RESUMO
The biogas production potential and biomethane content of teff straw through pretreatment by NaOH was investigated. Different NaOH concentrations (1%, 2%, 4% and 6%) were used for each four solid loadings (50, 65, 80 and 95 g/L). The effects of NaOH as pretreatment factor on the biodegradability of teff straw, changes in main compositions and enhancement of anaerobic digestion were analyzed. The result showed that, using 4% NaOH for pretreatment in 80 g/L solid loading produced 40.0% higher total biogas production and 48.1% higher biomethane content than the untreated sample of teff straw. Investigation of changes in chemical compositions and physical microstructure indicated that there was 4.3-22.1% total lignocellulosic compositions removal after three days pretreatment with NaOH. The results further revealed that NaOH pretreatment changed the structural compositions and lignin network, and improved biogas production from teff straw.
Assuntos
Biocombustíveis , Biotecnologia/métodos , Eragrostis/metabolismo , Metano/biossíntese , Hidróxido de Sódio/farmacologia , Resíduos , Anaerobiose , Eragrostis/efeitos dos fármacos , Concentração de Íons de Hidrogênio , Lignina/química , Esgotos , VolatilizaçãoRESUMO
A new biological pretreatment method by using liquid fraction of digestate (LFD) was advanced for promoting anaerobic biogasification efficiency of corn stover. 17.6% TS content and ambient temperature was appropriate for pretreatment. The results showed that C/N ratio decreased to about 30, while total lignin, cellulose, and hemicellulose (LCH) contents were reduced by 8.1-19.4% after pretreatment. 3-days pretreatment was considered to be optimal, resulting in 70.4% more biogas production, 66.3% more biomethane yield and 41.7% shorter technical digestion time compared with the untreated stover. The reductions on VS, cellulose, and hemicellulose were increased by 22.1-35.9%, 22.3-35.4%, and 19.8-27.2% for LFD-treated stovers. The promoted anaerobic biogasification efficiency was mainly attributed to the improved biodegradability due to the pre-decomposition role of the bacteria in LFD. The method proved to be an efficient and low cost approach for producing bioenergy from corn stover, meanwhile, reducing LFD discharge and minimizing its potential pollution.
Assuntos
Biotecnologia/métodos , Metano/biossíntese , Zea mays/química , Zea mays/metabolismo , Anaerobiose , Biodegradação Ambiental , Biocombustíveis , Carbono/metabolismo , Celulose/metabolismo , Lignina/metabolismo , Nitrogênio/metabolismo , Brotos de Planta/química , Brotos de Planta/metabolismo , Polissacarídeos/metabolismo , Zea mays/microbiologiaRESUMO
As a lignocellulose-based substrate for anaerobic digestion, rice straw is characterized by low density, high water absorbability, and poor fluidity. Its mixing performances in digestion are completely different from traditional substrates such as animal manures. Computational fluid dynamics (CFD) simulation was employed to investigate mixing performances and determine suitable stirring parameters for efficient biogas production from rice straw. The results from CFD simulation were applied in the anaerobic digestion tests to further investigate their reliability. The results indicated that the mixing performances could be improved by triple impellers with pitched blade, and complete mixing was easily achieved at the stirring rate of 80 rpm, as compared to 20-60 rpm. However, mixing could not be significantly improved when the stirring rate was further increased from 80 to 160 rpm. The simulation results agreed well with the experimental results. The determined mixing parameters could achieve the highest biogas yield of 370 mL (g TS)(-1) (729 mL (g TS(digested))(-1)) and 431 mL (g TS)(-1) (632 mL (g TS(digested))(-1)) with the shortest technical digestion time (T 80) of 46 days. The results obtained in this work could provide useful guides for the design and operation of biogas plants using rice straw as substrates.
Assuntos
Biocombustíveis , Oryza , Caules de Planta , Eliminação de Resíduos/métodos , Anaerobiose , Simulação por Computador , Arquitetura de Instituições de Saúde , Hidrodinâmica , LigninaRESUMO
The co-digestion of fruit & vegetable waste (FVW) and food waste (FW) was performed at various organic loading ratios (OLRs) in single-phase and two-phase system, respectively. The results showed that the ethanol-type fermentation dominated in both digestion processes when OLR was at low levels (<2.0 g(VS) L(-1) d(-1)). The propionic acid was rapidly accumulated as OLR was increased to higher levels (>2.0 g(VS) L(-1) d(-1)), which could cause unstable anaerobic digestion. Single-phase digestion was better than two-phase digestion in term of 4.1% increase in CH4 production at lower OLRs (<2.0 g(VS) L(-1) d(-1)). However, at higher level of OLR (≥2.0 g(VS) L(-1) d(-1)), two-phase digestion achieved higher CH4 production of 0.351-0.455 L(g VS)(-1) d(-1), which were 7.0-15.8% more than that of single-phase. Additionally, two-phase digestion presented more stable operation, and higher OLR treatment capacity. Furthermore, comparison of these two systems with bioenergy recovery revealed that two-phase system overall presented higher bioenergy yield than single-phase.
Assuntos
Alimentos , Frutas/química , Eliminação de Resíduos/métodos , Verduras/química , Resíduos/análise , Ácidos/química , Anaerobiose , Biodegradação Ambiental , Biocombustíveis/análise , Dióxido de Carbono/análise , Ácidos Graxos Voláteis/análise , Hidrogênio/análise , Metano/análise , Compostos Orgânicos/química , EsgotosRESUMO
The aim of this work was to investigate the effects of aeration rate, aeration method, moisture content, and manure age on the characteristics of dairy manure composting with rice straw in terms of composting temperature, oxygen consumption rate, emission of odorous gases, and final compost property. It was found that the aeration rate of 0.25 L/min-kg VS was capable of achieving the highest composting temperature, longest retention time of high temperature, and less emission of odor gases. Except for the composting temperature reached, there was no significant difference between bottom-forced and top-diffusion aerations in terms of final compost property. The higher initial moisture content (65%) was more favorable for its higher temperature, longer retention time of high temperature, and more stable end compost obtained. Fresh manure showed better composting performance than the aged manure for its higher temperature reached in less time and less ammonia emission. Oxygen consumption rates were basically similar to those of temperatures. Most emissions of the odorous gases occurred during the first week of composting, therefore, special attention should be paid to this period of time for effective odor control.