Construction of a novel ternary synergistic CuFe2O4-SnO2-rGO heterojunction for efficient removal of cyanide from contaminated water.

Many industrial effluents release cyanide, a well-known hazardous and bio-recalcitrant pollutant, and thus, the treatment of cyanide wastewater is a major challenge. In the current study, a CuFe2O4-SnO2-rGO nanocomposite was synthesized to remove cyanide from an aqueous system. The structural and morphological characterizations of the nanomaterials were investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and energy dispersive spectra (EDX) analysis. The results revealed that almost 97.7% cyanide removal occurred using the nanocomposite at an initial concentration of 100 mg L-1 within 1 h. The experimental data were fitted to various adsorption models, among which the Langmuir model fitted the data very well, confirming the monolayer adsorption process. The kinetic investigation revealed that the cyanide adsorption process followed a pseudo-second-order kinetic model, indicating a chemisorption process with a high cyanide adsorption capacity of 114 mg g-1. The result of the intraparticulate diffusion model fitting revealed a decreasing slope value (K) from stage 1 to stage 2, indicating that external mass transfer is the predominating step. Moreover, the CuFe2O4-SnO2-rGO nanocomposite shows excellent reusability.

Multi-model exploration of groundwater quality and potential health risk assessment in Jajpur district, Eastern India.

The presence of fluoride and nitrate is a serious groundwater quality issue in India impacting human health. In the present study, 14 different hydrochemical parameters for 76 groundwater samples collected from the Jajpur district of Odisha, India, were evaluated. Entropy-weighted water quality index (EWQI), fixed-weight groundwater quality index (GWQI), principal component analysis (PCA), and rotated factor loading-based water quality index (PCWQI) were employed to assess groundwater quality. About 65.79 ± 4.68%, 33.55 ± 3.95%, and 0.66 ± 0.76% of the samples were rated as "excellent," "good," or "medium" quality, respectively, across the four different water quality indices, with a nominal rating discrepancy of 13.15%. Though 86% of samples consistently received excellent or good ratings across all WQI frameworks, concentrations of F- and NO3- in 36.8% and 11.84% of the samples exceeded the WHO permissible limit. In health risk assessment, about 38.15% of samples surpassed the F- hazard quotient (HQ > 1) posing non-carcinogenic health risks for children. The non-carcinogenic health risks due to NO3- were evident in 55.26% and 11.84% of samples for children and adults, respectively. The higher concentration of NO3- in some of the water samples, together with its positive correlation with HCO3-, may worsen groundwater pollution. The moderate correlation between Ca2+ and HCO3- (r = 0.410) and the insignificant correlation between Mg2+ and HCO3- (r = 0.234) suggests calcite dissolution is far more common than dolomite.

Assessment of kinetic and statistical models for predicting breakthrough curves of bio-colloid transport through saturated porous media.

The microbial contamination of groundwater and its prevention is a widespread concern in developing countries. The present study simulated the transportation and interception of bio-colloid, Escherichia coli in porous media experimentally using packed columns to address certain aspects of underexplored sorption potential and validated using several kinetic models. The breakthrough curves obtained through experiments are observed to be in good agreement with its prediction using kinetic models namely Thomas, Yoon-Nelson and Modified Dose-Response. The overall comparisons of R2 among all the three models suggest that the MDR model fits more perfectly to experimental results. The combined effect of independent factors (column depth, particle size and alumina content) on response factors (maximum relative concentration and time required to achieve peak concentration) was investigated by using Box-Behnken Design under Response Surface Methodology (RSM) to check statistical significancy of independent factors. The R2 values for both response factors are observed to be 0.94 and 0.99, indicating a very high correlation between predicted and actual values. The results obtained in the present study also confirms that the travel distance and particle size are the statistically significant parameters that efficiently impact on sorption of Escherichia coli during their transport whereas the alumina content also affects the sorption but is observed to be a statistically non-significant.

Technological advancements in valorisation of industrial effluents employing hydrothermal liquefaction of biomass: Strategic innovations, barriers and perspectives.

Hydrothermal liquefaction (HTL) is identified as a promising thermochemical technique to recover biofuels and bioenergy from waste biomass containing low energy and high moisture content. The wastewater generated during the HTL process (HTWW) are rich in nutrients and organics. The release of the nutrients and organics enriched HTWW would not only contaminate the water bodies but also lead to the loss of valued bioenergy sources, especially in the present time of the energy crisis. Thus, biotechnological as well as physicochemical treatment of HTWW for simultaneous extraction of valuable resources along with reduction in polluting substances has gained significant attention in recent times. Therefore, the treatment of wastewater generated during the HTL of biomass for reduced environmental emission and possible bioenergy recovery is highlighted in this paper. Various technologies for treatment and valorisation of HTWW are reviewed, including anaerobic digestion, microbial fuel cells (MFC), microbial electrolysis cell (MEC), and supercritical water gasification (SCWG). This review paper illustrates that the characteristics of biomass play a pivotal role in the selection process of appropriate technology for the treatment of HTWW. Several HTWW treatment technologies are weighed in terms of their benefits and drawbacks and are thoroughly examined. The integration of these technologies is also discussed. Overall, this study suggests that integrating different methods, techno-economic analysis, and nutrient recovery approaches would be advantageous to researchers in finding way for maximising HTWW valorisation along with reduced environmental pollution.

Sustainable utilization of food waste for bioenergy production: A step towards circular bioeconomy.

The population growth, along with lifestyle changes, has resulted in unprecedented levels of food waste at all phases of the supply chain, including harvest, packing, transportation, and consumption. Conventional practices involve dumping of food waste with municipal garbage. However, these methods have serious environmental and health consequences. Food waste has a great recycling perspective due to its high biodegradability and water content, making it an ideal substrate for the production of biofuels and other industrially important chemicals including pigments, enzymes, organic acids, and essential oils. This review extensively covers conversion of food waste to generate bioenergy which will help to reduce environmental pollution and facilitate implementation of a circular bioeconomy. Moreover, review also highlights novel technologies like supercritical fluid extraction, ultra-sonication, pressurized liquid extraction, and microwave assisted extractions that are being employed in food waste management to increase the efficiency of value-added product recovery in an economically viable manner. Metabolic engineering of microorganisms for specificity of product would be a future breakthrough in food waste valorization/management.

A critical review on biogas production from edible and non-edible oil cakes.

The circular economy is at the core of sustainable development. The generation of biogas from the massive quantity of agricultural waste biomass is one of the critical drivers of the circular economy. Biogas has enormous renewable energy potential and has multitudes of applications in today's energy-intensive society. Oil cakes, a known Agri-waste, are the by-product of oil processing, and are rich in nutrients. The edible oil cakes mostly have been used as a cattle feed; however, non-edible oil cakes do not find many applications. Their production is continuously escalating as non-edible oils are increasingly used in biodiesel production. Recently, there is a lot of emphasis on biogas production from these oil cakes. This paper reviews in detail biogas production from both edible and non-edible oil cakes. Chemical composition and various other applications of the cakes are also reviewed in brief. The survey illustrates that multiple parameters such as inoculum sources, co-digestion and reactor design affect the biogas production. All those factors, along with biogas upgrading and the economy of the process, are reviewed. Finally, future research opportunities are suggested to improve the viability of the biogas production from oil cakes.

Greenhouse gas emissions in sludge ultrasonication followed by anaerobic digestion processes.

This paper presents the greenhouse gas (GHG) emissions during ultrasonication of sludge and anaerobic digestion (AD) of the ultrasonicated sludge using mass-energy balance. Computation of the net energy (energy recovered - energy input) revealed that high solids concentration with low sonication specific energy provides positive net energy. Moreover, the GHG emissions can be minimised at low sonication specific energy input and high solids concentration compared to that of the control without sonication. Increase in temperature of sludge during sonication will reduce the energy input required for raising the sludge temperature to AD temperature and thus decreases the GHG emissions. With energy recovery from the methane produced in AD, the total GHG emissions can further be reduced, lower than that without energy recovery from methane.

Nutrient removal from domestic wastewater: A comprehensive review on conventional and advanced technologies.

Nitrogen and phosphorous are indispensable for growth and vitality of living beings, hence termed as nutrients. However, discharge of nutrient rich waste streams to aquatic ecosystems results in eutrophication. Therefore, nutrient removal from wastewater is crucial to meet the strict nutrient discharge standards. Similarly, nutrient recovery from waste streams is vital for the realization of a circular economy by avoiding the depletion of finite resources. This manuscript presents analysis of existing information on different conventional as well as advanced treatment technologies that are commonly practiced for the removal of nutrient from domestic wastewater. First, the information pertaining to the biological nutrient removal technologies are discussed. Second, onsite passive nutrient removal technologies are reviewed comprehensively. Third, advanced nutrient removal technologies are summarized briefly. The mechanisms, advantages, and disadvantages of these technologies along with their efficiencies and limitations are discussed. An integrated approach for simultaneous nutrient removal and recovery is recommended. The fifth section of the review highlights bottlenecks and potential solutions for successful implementation of the nutrient removal technologies. It is anticipated that the review will offer an instructive overview of the progress in nutrient removal and recovery technologies and will illustrate necessity of further investigations for development of efficient nutrient removal and recovery processes.

The applicability of anaerobically treated domestic wastewater as a nutrient medium in hydroponic lettuce cultivation: Nitrogen toxicity and health risk assessment.

The applicability of anaerobic effluent (AE) from an anaerobic membrane bioreactor (AnMBR) treating domestic wastewater as a nutrient medium was evaluated through hydroponic cultivation of lettuce. The growth of lettuce plants on AE media was significantly inhibited to 31-40% in height and 36-48% in number of leaves compared to that on half-strength Hoagland solution (HHS) as a control. The primary cause of inhibition was nitrite toxicity as induced by partial nitrification. Therefore, the nitrification of AE as a pre-treatment step was adopted to prevent the toxicity of nitrite. The heights of lettuce grown on nitrified anaerobic effluent (NAE) and nitrified anaerobic effluent with 96 mg/L sulfate (NAES) were in the range of 11.4-11.5 cm and was comparable to that on control solution (11.4 cm). The potential health risk for heavy metals was insignificant based on health risk index (HRI < 1) and targeted hazardous quotient (THQ < 1). These results show that efficient crop production can be achieved with AE, but suitable pre-treatment steps should be followed.

Process optimization and energy analysis of vacuum degasifier systems for the simultaneous removal of dissolved methane and hydrogen sulfide from anaerobically treated wastewater.

The control of dissolved methane (CH4) and hydrogen sulfide (H2S) emissions in anaerobic effluents is essential for minimizing the environmental implications of greenhouse gases, odor, and carbon footprint, as well as for preventing energy loss in the form of unrecovered dissolved methane. This study assessed the feasibility of a vacuum degasifier for the removal of CH4 and H2S from staged anaerobic fluidized membrane bioreactor (SAF-MBR) effluent. The optimization results showed that the efficiency of the nozzle fitted degasifiers were superior to the media packed ones. In three-stage vacuum degasifiers at a -0.8 bar vacuum pressure, H2S removal was mostly pH dependent and 88% removal efficiency was achieved with an initial concentration of 13.6 mg/L. Methane removal was dependent primarily on the number of degasifier units, and approximately 94% efficiency was achieved in a three-stage degasifier. Energy balance analysis showed that energy production exceeded the system energy requirements with 0.05-0.07 kWh/m3 of surplus energy. These results provide deep insights into this new technology for simultaneous removal of dissolved CH4 and H2S, which can be referred for potential future applications.

A brief review of anaerobic membrane bioreactors emphasizing recent advancements, fouling issues and future perspectives.

This review summarizes the recent development and studies of anaerobic membrane bioreactor (AnMBR) to control fouling issues. AnMBR is an emerging waste water treatment technology mainly because of its low sludge residual, high volumetric organic removal rate, complete liquid-solid separation, better effluent quality, efficient resource recovery and the small footprint. This paper surveys the fundamental aspects of AnMBRs, including its applications, membrane configurations, and recent progress for enhanced reactor performance. Furthermore, the membrane fouling, a major restriction in the practical application of AnMBR, its mechanism and antifouling strategies like membrane cleaning, quorum quenching, ultrasonic treatment, membrane modifications, and antifouling agents are briefly discussed. Based on the review, the key issues that require urgent attention to facilitate large scale and integrated application of AnMBR technology are identified and future research perspectives relating to the prevalent issues are proposed.

Effects of sodium hypochlorite concentration on the methanogenic activity in an anaerobic fluidized membrane bioreactor.

The effect of membrane cleaning chemical, NaOCl on specific acetoclastic methanogenic activity (SAMA) of biomass in the anaerobic fluidized membrane bioreactors (AFMBRs) was assessed. Granular activated carbon (GAC) was used as a fluidizing media in the AFMBR to provide membrane scouring effect and surface for biofilm attachment. Effect of NaOCl on methane production was negligible for GAC with biofilm (bGAC) samples up to 150 mg NaOCl/g VSS, but was significant for the bulk liquid samples with noticeable lag period over 300 h even at the dosage of 50 mg NaOCl/g VSS. The toxicity of NaOCl on methane production was reduced in samples with virgin GAC (vGAC) by allowing 14 days of biomass buildup period prior to NaOCl addition, although the vGAC alone did not alleviate the toxicity. The results revealed that NaOCl concentrations beyond 100 mg/L within the reactor inhibited methanogenic activity and the effects were more pronounced on suspended biomass than the immobilized biomass on GAC.

Role of Bacillus cereus GS-5 strain on simultaneous nitrogen and phosphorous removal from domestic wastewater in an inventive single unit multi-layer packed bed bioreactor.

This work evaluates the performance efficiency of a newly developed single unit packed bed bioreactor for nutrient removal from domestic wastewater. The packing materials, including dolochar, and a mixture of waste organic solid substance, were immobilized with a simultaneous nitrifying, denitrifying and phosphate removing bacterial strain, Bacillus cereus GS-5 and packed in the bioreactor alternatively in multiple layers. The bioreactor was operated continuously for a period of 70 days using both synthetic and real domestic wastewater (NH4+-N 30-100 mg/L, NO3--N 10-100 mg/L, PO43--P 5-20 mg/L and COD 250-1000 mg/L). The innovative single unit bioreactor exhibited simultaneous removal of NH4+-N (87.1-93.1%), NO3--N (69.4-88.4%), PO43--P (84-100%), and even COD (69.8-92.1%), in a remarkable disparity to traditional distinct aerobic-anaerobic treatment systems. This work advocated for a promising and feasible application prospect of the developed single unit packed bed bioreactor in domestic wastewater treatment emphasizing on nutrient removal.

Simultaneous removal of nitrogen and phosphorous from domestic wastewater using Bacillus cereus GS-5 strain exhibiting heterotrophic nitrification, aerobic denitrification and denitrifying phosphorous removal.

A newly isolated GS-5 strain exhibiting heterotrophic nitrification, aerobic denitrification and denitrifying phosphorous removal was identified as Bacillus cereus GS-5 based on its phenotypic and phylogenetic characteristics. The isolate had exhibited efficient NH4+-N, NO3--N, NO2--N and PO43--P removal from nutrient spiked real domestic wastewater with average rates of 2.62, 2.69, 1.16 and 0.42mgL-1h-1, respectively under aerobic condition. Metabolic inhibitor based mass balance analysis indicated that dinitrogen gas (41%), intracellular nitrogen (29%) and intracellular phosphorous (60%) were the major fates of the initial NH4+-N and PO43--P. The successfully expression of hydroxylamine oxidase (hao), nitrate reductase (nar), nitrite reductase (nir) and poly phosphate kinase (ppk) enzyme in the cell free extracts and PCR amplification of nar, nir and ppk genes in the isolated strain provided further evidences for the nutrient removal possibility. A possible pathway of for nitrogen removal by GS-5 is suggested.

Characterizing novel thermophilic amylase producing bacteria from taptapani hot spring, odisha, India.

BACKGROUND: Amylases play a vital role in biotechnological studies and rank an important position in the world enzyme market (25% to 33%). Bioprocess method of amylase production is more effective than the other sources, since the technique is easy, cost effective, fast, and the enzymes of required properties can be procured. OBJECTIVES: The current study aimed to report the characteristics of novel amylase producing bacterial strains isolated from Taptapani hot spring, Odisha, India. MATERIALS AND METHODS: Bacterial strains were isolated by dilution plating method from the water samples collected from Taptapani Hot Spring, Odisha and screened for amylase production through starch hydrolysis. The bacterial isolates were identified morphologically, biochemically, and finally by 16S rDNA profiling. RESULTS: Based on the morphological, physiological, biochemical characteristics and the molecular characterization, the isolates SS1, SS2, and SS3 were identified as Bacillus barbaricus, Aeromonas veroni, and Stenotrophomonas maltophilia, respectively. The approximate molecular weight of enzymes from SS1, SS2, and SS3 strains were 19 kDa, 56 kDa and 49 kDa, respectively. CONCLUSIONS: The current report isolates, characterizes, and demonstrates the novel heat-adapted amylase-producing bacteria SS1, SS2 and SS3 from Taptapani hot spring, indicating its potentiality and stability under acidic conditions.