Combustion characteristics of refuse-derived fuel pellets having varying plastic compositions.

The plastic fraction of refuse-derived fuel (RDF) pellets influences fuel's physico-chemical, and mechanical properties, which in turn might affect the combustion behavior of RDF. In the present study, the combustion behavior of different plastic fraction-simulated RDF pellets is reported. The simulated pellets were prepared based on the Indian commercial RDF composition. Initially, the plastic content varied from the existing fraction in Indian commercial RDF, i.e., 35% (RDF-1), to a lower plastic content of 5% (RDF-2). Physico-chemical characterization showed that a higher plastic fraction in RDF-1 reduces its pellet density by 25% as compared to RDF-2. The changes in RDF physico-chemical properties due to plastic variation are reflected in the RDF conversion process. Single-particle and packed-bed studies concluded that the lower density for higher plastic RDF-1 leads to lower conversion times (36%), and higher flame front speed (11%), which are desirable conditions for faster conversion. However, packed-bed studies also showed limitations regarding the utilization of high plastic RDF as RDF-1 has a narrow range of operating air mass flux due to the early advent of convective cooling of the bed. Finally, considering the constraints associated with the utilization of high plastic fraction (~ 35%) RDF and to maximize the effective utilization of plastic in RDF, a workable plastic fraction of 15% in RDF was proposed and tested for its combustion properties. RDF with 15% plastic showed faster conversion, higher flame front speed, and a wider range of operating air mass flux before the advent of convective cooling of the bed.

Foam control in lakes and sewage receiving water bodies: A pre-emptive approach using decentralized inline water treatment design.

Hideous and persistent foams on surface water bodies are global issues with far-reaching environmental consequences. This study examines Bellandur Lake (Bengaluru, India) plagued by foam since 2005 due to surfactant-laden untreated sewage ingress. Bellandur Lake receives 258 million liters of inadequately treated sewage daily, constituting 47% of its total volume. Yearlong water quality monitoring reveals that a) high surfactant levels (up to 17.8 ± 1 ppm) and b) prevalent anoxic conditions at lake inlets. Laboratory experiments show that controlled aeration achieved >90% surfactant degradation within 30 h at 3.5 ppm of dissolved oxygen conditions, indicating the need for an aeration chamber design based on the required residence time for inline water treatment. Based on these findings, a design of an inline wastewater treatment system to be installed at sewage entry points into the lake is presented in this work. The inline system was based on experimentally validated BioWin software. Simulations show that recirculating sludge enhances treatment efficiency, achieving effective surfactant degradation in 20 h (2/3rd original time) of residence time. Predictions suggest <1 ppm surfactant levels in the receiving water body, meeting local discharge norms to prevent frothing. This holistic approach, proposed for the first time, could serve as a blueprint for managing foam-related challenges in other waterbodies, offering insights into design, stakeholder engagement, and process optimization.

Tar Formation in Gasification Systems: A Holistic Review of Remediation Approaches and Removal Methods.

Gasification is an advanced thermochemical process that converts carbonaceous feedstock into syngas, a mixture of hydrogen, carbon monoxide, and other gases. However, the presence of tar in syngas, which is composed of higher molecular weight aromatic hydrocarbons, poses significant challenges for the downstream utilization of syngas. This Review offers a comprehensive overview of tar from gasification, encompassing gasifier chemistry and configuration that notably impact tar formation during gasification. It explores the concentration and composition of tar in the syngas and the purity of syngas required for the applications. Various tar removal methods are discussed, including mechanical, chemical/catalytic, and plasma technologies. The Review provides insights into the strengths, limitations, and challenges associated with each tar removal method. It also highlights the importance of integrating multiple techniques to enhance the tar removal efficiency and syngas quality. The selection of an appropriate tar removal strategy depends on factors such as tar composition, gasifier operating and design factors, economic considerations, and the extent of purity required at the downstream application. Future research should focus on developing cleaning strategies that consume less energy and cause a smaller environmental impact.

Determination of degradation/reaction rate for surface water quality of recycled water using Lake2K model for large-scale water recycling.

The depletion of groundwater resources in the water-stressed regions has led to the overuse of surface water reservoirs. Recharging groundwater by rejuvenating dried surface reservoirs using recycled water is a new sustainable solution. To ensure the prevention of groundwater contamination and associated health risks (as recycled water is used), it is crucial to assess the surface reservoir water quality. The study for the first time suggests the Lake2K model, a one-dimensional mechanistic mass-balance model, to simulate the changes in water quality in a series of man-made surface water reservoirs where recycled water flows under an indirect groundwater recharge scheme (soil aquifer treatment system). The model was developed, calibrated, and validated using field observations to estimate degradation/reaction rate constants for various water quality parameters. The observed average degradation/reaction rate constants for parameters including ammonia-N, nitrate-N, total nitrogen, total organic carbon, and organic phosphorous were 0.043 day-1, 0.04 day-1, 0.043 day-1, 0.055 day-1, and 0.056 day-1, respectively, which were found to be relatively high compared to existing literature, indicating a greater degradation of these parameters in warmer climates. The results showed that the water quality improved significantly as the water progressed through the reservoirs, aligning with field observations. Additionally, the simulated seasonal variations revealed that the maximum growth rate of phytoplankton occurred during July, August, and September for each reservoir, while the nutrient pool (nitrate-N and orthophosphates) experienced the greatest depletion during this growth period. These findings shed light on the dynamics of surface water quality in regions facing water scarcity and contribute to the development of sustainable groundwater management strategies.

Unveiling the origin, fate, and remedial approaches for surfactants in sewage-fed foaming urban (Bellandur) Lake.

Foam formation in surface water bodies has become a global phenomenon, but the solutions to this crisis are often insufficient. Foam formation in water bodies is attributed to surfactants and requires a comprehensive assessment of various sources of surfactants to evolve mitigation strategies. The study is focused on thoroughly analyzing surfactants in the water and foam fractions of a large waterbody in Bangalore (India) spanning around 1000 acres (400 ha), which has been foaming for two decades. Results revealed that the key surfactants originate predominantly from anthropogenic sources with a small component emerging from naturogenic sources. Anthropogenic surfactants were found to be predominant (96.5%), with linear alkylbenzene sulphonates (LAS) of various C-chain lengths 12-20 being the most prevalent. Naturogenic surfactants derived from bacterial genera Pseudomonas exhibited significant microbial diversity, accounting for over 19% of total bacterial population in both the water and organic sediments of the lake. Modelling studies and field validation efforts were carried out to understand the fate of LAS in the foaming lake. The results indicated that these surfactants donot degrade under the prevailing conditions and timeframe as wastewater traverses through the lake, and their presence was also observed in the organic sludge sediment. Modeling the underlying processes revealed that a minimum dissolved oxygen (DO) concentration of 3.5 mg/l enables the degradation of over 90% of surfactants within the residence time of 8-10 days in Lake. Additionally, the process of desludging could contribute to an additional increase to the overall efficiency of surfactant removal, simultaneously removing legacy sorbed surfactants to sediments.

Water, sanitation, and hygiene implications of large-scale recycling of treated municipal wastewater in semi-arid regions.

Access to water, sanitation, and hygiene (WaSH) is crucial for national development, as it improves human health and fulfills a fundamental need. This study examines the impact of a large-scale groundwater (GW) recharge scheme using secondary treated wastewater (STW) on WaSH characteristics and identifies the major determinants of improved WaSH charecteristics in drought-hit regions of Kolar district, southern India. The study quantifies improved WaSH practices by comparing WaSH characteristics between impacted areas (influenced by STW) and non-impacted areas (not influenced by STW) of Kolar, using household survey data. Pearson's chi-square and student's t-test are used to verify differences between WaSH characteristics. Furthermore, a composite WaSH score is formulated, and a hierarchical stepwise multiple linear regression model is constructed to identify major determinants of improved WaSH scores. The results show that impacted areas have better WaSH characteristics, including daily water supply by gram panchayat, enhanced toilet uses among all family members, bathing patterns, cloth washing practices, toilet cleaning patterns, and water consumption per capita per day. The maximum and minimum WaSH scores of impacted areas were 17.50 and 6.50, respectively, while those of non-impacted areas were 14 and 4.5. This study finds that improved water availability, quality, and security due to daily water supply at the household level are the major determinants of improved WaSH practices. These results can inform policymakers in designing sanitation and hygiene improvement policies that integrate water recycling projects in drought-hit areas.

Investigating the effects of irrigation with indirectly recharged groundwater using recycled water on soil and crops in semi-arid areas.

The utilization of direct wastewater for irrigation poses many environmental problems such as soil quality deterioration due to the accumulation of salts, heavy metals, micro-pollutants, and health risks due to undesirable microorganisms. This hampers its agricultural reuse in arid and semi-arid regions. To address these concerns, the present study introduces a recent approach that involves using indirectly recharged groundwater (GW) with secondary treated municipal wastewater (STW) for irrigation through a Soil Aquifer Treatment-based system (SAT). This method aims to mitigate freshwater scarcity in semi-arid regions. The study assessed GW levels, physicochemical properties, and microbial diversity of GW, and soil in both impacted (receiving recycled water) and non-impacted (not receiving recycled water) areas, before recycling (2015-2018) and after recycling (2019-2022) period of the project. The results indicated a significant increase of 68-70% in GW levels of the studied boreholes in the impacted areas. Additionally, the quality of indirectly recharged GW in the impacted areas improved notably in terms of electrical conductivity (EC), hardness, total dissolved solids (TDS), sodium adsorption ratio (SAR), along with certain cations and anions (hard water to soft water). No significant difference was observed in soil properties and microbial diversity of the impacted areas, except for EC and SAR, which were reduced by 50% and 39%, respectively, after the project commenced. The study also monitored specific microbial species, including total coliforms, Escherichia coli (as indicator organisms), Shigella, and Klebsiella in some of the harvested crops (beetroot, tomato, and spinach). However, none of the analysed crops exhibited the presence of the studied microorganisms. Overall, the study concludes that indirectly recharged GW using STW is a better sustainable and safe irrigation alternative compared to direct wastewater use or extracted hard GW from deep aquifers.

Unravelling the reason for seasonality of foaming in sewage-fed urban lakes.

Foaming surface waters are a global phenomenon but are understudied. Bellandur lake in India has gained international attention due to its foaming events, which occur seasonally after rainfall. This study investigates the seasonality of foaming and the sorption/desorption of surfactants onto sediment and suspended solids (SS). Results show that foaming lake sediment can contain as much as 3.4 g of anionic surfactant/ kg of dry sediment, and its concentration was proportional to the organic matter (OM) content and surface area of the sediment sample. This is the first study to demonstrate the sorption capacity of SS in wastewater, which was found to be 53.5 ± 4 mg surfactant/g SS. In contrast, only a maximum of 5.3 mg surfactant was sorbed/g of sediment. The lake model analysis revealed that sorption is a first-order process and that surfactant sorption on SS and sediment is reversible. SS was found to desorb ∼73 % of sorbed surfactant back to the bulk water, while sediment desorbed 33-61 % of sorbed surfactants proportional to their OM. Contrary to the common assumption, rain does not dilute the surfactant concentration but instead increases the foaming potential of lake water through desorption from SS.

Assessing groundwater recharge rates, water quality changes, and agricultural impacts of large-scale water recycling.

The over-exploitation and insufficient replenishment of groundwater (GW) have resulted in a pressing need to conserve freshwater and reuse of treated wastewater. To address this issue, the Government of Karnataka launched a large-scale recycling (440 million liters/day) scheme to indirectly recharge GW using secondary treated municipal wastewater (STW) in drought-prone areas of Kolar district in southern India. This recycling employs soil aquifer treatment (SAT) technology, which involves filling surface run-off tanks with STW that intentionally infiltrate and recharge aquifers. This study quantifies the impact of STW recycling on GW recharge rates, levels, and quality in the crystalline aquifers of peninsular India. The study area is characterized by hard rock aquifers with fractured gneiss, granites, schists, and highly fractured weathered rocks. The agricultural impacts of the improved GW table are also quantified by comparing areas receiving STW to those not receiving it, and changes before and after STW recycling were measured. The AMBHAS_1D model was used to estimate the recharge rates and showed a tenfold increase in daily recharge rates, resulting in a significant increase in the GW levels. The results indicate that the surface water in the rejuvenated tanks meets the country's stringent water discharge standards for STW. The GW levels of the studied boreholes increased by 58-73 %, and the GW quality improved significantly, turning hard water into soft water. Land use land cover studies confirmed an increase in the number of water bodies, trees, and cultivated land. The availability of GW significantly improved agricultural productivity (11-42 %), milk productivity (33 %), and fish productivity (341 %). The study's outcomes are expected to serve as a role model for the rest of Indian metro cities and demonstrate the potential of reusing STW to achieve a circular economy and a water-resilient system.

Socio-economic impact assessment of large-scale recycling of treated municipal wastewater for indirect groundwater recharge.

Reusing treated wastewater is an emerging solution to address freshwater scarcity, and surface water contamination faced worldwide. A unique large-scale wastewater recycling project was implemented to replenish groundwater by filling secondary treated wastewater (STW) into existing irrigation tanks in severely drought-hit areas of the Kolar districts of Southern India. This study quantifies the socio-economic impacts of this large-scale indirect groundwater recharge scheme. The changes in areas receiving STW i.e., impacted areas and those areas which did not receive STW i.e., non-impacted areas was studied. Also, pre and post recycling changes were quantified in the Kolar district. The results show that surface water quality meets India's most stringent treated wastewater discharge standards prescribed by the Hon'ble National Green Tribunal. Due to these recycling efforts, significant improvements in groundwater level and quality were found. It was observed that there was a noticeable difference in agricultural cropping areas, seasons, patterns, and production between impacted and non-impacted areas. Post-recycling, farmers tended to cultivate cash and water-intensive crops over less water-intensive crops. During the post-recycling period, livestock and milk production also increased, and in impacted areas, it was significantly higher. Post-recycling, fish production increased and land prices per hectare increased by 118 % in impacted areas. The farmer's net income under flowers and vegetable farming increased by 202 % and 150 % respectively in impacted areas compared to non-impacted areas. Furthermore, this project contributes to a circular economy transition in the water sector, which has economic, environmental, social, and cultural benefits. A key recommendation from the outcomes of the study is to draft and implement a policy that encourages the reuse of recycled water for groundwater recharge which in turn will improve the agro-economic system and food security.

Study towards understanding foaming and foam stability in urban lakes.

Foaming water bodies have become a matter of great concern globally. Foam disrupts aquatic ecosystems, emits an offensive smell, disrupts the day-to-day activities in neighbouring localities, and is visually unpleasant. The downstream water bodies are also exposed to the risk of foaming. Even though widespread, the foaming phenomena of surface water bodies are not adequately studied. The present study focuses on the foaming Lake of Bellandur in South India - wherein the sources and concentration of surfactants, effect of phosphorous, effect of bacteria, and its synergy with surfactants were studied. The study revealed that the significant source of pollution in the Lake was the entry of untreated sewage, which consisted of surfactants. The anionic surfactant concentration in the Lake was 17 ± 3 ppm, and surface tension remained around 50 mN/m, similar to the treatment plant inlet. The Phosphorus concentration in the Lake was high at 10 ± 3 ppm, with the primary source being feces and urine. Phosphorus indirectly affected the surfactant concentration of the Lake. Foam stability studies showed that mixed bacteria (filamentous) from Bellandur, in its stationary phase-played a crucial role in adding to the stability of the foam. The highest contributing filamentous bacterial family was found to be Flavobacteriia.

Influence of flow regime on the decomposition of diluted methane in a nitrogen rotating gliding arc.

This work reports the operation of rotating gliding arc (RGA) reactor at a high flow rate and the effect of flow regimes on its chemical performance, which is not explored much. When the flow regime was changed from transitional to turbulent flow ([Formula: see text]), operation mode transitioned from glow to spark type; the average electric field, gas temperature, and electron temperature raised ([Formula: see text], [Formula: see text], and [Formula: see text]). The decomposition's energy efficiency ([Formula: see text]) increased by a factor of 3.9 ([Formula: see text]). The first three dominant methane consumption reactions (MCR) for both the flow regimes were induced by [Formula: see text], CH, and [Formula: see text] (key-species), yet differed by their contribution values. The MCR rate increased by 80-148% [induced by e and singlet-[Formula: see text]], and decreased by 34-93% [CH, [Formula: see text], triplet-[Formula: see text]], due to turbulence. The electron-impact processes generated atleast 50% more of key-species and metastables for every 100 eV of input energy, explaining the increased [Formula: see text] at turbulent flow. So, flow regime influences the plasma chemistry and characteristics through flow rate. The reported RGA reactor is promising to mitigate the fugitive hydrocarbon emissions energy efficiently at a large scale, requiring some optimization to improve conversion.

A novel approach to baseline water quality assessment at local and catchment scale: a case study from Berambadi, India.

Optimal design and maintenance are necessary for the sustainability of wastewater treatment systems. In this study, we present the outcome of a novel approach to baseline assessment conducted prior to the design and deployment of a decentralized wastewater treatment system at a school in rural India. The baseline water quality monitoring protocol was deployed to assess (a) the quality and quantity of wastewater (greywater and blackwater) flows from the school and (b) the status of surface water and groundwater quality in the catchment. Hourly greywater flows and water quality trends were monitored across four seasons at the school. Average freshwater consumption at the school was 518 ± 322 L/day for hand washing and 287 ± 97 L/day for cooking meals. Greywater generation showed high hourly variations in COD levels. Greywater generated from hand wash and kitchen sources contributed to 110 g/day and 96 g/day of BOD5 respectively and 214 g/day and 141 g/day of COD respectively. Based on additional data from a self-reporting sanitation survey, the organic contaminant load generated from the toilet was estimated to be 1.5 ± 0.1 kg COD/day. At the catchment scale, both groundwater and surface water quality were monitored seasonally to assess the impact of raw sewage and stormwater inputs. Compared with borewells, high nitrate-N levels (> 10 mg/L) were observed in the village hand pump samples throughout the year. Maximum nitrate-N (16 mg/L) and fecal coliforms (3.9 log MPN/100 mL) levels were observed in surface waters during monsoons, indicating the impact of sewage and surface runoff on water quality. The proposed approach is useful to estimate data on freshwater use and wastewater generation at the school and hence to make the case for, and design of, a sustainable water management intervention.

Sustainable water resources through harvesting rainwater and the effectiveness of a low-cost water treatment.

Increases in world population and climate change are some of the pressures affecting water resources for current and future water availability. The variability in water availability can reduce agricultural yields, food supplies and potentially leads to malnutrition and spread of diseases in water-poor countries. Even some water-rich countries can experience prolonged periods of dry weather, causing a drop in water reservoirs levels, forcing more restricted water resources management. Rainwater harvesting is one key option in adapting to water shortage and future demands that may alleviate the pressure on existing water resources. This work evaluates a roof top rainwater harvesting system (RWHS) installed as part of a decentralised wastewater treatment system designed to enable a circular economy by providing a more reliable water supply system in a remote public school in rural India. The effectiveness of the RWHS in reducing the pressure on a groundwater supply was assessed along with the physical, chemical and microbial characteristics of the stored rainwater over time. Further, the application of a low-cost primary treatment to make the harvested water safe to use for multiple purposes was investigated. The results revealed that the harvested water was of acceptable quality at the start of collection, however, microbial abundance increased when the rainwater was stored for a long time without treatment. Thus, a chlorine dosing regimen for the RWHS was designed based on laboratory and field experiments. The results also demonstrated that the low-cost chlorination process was effective in the field in reducing microbial abundance in the stored water for more than 30 days. However, as the residual chlorine level was reduced with time to <0.2 mg/l in the storage vessel, the microbial abundance increased, albeit to a much lower level that meets the Indian bathing water standards. The results provide evidence that installed RWHS has reduced the pressure on existing water supply at the school by up to 25% of the water that used for washing and flushing with no treatment, and with regular chlorination, greater savings and multiple uses of the stored rainwater can be achieved.