Preparation and characterization of CS/PAT/ MWCNT@MgAl-LDHs nanocomposite for Cd2+ removal and 4-nitrophenol reduction.

The present study evaluated the performance of multiwalled carbon nanotube (MWCNT)@MgAl-layered double hydroxide (LDH) nanoparticles loaded on poly-2 aminothiazole (PAT)/chitosan (CS) matrix (CPML) to remove Cd2+ ions from aqueous solution. The removal efficiency of modified CS/PAT with MWCNT@MgAl-LDHs was increased significantly compared to pure CS/PAT. The influence of heavy metal ion concentration, pH, temperature, adsorbent dosage, and contact time on the adsorption was examined. The optimum conditions for the adsorption of Cd2+ ions were 25 0C with the adsorbent dosage of 0.06 g and initial concentration for adsorption of the Cd2+ 100 mg/L at pH = 8. The maximum adsorption capacity was measured to be 1106.19 mg/g. The values of thermodynamic parameters namely Gibbs free energy (ΔG°), entropy change (ΔS°), and enthalpy change (ΔH°) indicated the feasibility, spontaneity and the endothermic nature of the adsorption process, respectively. The pseudo-second-order kinetics and the Langmuir model were selected as the best models for the adsorption process. Also, CPML nanocomposite (NC) was successfully tested for p-nitrophenol (p-NP) reduction in the presence of NaBH4. The reaction was nearly completed in 6 min. The fabricated CPML-NC could be reused for three consecutive cycles.

Surface modified of chitosan by TiO2@MWCNT nanohybrid for the efficient removal of organic dyes and antibiotics.

Considering the increase in the discharge of industrial effluents containing dyes and antibiotic resistance as a consequence of increasing the prescription and easy distribution of antibiotic drugs at the global level, designing efficient, biodegradable and non-toxic absorbents is necessary to reduce environmental harm effects. Herein, we present a series of novel eco-friendly ternary hybrid nanocomposite hydrogels CS/TiO2@MWCNT (CTM) composed of chitosan (CS), TiO2, and multiwalled carbon nanotube (MWCNT) for removal of methylene blue (MB) and methyl orange (MO) and common antibiotic ciprofloxacin (CIP) in aqueous medium. The combination of MWCNT and TiO2 improves the physicochemical properties of CS hydrogel and increases the adsorption capacity toward pollutants in the presence of different loadings. CTM hydrogel showed a specific surface area of 236.45 m2 g-1 with a pore diameter of 7.89 nm. Adsorption mechanisms were investigated in detail using kinetic, isotherm, and thermodynamic studies of adsorption as well as various spectroscopic techniques. Adsorption of these pollutants by CTM nanocomposite hydrogel occurred using various interactions at different pHs, which showed the obvious dependence of CTM adsorption capacity on pH. Electrostatic attractions, complex formation, π-π stacking and hydrogen bonds played a key role in the adsorption process. The adsorption of MB, MO, and CIP was fitted with the Langmuir isotherm with maximum adsorption capacities of 531.91, 1763.6, and 1510.5 mg g-1, respectively. CTM had a minor decrease in adsorption strength and showed good structural stability even after 8 adsorptions-desorption cycles. The total cost of producing a 1 kg adsorbent was calculated to be $ 450, which helped us determine the economic feasibility of the adsorbent in large-scale applications.

Recent advances in chitosan-based nanocomposites for adsorption and removal of heavy metal ions.

Due to the high concentration of various toxic and dangerous pollutants, industrial effluents have imposed increasing threats. Among the various processes for wastewater treatment, adsorption is widely used due to its simplicity, good treatment efficiency, availability of a wide range of adsorbents, and cost-effectiveness. Chitosan (CS) has received great attention as a pollutant adsorbent due to its low cost and many -OH and -NH2 functional groups that can bind heavy metal ions. However, weaknesses such as sensitivity to pH, low thermal stability and low mechanical strength, limit the application of CS in wastewater treatment. The modification of these functional groups can improve its performance via cross-linking and grafting agents. The porosity and specific surface area of CS in powder form are not ideal, so physical modification of CS via integration with other materials (e.g., metal oxide, zeolite, clay, etc.) leads to the creation of composite materials with improved absorption performance. This review provides reports on the application of CS and its nanocomposites (NCs) for the removal of various heavy metal ions. Synthesis strategy, adsorption mechanism and influencing factors on sorbents for heavy metals are discussed in detail.