Giant Cell Tumor and Giant Cell Reparative Granuloma of Bone of the Head: CT and MR Imaging Findings.

BACKGROUND: This study aimed to determine the features and differentiation of Giant Cell Reparative Granuloma (GCRG) and Giant Cell Tumor (GCT) of the head on CT and MRI. METHODS: This retrospective study included six patients with histopathology-confirmed head GCRG and 5 patients with histopathology-confirmed head GCT. All images were independently reviewed by two radiologists. The growth pattern, bone changes, MRI signal intensity, enhancement patterns and other image features were recorded. All patients received CT scans and MR images. RESULTS: All the lesions were located centrally in the bone. Osteolytic bone destruction and expansive growth patterns were observed on CT images. Four of six cases broke the cortical bone with residual cortical bone, and the last two showed a thin cortex in GCRG. Five cases broke the cortical bone with residual cortical bone in GCT. There were enhancing septations in GCT lesions on contrast- enhanced T1-Weighted Images (T1WI) while enhancing septations were not present in GCRG cases. The size of GCT lesions was larger than that of GRCG. GCRG and GCT showed iso-low signals on T1WI and iso-high signals on T2-Weighted Images (T2WI). There was a case with cystic or necrotic lesions in each of the two types of lesions. Osteolytic bone destruction and expansive growth patterns were observed in GCTs and GCRGs. CONCLUSION: The size of the GRCG lesion was smaller than that of the GCT. The presence of enhancing septations and the size of the lesion may distinguish GCTs from GCRG.

Porous Organic Polymers for Catalytic Conversion of Carbon Dioxide.

To overcome the challenges of global warming and environmental pollution, it is necessary to reduce the concentration of carbon dioxide (CO2 ) in the atmosphere, which is mainly accumulated in the air through the burning of fossil fuels. Therefore, the development of environmentally friendly strategies to capture carbon dioxide and convert it into value-added products offers a promising way forward for reducing carbon dioxide concentration in the atmosphere. In this context, POPs (porous organic polymers) have shown great potential as CO2 selective adsorbents due to their high specific surface area, chemical stability, nanoscale porosity and structural diversity, as well as POPs based heterogeneous catalysts for CO2 conversion. This review provides a concise account of preparation methods of various POPs, challenges and current development trends of POPs in photocatalytic CO2 reduction, electrocatalytic CO2 reduction and chemical CO2 conversion.

Fabrication and adsorption performance for CO2 capture of advanced nanoporous microspheres enriched with amino acids.

Advanced porous organic materials with high gas storage capacity and high selectivity have been rapidly developed for CO2 adsorbents in the recent decade, due to extremely high surface area and nanoscale pore size. Here, novel amino acids-incorporated solid adsorbents based on porous hypercrosslinked polymers were fabricated by a dispersion polymerization of an aromatic monomer and quaternary ammonium salt comonomer, subsequently a hypercrosslinked reaction and an ion-exchange step. The developed adsorbents presented mesopores structure with BET surface area up to 864 m2/g and an extremely high CO2 capturing capacity up to 60.7 wt% (13.8 mmol/g) at 273 K/1 bar. The results also showed the adsorbent had an excellent recycling ability over repetitive adsorption-desorption cycles. All the results suggest that the amino acids-modified porous sorbents are promising CO2 sorbents that can meet the challenges of the current CO2 capture and storage technology.

Splenic siderotic nodules in patients with liver cirrhosis.

The aim of this study was to investigate the interrelation between splenic siderotic nodules, hypersplenism and liver function in patients with liver cirrhosis. The splenic enhanced susceptibility-weighted angiography (ESWAN) and conventional magnetic resonance images of 33 patients with liver cirrhosis were retrospectively studied and the ESWAN images were graded. The distribution and prevalence of the image grades for patients with and without hypersplenism were evaluated. In addition, the splenic volume and the distribution of Child-Pugh and albumin scores were compared between patients with and without siderotic nodules, and the correlation between splenic volume and the ESWAN image grades were evaluated in the patients with siderotic nodules. The ESWAN images revealed splenic siderotic nodules in 24 patients. The distribution and prevalence of the ESWAN image grades were demonstrated to be significantly different (P<0.001) between patients with and without hypersplenism. Furthermore, significant differences were observed between patients with and without siderotic nodules with regard to splenic volume and the distribution of Child-Pugh and serum albumin scores (P<0.001). No significant correlation was demonstrated between splenic volume and the ESWAN image grades (P>0.05). In conclusion, a higher prevalence of splenic siderotic nodules (72.7%) was observed using the ESWAN sequence, in comparison with results from previous studies, obtained using the T1-spoiled gradient echo sequence. The presence of splenic siderotic nodules was consistent with the occurrence of hypersplenism and was interrelated with reserved liver function.

CuI/I2-promoted electrophilic tandem cyclization of 2-ethynylbenzaldehydes with ortho-benzenediamines: synthesis of iodoisoquinoline-fused benzimidazoles.

An efficient tandem route to the synthesis of iodoisoquinoline-fused benzimidazole derivatives including an iodocyclization strategy has been developed. In the presence of CuI, a variety of 2-ethynylbenzaldehydes underwent the tandem reaction with benzenediamines and iodine to afford the corresponding iodoisoquinoline-fused benzimidazoles in moderate to good yields.