Formation, Stability, and Crystallinity of Various Tricalcium Aluminate Polymorphs.

Tricalcium aluminate is an important phase of Portland clinker. In this paper, three polymorphs of C3A were prepared by means of the solid-state synthesis method using intensive milling of the raw material mixture which was doped with various amounts of Na2O and sintered at a temperature of 1300 °C for 2 h. The final products were evaluated through X-ray diffraction using Rietveld analysis. The effect of the Na dopant content on the change in the crystalline structure of tricalcium aluminate was studied. It was proven that the given preparation procedure, which differed from other studies, was close to the real conditions of the formation of Portland clinker, and it was possible to prepare a mixture of different polymorphs of calcium aluminate. Fundamental changes in the crystal structure occurred in the range of 3-4% Na, when the cubic structure changes to orthorhombic. At a dosage of Na dopant above 4%, the orthorhombic structure changes to a monoclinic structure. There are no clearly defined boundaries for the existence of individual C3A phases; these phases arise at the same time and overlap each other in the areas of their formation at different Na doses.

Application of a Method for Measuring the Grindability of Fine-Grained Materials by High-Speed Milling.

This article deals with the development of an alternative method for determining the grindability index of fine-grained materials. This method is inspired by the commercially used VTI method (also known as RTI after the Russian Thermal Energy Institute), which was widely used in Central and Eastern Europe in coal grinding. The disadvantage of the VTI method is that it uses a specific grinding device that otherwise has no other use and nowadays is no longer commonly available. Through the new method, high-energy grinding was performed using a commercially available planetary mill on silicate materials such as limestone, feldspar, corundum, and quartz. The effectiveness of the method was verified on clinker as a representative of widely used materials. The deviation between the grindability index calculated by the origin VTI method and the new developed method was on average approximately 8%; in the case of clinker grinding, it was only 3%. The results showed that the VTI method could be replaced by a new method that uses a modern available planetary mill and laser granulometry to determine the grindability index. The result is a new classification of materials according to their grindability indexes, which is based on the original VTI method.

Development of Crystallinity of Triclinic Polymorph of Tricalcium Silicate.

Tricalcium silicate phase is one of the main components of modern Portland cements. One of the major industrial challenges in the field of cement production is mapping the influence of individual clinker minerals and their polymorphs on the properties of industrially produced clinkers. The primary goal of this work is to improve the fundamental knowledge of understanding the process of alite formation and development from a crystallographic point of view. This study focuses on the observation of the crystallization process of triclinic alite during the firing process, which to date has not been thoroughly described. The effects of a wide range of temperatures and sintering periods on crystallinity were assessed on samples fired in platinum crucibles in a laboratory furnace. X-ray analysis-together with calculation of crystallinity using Scherrer's equation-was used for observing the crystallite size changes of T1 alite polymorph. According to the acquired results, among the most technologically and economically advantageous regimes of production of a high-quality triclinic alite is the temperature of 1450 °C and sintering time of two hours. The most significant changes in the crystallite size occurred within the first hour of sintering for the whole investigated temperature range.

Effect of Imposed Shear Strain on Steel Ring Surfaces during Milling in High-Speed Disintegrator.

This contribution characterizes the performance of a DESI 11 high-speed disintegrator working on the principle of a pin mill with two opposite counter-rotating rotors. As the ground material, batches of Portland cement featuring 6-7 Mohs scale hardness and containing relatively hard and abrasive compounds with the specific surface areas ranging from 200 to 500 m2/kg, with the step of 50 m2/kg, were used. The character of the ground particles was assessed via scanning electron microscopy and measurement of the absolute/relative increase in their specific surface areas. Detailed characterization of the rotors was performed via recording the thermal imprints, evaluating their wear by 3D optical microscopy, and measuring rotor weight loss after the grinding of constant amounts of cement. The results showed that coarse particles are ground by impacting the front faces of the pins, while finer particles are primarily milled via mutual collisions. Therefore, the coarse particles cause higher abrasion and wear on the rotor pins; after the milling of 20 kg of the 200 m2/kg cement sample, the wear of the rotor reached up to 5% of its original mass and the pins were severely damaged.