1.
Chem Commun (Camb)
; 57(84): 11060-11063, 2021 Oct 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34610631
RESUMO
Mn cage complexes are rare, and the ones successfully isolated in the solid state are not stable in water and organic solvents. Herein, we present the first report of mononuclear Mn clathrochelates, in which the encapsulated metal exists in the oxidation state +4. The complexes are extremely stable in the crystalline state and in solutions and show rich redox chemistry.