducing the biogas to a column that was packed with approximately 50 L of commercial GAC. The operation ceased if the effluent gas had an H2S concentration of over 100 ppm. The GAC was replaced by a given weight of new GAC in a subsequent test. According to the results, for H2S concentrations in the range of 932-1,560 ppm (average±SD = 1,260 ± 256 ppm), 1 kg of the GAC yielded biogas treatment capacities of 568 ± 112 m3 and H2S adsorption capacities of 979 ± 235 g. For the higher influent H2S concentrations of 2,110 ± 219 ppm, the biogas treatment and H2S-adsorption capacities decreased to 229 ± 18 m3 and 668 ± 47 g, respectively. An estimation indicated a requisite cost of US$16.5 for the purification of 1,000 m3 of biogas containing 2,110 ppm of H2S. This cost is approximately 5% of US$330, the value of 1,000 m3 of biogas. IMPLICATIONS: Biogas generated from anaerobic digesters of animal manure and municipal wastewater sludge contains hydrogen sulfide which must be removed before it can be combusted in electricity-generation engines. This study demonstrated that commercial activated carbon adsorption can be an economical and effective approach for removing hydrogen sulfide from biogas. In this study, granular activated carbon (GAC) was used as an adsorbent for biogas desulfurization. The biogas containing 932-2,350 ppm of H2S was collected from an anaerobic digester for treating wastewater collected from a 200 dairy farm. The adsorption test was performed by introducing the biogas to a PVC column packed with a commercial GAC of around 50 L. Operation ceased if the effluent gas had an H2S concentration of over 100 ppm. A given weight of the new GAC was replaced for a successive test.

Electronic structure and unusual exchange splitting in the spin-density-wave state of the BaFe2As2 parent compound of iron-based superconductors.

The magnetic properties in the parent compounds are often intimately related to the microscopic mechanism of superconductivity. Here we report the first direct measurements on the electronic structure of a parent compound of the newly discovered iron-based superconductor, BaFe2As2, which provides a foundation for further studies. We show that the energy of the spin density wave in BaFe2As2 is mainly lowered through exotic exchange splitting of the band structure.

Unusual doping dependence of the electronic structure and coexistence of spin-density-wave and superconductor phases in single crystalline Sr1-xKxFe2As2.

The nature of the spin-density wave (SDW) and its relation with superconductivity are crucial issues in the newly discovered iron-pnictide superconductors. Particularly, it is unclear whether the superconducting phase and SDW are truly exclusive from each other. We here report splittings of the band structures in Sr1-xKxFe2As2 (x=0, 0.1, 0.18), and their unusual doping dependence. Our data on single crystalline samples prove that the SDW and superconductivity could coexist in iron pnictides.

Novel electronic structure induced by a highly strained oxide interface with incommensurate crystal fields.

The misfit oxide, Bi2Ba1.3K0.6Co2.1O7.94, made of alternating rocksalt-structured [BiO/BaO] layers and hexagonal CoO2 layers, was studied by angle-resolved photoemission spectroscopy, revealing the electronic structure of a highly strained oxide interface. We found that low-energy states are confined within individual sides of the interface, but scattered by the incommensurate crystal field from the other side. Furthermore, the high strain on the rocksalt layer induces large charge transfer to the CoO2 layer, and a novel effect, the interfacial enhancement of electron-phonon interactions, is discovered.

Primary role of the barely occupied states in the charge density wave formation of NbSe2.

NbSe2 is a prototypical charge-density-wave (CDW) material, whose mechanism remains mysterious so far. With angle resolved photoemission spectroscopy, we recovered the long-lost nesting condition over a large broken-honeycomb region in the Brillouin zone, which consists of six saddle band point regions with high density of states (DOS), and large regions away from Fermi surfaces with negligible DOS at the Fermi energy. We show that the major contributions to the CDW formation come from these barely occupied states rather than the saddle band points. Our findings not only resolve a long-standing puzzle, but also overthrow the conventional wisdom that CDW is dominated by regions with high DOS.

Superconducting coherence peak in the electronic excitations of a single-layer Bi2Sr1.6La0.4CuO6+delta cuprate superconductor.

Angle resolved photoemission spectroscopy study is reported on a high quality optimally doped Bi2Sr1.6La0.4CuO6+delta high-Tc superconductor. In the antinodal region with a maximal d-wave gap, the symbolic superconducting coherence peak, which has been widely observed in multi-CuO2-layer cuprate superconductors, is unambiguously observed in a single-layer system. The associated peak-dip separation is just about 19 meV, which is much smaller than its counterparts in multilayered compounds, but correlates with the energy scales of spin excitations in single-layer cuprates.

Evolution of the electronic structure of 1T-Cu(x)TiSe(2).

The electronic structure of a new charge-density-wave system or superconductor, 1T-Cu(x)TiSe(2), has been studied by photoemission spectroscopy. A correlated semiconductor band structure is revealed for the undoped case, which resolves a long-standing controversy in the system. With Cu doping, the charge-density wave is suppressed by the raising of the chemical potential, while the superconductivity is enhanced by the enhancement of the density of states, and possibly suppressed at higher doping by the strong scattering.

High-energy scale revival and giant kink in the dispersion of a cuprate superconductor.

In the present photoemission study of a cuprate superconductor Bi1.74Pb0.38Sr1.88CuO6+delta, we discovered a large scale dispersion of the lowest band, which unexpectedly follows the band structure calculation very well. Similar behavior observed in blue bronze and the Mott insulator Ca2CuO2Cl2 suggests that the origin of hopping-dominated dispersion in an overdoped cuprate might be quite complicated. A giant kink in the dispersion is observed, and the complete self-energy containing all interaction information is extracted for a doped cuprate. These results recovered significant missing pieces in our current understanding of the electronic structure of cuprates.