Mechanical Properties, Corrosion Behavior, and In Vitro Cell Studies of the New Ti-25Ta-25Nb-5Sn Alloy.

This study aims to characterize a new Ti-25Ta-25Nb-5Sn alloy for biomedical application. Microstructure, phase formation, mechanical and corrosion properties, along with the cell culture study of the Ti-25Ta-25Nb alloy with Sn content 5 mass% are presented in this article. The experimental alloy was processed in an arc melting furnace, cold worked, and heat treated. For characterization, optical microscopy, X-ray diffraction, microhardness, and Young's modulus measurements were employed. Corrosion behavior was also evaluated using open-circuit potential (OCP) and potentiodynamic polarization. In vitro studies with human ADSCs were performed to investigate cell viability, adhesion, proliferation, and differentiation. Comparison among the mechanical properties observed in other metal alloy systems, including CP Ti, Ti-25Ta-25Nb, and Ti-25Ta-25-Nb-3Sn showed an increase in microhardness and a decrease in the Young's modulus when compared to CP Ti. The potentiodynamic polarization tests indicated that the corrosion resistance of the Ti-25Ta-25Nb-5Sn alloy was similar to CP Ti and the experiments in vitro demonstrated great interactions between the alloy surface and cells in terms of adhesion, proliferation, and differentiation. Therefore, this alloy presents potential for biomedical applications with properties required for good performance.

Fatigue Life Enhancement of Titanium Alloy by the Development of Nano/Micron Surface Layer Using Laser Peening.

Ti-15V-3Cr-3Al-3Sn (Ti-15-3) is a metastable beta alloy which is considered to be a potential alternative for Ti-6Al-4V alpha+beta alloy for aerospace applications, especially for sheet products. This paper describes the work carried out to enhance the fatigue life of Ti-15-3 in an economical way by means of laser peening without coating (LPwC) using Nd:YAG laser operating at a power density of 5 GW cm-2. In order to have a sufficient bulk hardness and high compressive stresses on the surface, as-received beta solution treated (ST) Ti-15-3 was subjected to aging (520 °C/10 h/Air-cooled) and then to LPwC. Laser peening induced a notable increase in Ra (arithmetic mean roughness), which was measured using MAHR GD-120 profilometer. The Electron Back Scatter Diffraction (EBSD) analysis of the aged sample (STA) revealed a significant increase in the alpha precipitation (20 vol%), and this led to a substantial increase in the hardness (~40%) and UTS (~50%). In addition to this, peening of aged (STA+LPwC) sample resulted in a considerable increase (~12%) in near-surface microhardness and compressive residual stress (maximum stress of -195 MPa at a depth of 150 µm). This increase in compressive stress and microhardness led to an enhancement in the fatigue life of the STA+LPwC sample by 210% when compared to STA sample. In spite of high surface roughness induced by the LPwC, fractography studies revealed that crack initiation was independent of surface roughness.