Studies on structure property relations of efficient decal substrates for industrial grade membrane electrode assembly development in pemfc.

Electrode fabrication and membrane electrode assembly (MEA) processes are critical steps in polymer electrolyte membrane fuel cell (PEMFC) technology. The properties of decal substrate material are important in decal coating technique for efficient transfer of catalyst layer. In the present study, MEAs are fabricated in decal method using 6 different decal substrates among which polypropylene (PP) is found ideal. Morphological, thermal, spectroscopic and sessile drop measurements are conducted for 6 decal substrates to evaluate the thermal and physicochemical properties. Studies indicate PP is thermally stable at hot-press conditions, having optimal hydrophobicity that hinders the coagulation of catalyst ink slurry cast. The pristine PP film has been identified to showcase 100% transfer yield onto the Nafion membrane without contamination and delamination of catalyst layer from membrane. The PP based MEAs are evaluated underconstant current mode in a hydrogen-oxygen fuel cell test fixture. The performance is found to be of 0.6 V at a constant current density of 1.2 A.cm-2. Besides, the cost of PP-film is only 7.5% of Kapton-film, and hence the current research work enables the high throughput electrode fabrication process for PEMFC commercialization.

Interaction of vasicine with calf thymus DNA: Molecular docking, spectroscopic and differential scanning calorimetric insights.

The present study brings out the interaction between vasicine, an alkaloid of Adhatoda vasica Nees with double stranded DNA [corrected]. The physico-chemical interaction between small molecules and nucleic acids is a major area of focus in screening drugs against various cancers. Molecular probing in our study using Molecular Operating Environment (MOE) has revealed interaction of vasicine with DNA double helix. Here we report the interaction of vasicine with Calf thymus DNA. We present for the first time the results obtained from UV-visible, fluorescence spectroscopic and differential scanning calorimetric techniques that suggest a moderate to strong electrostatic, hydrophobic and van der Waals interactions mediating the DNA binding properties of vasicine, leading to disruption of DNA secondary structure.