The role of solution temperature in characteristics of TiO2 nanotube arrays prepared on Ti foil in acid solution.

The characteristics of TiO2 nanotube arrays (TNTs) prepared on Ti foil in sulfuric acid solution that contains Cl- under different temperatures are investigated by field emission scanning electron microscopy (FESEM), electrochemical impedance spectroscopy (EIS), Mott-Schottky measurement and Raman spectra. The solution temperature significantly affects the morphologies of TNTs, i.e., when solution temperature rises from -10 °C to 90 °C, the inner diameter of the nanotube increases and the barrier layer thickness decreases, and, as TNTs display n-type semiconductive properties, the donor density (ND) and corrosion protection decrease. Two types (types I and II) of pulse temperature are used to fabricate TNTs, in which type I is firstly anodized at a low temperature for time t, and then increases to a high temperature. While for type II, the solution temperature order is opposite to that of type I. The ND of TNTs in the case of type I is lower than ND of TNTs in the case of type II. ND decreases with the increased pulse step time for type I, while ND increases with the increased pulse step time for type II.

Wearable Aerogels for Personal Thermal Management and Smart Devices.

Extreme climates have become frequent nowadays, causing increased heat stress in human daily life. Personal thermal management (PTM), a technology that controls the human body's microenvironment, has become a promising strategy to address heat stress. While effective in ordinary environments, traditional high-performance fibers, such as ultrafine, porous, highly thermally conductive, and phase change materials, fall short when dealing with harsh conditions or large temperature fluctuations. Aerogels, a third-generation superinsulation material, have garnered extensive attention among researchers for their thermal management applications in building energy conservation, transportation, and aerospace, attributed to their extremely low densities and thermal conductivity. While aerogels have historically faced challenges related to weak mechanical strength and limited secondary processing capacity, recent advancements have witnessed notable progress in the development of wearable aerogels for PTM. This progress underscores their potential applications within extremely harsh environments, serving as self-powered smart devices and sensors. This Review offers a timely overview of wearable aerogels and their PTM applications with a particular focus on their wearability and suitability. Finally, the discussion classifies five types of PTM applications based on aerogel function: thermal insulation, heating, cooling, adaptive regulation (involving thermal insulation, heating, and cooling), and utilization of aerogels as wearable smart devices.

A Multi-Target Localization and Vital Sign Detection Method Using Ultra-Wide Band Radar.

Life detection technology using ultra-wideband (UWB) radar is a non-contact, active detection technology, which can be used to search for survivors in disaster rescues. The existing multi-target detection method based on UWB radar echo signals has low accuracy and has difficulty extracting breathing and heartbeat information at the same time. Therefore, this paper proposes a new multi-target localization and vital sign detection method using ultra-wide band radar. A target recognition and localization method based on permutation entropy (PE) and K means++ clustering is proposed to determine the number and position of targets in the environment. An adaptive denoising method for vital sign extraction based on ensemble empirical mode decomposition (EEMD) and wavelet analysis (WA) is proposed to reconstruct the breathing and heartbeat signals of human targets. A heartbeat frequency extraction method based on particle swarm optimization (PSO) and stochastic resonance (SR) is proposed to detect the heartbeat frequency of human targets. Experimental results show that the PE-K means++ method can successfully recognize and locate multiple human targets in the environment, and its average relative error is 1.83%. Using the EEMD-WA method can effectively filter the clutter signal, and the average relative error of the reconstructed respiratory signal frequency is 4.27%. The average relative error of heartbeat frequency detected by the PSO-SR method was 6.23%. The multi-target localization and vital sign detection method proposed in this paper can effectively recognize all human targets in the multi-target scene and provide their accurate location and vital signs information. This provides a theoretical basis for the technical system of emergency rescue and technical support for post-disaster rescue.

Research progress and visualization of underground coal fire detection methods.

Underground coal fires are a widespread disaster prevailing in major coal-producing countries globally, posing serious threats to the ecological environment and restricting the safe exploitation of coal mines. The accuracy of underground coal fire detection directly affects the effectiveness of fire control engineering. In this study, we searched 426 articles from the Web of Science database within 2002-2022 as the data foundation and visualized the research contents of the underground coal fire field using VOSviewer and CiteSpace. The results reveal that the investigation of "underground coal fire detection techniques" is currently the focal area of research in this field. Additionally, the "underground coal fire multi-information fusion inversion detection methods" are considered to be the future research trend. Moreover, we reviewed the strengths and weaknesses of various single-indicator inversion detection methods, including the temperature method, gas and radon method, natural potential method, magnetic method, electric method, remote sensing, and geological radar method. Furthermore, we conducted an analysis of the advantages of the multi-information fusion inversion detection methods, which possesses high precision and wide applicability for detecting coal fires, while highlighting the challenges in handling diverse data sources. It is our hope that the research results presented in this paper will provide valuable insights and ideas for researchers involved in the detection and practical research of underground coal fires.

Development characteristics of the rock fracture field in strata overlying a mined coal seam group.

The fracture development of the overlying strata after coal mining is an important guarantee of efficient gas drainage. In order to explore the fracture evolution characteristics close to a mined coal seam group, the F15.16-24130 working face in the Pingdingshan No. 10 coal mine was taken as the research background. The FLAC3D numerical simulation software was used to study the migration and failure characteristics of the overlying strata during mining of a coal seam group, and the fracture evolution process of the stope was investigated. The results show that as the advancing distance increased, the fracture density and fracture height increased continuously due to deformation and failure of the overlying rock. The displacement of the overlying rock initially increased and then decreased, and the displacement of the floor rock initially decreased and then increased. When working face F15.16 of the coal seam advanced to 75 m, a saddle-shaped plastic zone gradually formed in the upper part of the goaf and the floor of the goaf was formed. The pressure relief depth was proportional to the advancement distance. As the advancement distance of the working face increased, the pressure relief depth gradually extended to the F17 coal seam, which was conducive to the development and penetration of the fractures in the coal floor and rock mass and was convenient for pressure relief gas drainage from the F17 coal seam.

Research on Ultra-Wideband Radar Echo Signal Processing Method Based on P-Order Extraction and VMD.

As a new method to detect vital signs, Ultra-wideband (UWB) radar could continuously monitor human respiratory signs without contact. Aimed at addressing the problem of large interference and weak acquisition signal in radar echo signals from complex scenes, this paper adopts a UWB radar echo signal processing method that combines strong physical sign information extraction at P time and Variational Mode Decomposition (VMD) to carry out theoretical derivation. Using this novel processing scheme, respiration and heartbeat signals can be quickly reconstructed according to the selection of the appropriate intrinsic mode functions (IMFs), and the real-time detection accuracy of human respiratory signs is greatly improved. Based on an experimental platform, the data collected by the UWB radar module were first verified against the measured values obtained at the actual scene. The results of a validation test proved that our UWB radar echo signal processing method effectively eliminated the respiratory clutter signal and realized the accurate measurement of respiratory and heartbeat signals, which would prove the existence of life and further improve the quality of respiration and heartbeat signal and the robustness of detection.

Study on the characteristics of induced airflow and particle dispersion based on the multivariate two-factor model.

To examine the diffusion characteristics of airflow and dust particles, a multi-factor and multi-level physical self-developed testing system is established. In this study, bunker height, chute angle, feeding speed, coal granularity, and belt speed are selected as independent variables, and airflow velocity and dust concentration are the response variables. The two-factor interactive model is established to analyze the primary and secondary relationship between the independent variables and the response variables. The results demonstrate a denser contour distribution of three-dimensional curved surfaces, suggesting an obvious interaction between the factors. The bunker height increases from 0.75 m to 1.15 m, the maximum increment of the induced airflow velocity at the outlet of the guide chute is observed to be 0.35 m/s, meanwhile, and with the increase in the feed speed from 2t/h to 8t/h, the increment of the induced airflow velocity at the outlet of the guide chute is recorded to be 51%. The coal granularity and bunker height depicted the highest influence on induced air velocity and dust concentration, and the feeding speed proved to be the secondary parameter. This two-factor interactive model can accurately forecast the actual values with a deviation of the calculated values limited to 9%. These research results support the existing research and provide a theoretical foundation to guide the dust control at belt conveyor transfer stations.

A Vital Signs Fast Detection and Extraction Method of UWB Impulse Radar Based on SVD.

The identification of weak vital signs has always been one of the difficulties in the field of life detection. In this paper, a novel vital sign detection and extraction method with high efficiency, high precision, high sensitivity and high signal-to-noise ratio is proposed. Based on the NVA6100 pulse radar system, the radar matrix which contains several radar pulse detection signals is received. According to the characteristics of vital signs and radar matrices, the Singular Value Decomposition (SVD) is adopted to perform signal denoising and decomposition after preprocessing, and the temporal and spatial eigenvectors of each principal component are obtained. Through the energy proportion screening, the Wavelet Transform decomposition and linear trend suppression, relatively pure vital signs in each principal component, are obtained. The human location is detected by the Energy Entropy of spatial eigenvectors, and the respiratory signal and heartbeat signal are restored through a Butterworth Filter and an MTI harmonic canceller. Finally, through an analysis of the performance of the algorithm, it is proved to have the properties of efficiency and accuracy.

Distribution of spontaneous combustion three zones and optimization of nitrogen injection location in the goaf of a fully mechanized top coal caving face.

In order to effectively prevent and control spontaneous combustion of residual coal in the goaf and reduce the waste of nitrogen caused by setting the position of nitrogen injection, 1303 fully mechanized coal caving faces of the Jinniu Mine are studied. By deploying a bundle tube monitoring system in the inlet air side and return air side of the goaf, changes in gas concentration in the goaf are continuously monitored. In addition, the distribution area for spontaneous combustion three-zone in the goaf is divided into heat dissipation zone, oxidized spontaneous combustion zone, and suffocation zone. Simulations from the COMSOL Multiphysics 5.3 software provide insight based on the three zones division standard of spontaneous combustion in the goaf. The gradual deepening of the nitrogen injection position into the goaf affects the lower limit of the oxidized spontaneous combustion zone significantly, but the impact on the upper limit of the oxidized spontaneous combustion zone is not obvious and is negligible. With regard to the width of the oxidized spontaneous combustion zone, it initially decreases followed by a gradual increase. Numerical calculations suggest the optimal nitrogen injection position is 40 m from the roof cutting line, with an oxidized spontaneous combustion zone width of 28 m. Based on the simulation analysis results, nitrogen injection controlling measures have been adopted for spontaneous combustion of residual coal in the goaf of the 1303 fully mechanized coal caving faces, and coal self-ignition in the goaf has been successfully extinguished.

Determination of the Spontaneous Combustion Hazardous Zone and Analysis of Influencing Factors in Bedding Boreholes of a Deep Coal Seam.

Accurately determining the spontaneous combustion zone of coal around the borehole plays an important role in preventing borehole accidents. To solve the problem of dividing the hazardous zone of spontaneous combustion in boreholes, a fully coupled model of the gas flow, coal oxidation reaction, and energy transportation is developed in this study. Taking the drainage borehole of the 24130 working face in the No. 10 Coal Mine of the Pingdingshan mining area as an example, the proposed model is used to simulate the seepage velocity field, oxygen concentration field, and temperature field of the coal around the borehole. The simulation results are found to be consistent with the field test results. Based on the simulation results, the coal around the borehole is divided into two areas in the axial direction of the borehole. The intersection of the seepage velocity u ≤ 0.004 m/s and oxygen concentration 7% ≤ C(O2) ≤ 21% are considered the "hazardous zone", and the union of the oxygen concentration C(O2) < 7% and seepage velocity u > 0.004 m/s are considered the "safety zone". The influences of various factors inducing spontaneous combustion of coal around the borehole on the hazardous zone are revealed by analyzing the drainage negative pressure, sealing length, and roadway temperature. The results show that reducing the drainage negative pressure and increasing the sealing length can effectively restrain the spontaneous combustion of the borehole and can also help reduce the scope of the hazardous zone of the borehole. Finally, a reasonable arrangement of the predrainage period in the appropriate season can also effectively inhibit the spontaneous combustion of coal around boreholes.

Seismic behaviour analysis of a wind turbine tower affected by sea ice based on a simplified model.

Ice-structure interaction threatens the safety of the offshore structure; however, dynamic seismic action even renders this process more sophisticated. This research constructed a simplified calculation model for the wind turbine tower, ice, and water under seismic loading, which could avoid solving the complex non-linear equations. Then, the seismic behaviour of the structure, i.e. wind turbine tower, in the presence and absence of influences of the sea ice was investigated, and we found the remarkable effect of sea ice upon the wind turbine tower when its mass is within a range; the wind turbine tower is found to have reduced capacity in energy dissipation, and thickness of tower walls or stiffening ribs is supposed to be enlarged for making the structure more ductile. Affected by the sea ice, the shear force and bending moment of the tower showed significant increases, and more attention needs to be paid to the tower bottom and action position of the sea ice. According to the dynamic similarity principle, finally paraffin was used to simulate sea ice, and shaking-table tests were performed for simulating dynamic ice-structure-water interactions. Results of shaking-table tests verified the rationality of our proposed simplified model.

Instability-negative pressure loss model of gas drainage borehole and prevention technique: A case study.

The internal collapse of deep seam drainage borehole and negative pressure loss represents a serious technical problem affecting gas drainage. To address this problem a creep model of coal around borehole was established based on the plastic softening characteristics of coal. The final collapse time of the borehole was determined and used to derive the three stages of the borehole collapse process. The model of negative pressure loss in drainage borehole was established according to the theory of fluid dynamics, the model of methane gas flow and the creep model of the coal around the borehole. The relationship between the negative pressure loss of drainage and the change of borehole aperture was derived, thereby revealing the main influencing factors of the negative pressure loss in the borehole. A drainage technique named "Full-hole deep screen mesh pipe" was introduced and tested to prevent the collapse of borehole and reduce the negative pressure loss. The result shows that after the borehole was drilled, the borehole wall was affected by the complex stress of the deep coal seam, the coal surrounding the borehole collapsed or presented the characteristics of creep extrusion towards the borehole. The "Full-hole deep screen mesh pipe drainage technology" could effectively control the collapse as well as the deformation of the borehole and reduced the negative pressure loss. Compared with the traditional drainage technology, the methane gas drainage concentration was increased by 101% and the gas flow was increased by 97% when the methane gas was drained for 90 days, the gas drainage efficiency increased significantly.

[Study on the calcium-based sorbent for removal fluorine during coal combustion].

In the paper, the reaction of CaO-HF and fluorine removal mechanics at high temperature by blending calcium-based sorbents with coal during coal combustion were discussed, and test results about fluorine retention during coal combustion in fluidized bed and chain-grate furnace were reported. The results identified that lime and calcium-based sorbets developed can restratin the emission of fluorine during coal combustion. The efficiency of fluorine removal can reach 66.7%-70.0% at Ca/F 60-70 by blending lime with coal in fluidized bed combustion, and the efficiency of fluorine removal are between 57.32% and 75.19% by blending calcium-based sorbets with coal in chain-grate furnace combustion. Blending CaO or lime with coal during coal combustion can remove SO2 and HF simultaneously.

[Distribution of fluoride in the combustion products of coal].

The static distribution characteristic of fluoride in the combustion products of coal was studied by ashing procedure of coal, and the dynamic distribution characteristics of fluorine in the combustion products of coal in pulverized-coal-fired boiler and layer-burning boiler were investigated. Experimental results identified that fluorine in coal belong to volatile elements, fluorine in fly ash and bottom ash were non-rich. About 94.5% of the fluorine in coal emitted as gaseous-fluorine during coal combustion in pulverized-coal-fired boiler, and about 80% of the fluorine in coal emitted as gaseous-fluorine during coal combustion in layer-burning boiler. 55%-60% of the fluorine in fly ash of pulverized-coal-fired boiler were distributed in fly ash particles with a diameter of 74 microns-104 microns.

[Stability of CaF2 at high temperature].

In this paper, the stabilities of CaF2 in atmosphere, dry and moist air at elevated temperatures were studied by gaseous fluorides direct absorption and fluoride ion-selective electrode (ISE) measurements technique supplemented by differential thermal analysis (DTA), chemical analysis (pyrohydrolysis-ISE method) and X-ray diffraction (XRD) analysis. The principal reaction was shown to be hydrolysis of CaF2 at high temperature and CaF2 were actually hydrolyzed appreciably at about 830 +/- 10 degrees C in moist atmospheres. Kinetics calculation showed that hydrolysis reaction was first order and the activation energy for the hydrolysis was 115 +/- 2 kJ/mol, applicable over the range 850 degrees C-1350 degrees C. The research results will be of significance for fluoride pollution control during coal combustion and clay-brickmaking.