Impacts of morphological-controlled ZnO nanoarchitectures on aerobic microbial communities during real wastewater treatment in an aerobic-photocatalytic system.

This study aimed to evaluate the impacts of morphological-controlled ZnO nanoarchitectures on aerobic microbial communities during real wastewater treatment in an aerobic-photocatalytic system. Results showed that the antibacterial properties of ZnO nanoarchitectures were significantly more overwhelming than their photocatalytic properties. The inhibition of microbial activities in activated sludge by ZnO nanoarchitectures entailed an adverse effect on wastewater treatment efficiency. Subsequently, the 16S sequencing analysis were conducted to examine the impacts of ZnO nanoarchitectures on aerobic microbial communities, and found the significantly lower microbial diversity and species richness in activated sludge treated with 1D-ZnO nanorods as compared to other ZnO nanoarchitectures. Additionally, 1D-ZnO nanorods reduced the highest proportion of Proteobacteria phylum in activated sludge due to its higher proportion of active polar surfaces that facilitates Zn2+ ions dissolution. Pearson correlation coefficients showed that the experimental data obtained from COD removal efficiency and bacterial log reduction were statistically significant (p-value < 0.05), and presented a positive correlation with the concentration of Zn2+ ions. Finally, a non-parametric analysis of Friedman test and post-hoc analysis confirmed that the concentration of Zn2+ ions being released from ZnO nanoarchitectures is the main contributing factor for both the reduction in COD removal efficiency and bacterial log reduction.

Multi-dimensional zinc oxide (ZnO) nanoarchitectures as efficient photocatalysts: What is the fundamental factor that determines photoactivity in ZnO?

While bulk zinc oxide (ZnO) is of non-toxic in nature, ZnO nanoarchitectures could potentially induce the macroscopic characteristics of oxidative, lethality and toxicity in the water environment. Here we report a systematic study through state-of-the-art controllable synthesis of multi-dimensional ZnO nanoarchitectures (i.e. 0D-nanoparticle, 1D-nanorod, 2D-nanosheet, and 3D-nanoflowers), and subsequent in-depth understanding on the fundamental factor that determines their photoactivities. The photoactivities of resultant ZnO nanoarchitectures were interpreted in terms of the photodegradation of salicylic acid as well as inactivation of Bacillus subtilis and Escherichia coli under UV-A irradiation. Photodegradation results showed that 1D-ZnO nanorods demonstrated the highest salicylic acid photodegradation efficiency (99.4%) with a rate constant of 0.0364 min-1. 1D-ZnO nanorods also exhibited the highest log reductions of B. subtilis and E. coli of 3.5 and 4.2, respectively. Through physicochemical properties standardisation, an intermittent higher k value for pore diameter (0.00097 min-1 per mm), the highest k values for crystallite size (0.00171 min-1 per nm) and specific surface area (0.00339 min-1 per m2/g) contributed to the exceptional photodegradation performance of nanorods. Whereas, the average normalised log reduction against the physicochemical properties of nanorods (i.e. low crystallite size, high specific surface area and pore diameter) caused the strongest bactericidal effect.

The influence of different solid-liquid ratios on the thermophilic anaerobic digestion performance of palm oil mill effluent (POME).

An alternative method was proposed to optimize the treatment process of palm oil mill effluent (POME) in an effort to address the poor removal efficiencies in terms of the chemical and biological oxygen demand (COD and BOD), total suspended solids (TSS) as well as oil and grease (O&G) content in treated POME along with many environmental issues associated with the existing POME treatment process. The elimination of the cooling ponds and the insertion of a dewatering device in the treatment process were recommended. The dewatering device should enhance the anaerobic digestion process by conferring a means of control on the digesters' load. The objective of this study is to identify the optimum solid: liquid ratio (total solids (TS) content) that would generate the maximum amount of biogas with better methane purity consistently throughout the anaerobic digestion of POME, all while improving the treated effluent quality. It was established that a 40S:60L (4.02% TS) was the best performing solid loading in terms of biogas production and methane yield as well as COD, BOD, TSS, and O&G removal efficiencies. Meanwhile, at higher solid loadings, the biogas production is inhibited due to poor transport and mass transfer. It is also speculated that sulfate-reducing bacteria tended to inhibit the biogas production based on the significantly elevated H2S concentration recorded for the 75S:25L and the 100S loadings.

A comprehensive guide of remediation technologies for oil contaminated soil - Present works and future directions.

Oil spills result in negative impacts on the environment, economy and society. Due to tidal and waves actions, the oil spillage affects the shorelines by adhering to the soil, making it difficult for immediate cleaning of the soil. As shoreline clean-up is the most costly component of a response operation, there is a need for effective oil remediation technologies. This paper provides a review on the remediation technologies for soil contaminated with various types of oil, including diesel, crude oil, petroleum, lubricating oil, bitumen and bunker oil. The methods discussed include solvent extraction, bioremediation, phytoremediation, chemical oxidation, electrokinetic remediation, thermal technologies, ultrasonication, flotation and integrated remediation technologies. Each of these technologies was discussed, and associated with their advantages, disadvantages, advancements and future work in detail. Nonetheless, it is important to note that no single remediation technology is considered the best solution for the remediation of oil contaminated soil. CAPSULE: This review provides a comprehensive literature on the various remediation technologies studied in the removal of different oil types from soil.

Extraction agents for the removal of polycyclic aromatic hydrocarbons (PAHs) from soil in soil washing technologies.

Polycyclic aromatic hydrocarbons (PAHs) in soil have been recognised as a serious health and environmental issue due to their carcinogenic, mutagenic and teratogenic properties. One of the commonly employed soil remediation techniques to clean up such contamination is soil washing or solvent extraction. The main factor which governs the efficiency of this process is the solubility of PAHs in the extraction agent. Past field-scale soil washing treatments for PAH-contaminated soil have mainly employed organic solvents or water which is either toxic and costly or inefficient in removing higher molecular weight PAHs. Thus, the present article aims to provide a review and discussion of the alternative extraction agents that have been studied, including surfactants, biosurfactants, microemulsions, natural surfactants, cyclodextrins, vegetable oil and solution with solid phase particles. These extraction agents have been found to remove PAHs from soil at percentages ranging from 47 to 100% for various PAHs.