Effect of Thermal Activation on the Structure and Electrochemical Properties of Carbon Material Obtained from Walnut Shells.

A simple activation method has been used to obtain porous carbon material from walnut shells. The effect of the activation duration at 400 °C in an atmosphere with limited air access on the structural, morphological, and electrochemical properties of the porous carbon material obtained from walnut shells has been studied. Moreover, the structure and morphology of the original and activated carbon samples have been characterized by SAXS, low-temperature adsorption porosimetry, SEM, and Raman spectroscopy. Therefore, the results indicate that increasing the duration of activation at a constant temperature results in a reduction in the thickness values of interplanar spacing (d002) in a range of 0.38-0.36 nm and lateral dimensions of the graphite crystallite from 3.79 to 2.52 nm. It has been demonstrated that thermal activation allows for an approximate doubling of the specific SBET surface area of the original carbon material and contributes to the development of its mesoporous structure, with a relative mesopore content of approximately 75-78% and an average pore diameter of about 5 nm. The fractal dimension of the obtained carbon materials was calculated using the Frenkel-Halsey-Hill method; it shows that its values for thermally activated samples (2.52, 2.69) are significantly higher than for the original sample (2.17). Thus, the porous carbon materials obtained were used to fabricate electrodes for electrochemical capacitors. Electrochemical investigations of these cells in a 6 M KOH aqueous electrolyte were conducted by cyclic voltammetry, galvanostatic charge/discharge, and impedance spectroscopy. Consequently, it was established that the carbon material activated at 400 °C for 2 h exhibits a specific capacity of approximately 110-130 F/g at a discharge current density ranging from 4 to 100 mA/g.

Prediction of phase composition and mechanical properties Fe-Cr-C-B-Ti-Cu hardfacing alloys: Modeling and experimental Validations.

Alloys of the Fe-Cr-C-B-Ti alloy system are characterized by brittleness, which can be eliminated by the copper alloy, while corrosion resistance and abrasive wear resistance are significantly reduced. In this article, comprehensive investigations are carried out on the microstructure and mechanical properties of the proposed high-copper boron-containing alloy 110Cr4Cu7Ti1VB. Systematic theoretical and experimental studies encompassed thermodynamic calculations in ThermoCALC, production of flux-cored wires for hardfacing and welding, receipt of SEM images, acquisition of load and unload diagrams (discharge) via instrumental indentation on various phases of the deposited metal, and determination of chemical composition at indentation points through local chemical analysis. Mechanical properties of some phases such as γ-Fe phase (austenite), hemioboride Fe2(В,С) and boron cementite Fe3(В,С) and titanium carbide TiC in Fe-Cr-C-B-Ti-Сг alloy were determined by using density functional theory (DFT) implemented in the CASTEP code. We also compared these compounds; properties with other available commercial compounds, where available. With the knowledge of calculated elastic constants, the moduli, the Pugh's modulus ratio G/B, the Poisson's ratio v and the hardness of the title phases, 110Cr4Cu7Ti1VB were further predicted and discussed.

Porous Structure and Fractal Dimensions of Activated Carbon Prepared from Waste Coffee Grounds.

The present work reports the results of a systematic study on the evolution of the morphological properties of porous carbons derived from coffee waste using a one-pot potassium-hydroxide-assisted process at temperatures in the range of 400-900 °C. Raw materials and obtained carbons were studied by TG, DTG, SEM and nitrogen adsorption porosimetry. The decomposition temperature ranges for hemicellulose, cellulose and lignin as the main component of the feedstock have been established. It is shown that the proposed method for the thermochemical treatment of coffee waste makes it possible to obtain activated carbon with a controllable pore size distribution and a high specific surface area (up to 1050 m2/g). A comparative study of the evolution of the distribution of pore size, pore area and pore volume has been carried out based on the BJH and NL-DFT (slit-like pores approximation) methods. The fractal dimension of the obtained carbons has been calculated by Frenkel-Halsey-Hill method for single-layer and multilayer adsorptions.

Optical and Mechanical Properties of Layered Infrared Interference Filters.

The design and manufacturing technology of interference-absorbing short-wave filters based on a layered composition of Si-SiO on a sapphire substrate of various shapes was developed. A transition layer of SiO was applied to the surface of the substrate, alternating with layers of Si-SiO with an odd number of quarter-wave layers of materials with high (Si) and low refractive indices (SiO), and the application of an outer layer of SiO as an appropriate control of the materials' thickness. The optical properties of the infrared light filter were studied. It was established that the created design of the light filter provides the minimum light transmission in the visible region of the spectrum from 0.38 to 0.78 µm and the maximum in the near infrared region from 1.25 to 5 µm and has stable optical indicators. A method for studying the stress-strain state and strength of a multilayer coating of a light filter under the action of a local arbitrarily oriented load was developed. For simplicity in the analysis and for obtaining results in the analytical form, the one-dimensional model of the configuration "multilayer covering-firm substrate" constructed earlier by authors was used. From a mechanical point of view, the upper protective layer of the multilayer coating was modeled by a flexible plate, and the inner operational composite N-layer was subjected to Winkler's hypothesis about the proportionality of stresses and elastic displacements.

Multiclass Level-Set Segmentation of Rust and Coating Damages in Images of Metal Structures.

This paper describes the combined detection of coating and rust damages on painted metal structures through the multiclass image segmentation technique. Our prior works were focused solely on the localization of rust damages and rust segmentation under different ambient conditions (different lighting conditions, presence of shadows, low background/object color contrast). This paper method proposes three types of damages: coating crack, coating flaking, and rust damage. Background, paint flaking, and rust damage are objects that can be separated in RGB color-space alone. For their preliminary classification SVM is used. As for paint cracks, color features are insufficient for separating it from other defect types as they overlap with the other three classes in RGB color space. For preliminary paint crack segmentation we use the valley detection approach, which analyses the shape of defects. A multiclass level-set approach with a developed penalty term is used as a framework for the advanced final damage segmentation stage. Model training and accuracy assessment are fulfilled on the created dataset, which contains input images of corresponding defects with respective ground truth data provided by the expert. A quantitative analysis of the accuracy of the proposed approach is provided. The efficiency of the approach is demonstrated on authentic images of coated surfaces.

Microstructure and Wear Characterization of the Fe-Mo-B-C-Based Hardfacing Alloys Deposited by Flux-Cored Arc Welding.

An analysis of common reinforcement methods of machine parts and theoretical bases for the selection of their chemical composition were carried out. Prospects for using flux-cored arc welding (FCAW) to restore and increase the wear resistance of machine parts in industries such as metallurgy, agricultural, wood processing, and oil industry were presented. It is noted that conventional series electrodes made of tungsten carbide are expensive, which limits their widespread use in some industries. The scope of this work includes the development of the chemical composition of tungsten-free hardfacing alloys based on the Fe-Mo-B-C system and hardfacing technology and the investigation of the microstructure and the mechanical properties of the developed hardfacing alloys. The composition of the hardfacing alloys was developed by extending the Fe-Mo-B-C system with Ti and Mn. The determination of wear resistance under abrasion and impact-abrasion wear test conditions and the hardness measurement by means of indentation and SEM analysis of the microstructures was completed. The results obtained show that the use of pure metal powders as starting components for electrodes based on the Fe-Mo-B-C system leads to the formation of a wear-resistant phase Fe(Mo,B)2 during FCAW. The addition of Ti and Mn results in a significant increase in abrasion and impact-abrasion wear resistance by 1.2 and 1.3 times, respectively.

Optimization of Technological Parameters of the Process of Forming Therapeutic Biopolymer Nanofilled Films.

The prospects of using biopolymer nano-containing films for wound healing were substantiated. The main components of biopolymer composites are gelatin, polyvinyl alcohol, glycerin, lactic acid, distilled water, and zinc oxide (ZnO) nanoparticles (NPs). Biopolymer composites were produced according to various technological parameters using a mould with a chrome coating. The therapeutic properties of biopolymer films were evaluated by measuring the diameter of the protective effect. Physico-mechanical properties were studied: elasticity, vapour permeability, degradation time, and swelling. To study the influence of technological parameters of the formation process of therapeutic biopolymer nanofilled films on their therapeutic and physico-mechanical properties, the planning of the experiment was used. According to the results of the experiments, mathematical models of the second-order were built. The optimal values of technological parameters of the process are determined, which provide biopolymer nanofilled films with maximum healing ability (diameter of protective action) and sufficiently high physical and mechanical properties: elasticity, vapour permeability, degradation time and swelling. The research results showed that the healing properties of biopolymer films mainly depend on the content of ZnO NPs. Degradation of these biopolymer films provides dosed drug delivery to the affected area. The products of destruction are carbon dioxide, water, and a small amount of ZnO in the bound state, which indicates the environmental safety of the developed biopolymer film.