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1.
Nat Commun ; 12(1): 4655, 2021 Aug 02.
Artigo em Inglês | MEDLINE | ID: mdl-34341360

RESUMO

The use of graphene in a form of discontinuous flakes in polymer composites limits the full exploitation of the unique properties of graphene, thus requiring high filler loadings for achieving- for example- satisfactory electrical and mechanical properties. Herein centimetre-scale CVD graphene/polymer nanolaminates have been produced by using an iterative 'lift-off/float-on' process and have been found to outperform, for the same graphene content, state-of-the-art flake-based graphene polymer composites in terms of mechanical reinforcement and electrical properties. Most importantly these thin laminate materials show a high electromagnetic interference (EMI) shielding effectiveness, reaching 60 dB for a small thickness of 33 µm, and an absolute EMI shielding effectiveness close to 3·105 dB cm2 g-1 which is amongst the highest values for synthetic, non-metallic materials produced to date.

2.
Materials (Basel) ; 11(9)2018 Sep 04.
Artigo em Inglês | MEDLINE | ID: mdl-30181508

RESUMO

Time domain spectroscopy is used to determine the THz electromagnetic response of amorphous transition metal dichalcogenides WSe2 and MoSe2 in thin-film form. The dielectric function is obtained using a rigorous transmission model to account for the large etalon effect. The Drude⁻Smith model is applied to retrieve the dielectric function, and from there, the sample conductivity.

3.
Sci Rep ; 6: 34536, 2016 10 06.
Artigo em Inglês | MEDLINE | ID: mdl-27708395

RESUMO

We investigate a hybrid re-configurable three dimensional metamaterial based on liquid crystal as tuning element in order to build novel devices operating in the terahertz range. The proposed metadevice is an array of meta-atoms consisting of split ring resonators having suspended conducting cantilevers in the gap region. Adding a "third dimension" to a standard planar device plays a dual role: (i) enhance the tunability of the overall structure, exploiting the birefringence of the liquid crystal at its best, and (ii) improve the field confinement and therefore the ability of the metadevice to efficiently steer the THz signal. We describe the design, electromagnetic simulation, fabrication and experimental characterization of this new class of tunable metamaterials under an externally applied small voltage. By infiltrating tiny quantities of a nematic liquid crystal in the structure, we induce a frequency shift in the resonant response of the order of 7-8% in terms of bandwidth and about two orders of magnitude change in the signal absorption. We discuss how such a hybrid structure can be exploited for the development of a THz spatial light modulator.

4.
Nat Commun ; 7: 10560, 2016 Feb 16.
Artigo em Inglês | MEDLINE | ID: mdl-26879257

RESUMO

Superconducting nanowires currently attract great interest due to their application in single-photon detectors and quantum-computing circuits. In this context, it is of fundamental importance to understand the detrimental fluctuations of the superconducting order parameter as the wire width shrinks. In this paper, we use controlled electromigration to narrow down aluminium nanoconstrictions. We demonstrate that a transition from thermally assisted phase slips to quantum phase slips takes place when the cross section becomes less than ∼150 nm(2). In the regime dominated by quantum phase slips the nanowire loses its capacity to carry current without dissipation, even at the lowest possible temperature. We also show that the constrictions exhibit a negative magnetoresistance at low-magnetic fields, which can be attributed to the suppression of superconductivity in the contact leads. These findings reveal perspectives of the proposed fabrication method for exploring various fascinating superconducting phenomena in atomic-size contacts.

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