Terahertz sensing of reduced graphene oxide nanosheets using sub-wavelength dipole cavities.

Because of extraordinary optoelectronic properties, two-dimensional (2D) materials are the subject of intense study in recent times. Hence, we investigate sub-wavelength dipole cavities (hole array) as a sensing platform for the detection of 2D reduced graphene oxide (r-GO) using terahertz time-domain spectroscopy (THz-TDS). The r-GO is obtained by reducing graphene oxide (GO) via Hummer's method. Its structural characteristics are verified using X-ray diffraction (XRD) and Raman spectroscopy. We also assessed the morphology and chemistry of r-GO nanosheets by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDAX), and Fourier Transformed Infrared (FTIR) spectroscopy. Further, we studied the surface plasmon resonance (SPR) characteristics of r-GO nanosheets hybridized dipole cavities using THz-TDS by varying the r-GO thickness on top of the dipole cavities, since these cavities are well known for sustaining strong SPRs. Based on these, we experimentally obtained a sensitivity of 12 GHz/µm for the porous r-GO film. Thus, a modification in SPR characteristics can be employed towards the identification and quantification of r-GO by suitably embedding it on an array of dipole cavities. Moreover, we have adopted a generic approach that can be expanded to sense other 2D materials like Boron Nitride (BN), phosphorene, MoS2, etc., leading to the development of novel THz nanophotonic sensing devices.

New insights into APCVD grown monolayer MoS2 using time-domain terahertz spectroscopy.

In modern era, wireless communications at ultrafast speed are need of the hour and search for its solution through cutting edge sciences is a new perspective. To address this issue, the data rates in order of terabits per second (TBPS) could be a key step for the realization of emerging sixth generation (6G) networks utilizing terahertz (THz) frequency regime. In this context, new class of transition metal dichalcogenides (TMDs) have been introduced as potential candidates for future generation wireless THz technology. Herein, a strategy has been adopted to synthesize high-quality monolayer of molybdenum di-sulfide (MoS2) using indigenously developed atmospheric pressure chemical vapor deposition (APCVD) set-up. Further, the time-domain transmission and sheet conductivity were studied as well as a plausible mechanism of terahertz response for monolayer MoS2 has been proposed and compared with bulk MoS2. Hence, the obtained results set a stepping stone to employ the monolayer MoS2 as potential quantum materials benefitting the next generation terahertz communication devices.

Simultaneous excitations of odd and even order resonances in plasmonic metasurfaces for an orthogonal terahertz probe.

Most of the compelling phenomena pertaining to plasmonic metamaterials revolve around the associated odd and even order resonances. However, excitation of odd and even order modes is polarization sensitive, particularly in the case of well-accepted split-ring resonator based terahertz (THz) plasmonic metasurfaces. Such a drawback limits the practical applications of plasmonic metasurfaces across the electromagnetic spectrum. In this context, we experimentally demonstrate multi-split-ring resonator based THz metasurfaces capable of simultaneously sustaining odd and even order resonances when the polarization of the probe beam is altered through 90°. We believe this work should be beneficial in realizing polarization-independent switches and frequency selective surfaces.

External bias dependent dynamic terahertz propagation through BiFeO3film.

Interactions of terahertz radiations with matter can lead to the realization of functional devices related to sensing, high-speed communications, non-destructive testing, spectroscopy, etc In spite of the versatile applications that THz can offer, progress in this field is still suffering due to the dearth of suitable responsive materials. In this context, we have experimentally investigated emerging multiferroic BiFeO3 film (∼200 nm) employing terahertz time-domain spectroscopy (THz-TDS) under vertically applied (THz propagation in the same direction) electric fields. Our experiments reveal dynamic modulation of THz amplitude (up to about 7% within 0.2-1 THz frequency range) because of the variation in electric field from 0 to 600 kV cm-1. Further, we have captured signatures of the hysteretic nature of polarization switching in BiFeO3film through non-contact THz-TDS technique, similar trends are observed in switching spectroscopy piezoresponse force microscope measurements. We postulate the modulation of THz transmissions to the alignment/switching of ferroelectric polarization domains (under applied electric fields) leading to the reduced THz scattering losses (hence, reduced refractive index) experienced in the BiFeO3film. This work indicates ample opportunities in integrating nanoscale multiferroic material systems with THz photonics in order to incorporate dynamic functionalities to realize futuristic THz devices.

Hybrid resonant cavities: A route towards phase engineered THz metasurfaces.

Coupled resonant cavities can enable strong photon energy confinement to facilitate the miniaturization of functional photonic devices for applications in designs of sensors, modulators, couplers, waveguides, color filters etc. Typically, the resonances in subwavelength plasmonic cavities rely on the excitation of surface plasmons at specific phase-matching conditions, usually determined by the lattice parameters and constituent material properties. Contrary to this notion, we experimentally demonstrate the control and manipulation of cavity resonances via suitably modifying the split ring resonator geometry in hybrid plasmonic-metasurface (dipole cavity-SRR) configuration without altering the lattice parameters. This results to the excitation of dual resonance peaks. Such dual channel characteristics demonstrate high quality (Q) factor, multi-band resonances, not permissible with typical (unhybridized) plasmonic dipole cavities. We envisage such hybrid meta-cavity designs can become important ingredients for futuristic terahertz devices that can hold the key for sixth generation (6G) communications, designer filters, dual channel sensors etc.

Magnetic wire: transverse magnetism in a one-dimensional plasmonic system.

We experimentally demonstrate magnetic wire in a coupled, cut-wire pair-based metasurface operating at the terahertz frequencies. A dominant transverse magnetic dipole (non-axial circulating conduction current) is excited in one of the plasmonic wires that constitute the coupled system, whereas the other wire remains electric. Despite having large asymmetry-induced strong radiation channels in such a metasurface, non-radiative current distributions are obtained as a direct consequence of interaction between the electric and magnetic wire(s). We demonstrate a versatile platform to transform an electric to a magnetic wire and vice-versa through asymmetry-induced polymorphic hybridization with potential applications in photonic/electrical integrated circuits.

Lattice-induced plasmon hybridization in metamaterials.

We explore an inherent connection between two fundamental concepts of physics-resonance (eigen mode) hybridization and lattice effect in sub-wavelength periodic structures. Our study reveals that coupling with lattice mode is the prime deciding factor to determine the nature, position, and line shape of the hybridized states. Modulating lattice modes can effectively control mode hybridization and tune the relative position of hybridized modes [symmetric (electric), anti-symmetric (magnetic)] without changing any other structural dimensions in subwavelength plasmonic metamaterials. Outcomes of this study can be exploited in designing linear and nonlinear photonic structures toward futuristic meta devices.

Modulating Fundamental Resonance in Capacitive Coupled Asymmetric Terahertz Metamaterials.

In this work, we experimentally investigate near-field capacitive coupling between a pair of single-gap split ring resonators (SRRs) in a terahertz metamaterial. The unit cell of our design comprises of two coupled SRRs with the split gaps facing each other. The coupling between two SRRs is examined by changing the gap of one resonator with respect to the other for several inter resonator separations. When split gap size of one resonator is increased for a fixed inter-resonator distance, we observe a split in the fundamental resonance mode. This split ultimately results in the excitation of narrow band low frequency resonance mode along with a higher frequency mode which gets blue shifted when the split gap increases. We attribute resonance split to the excitation of symmetric and asymmetric modes due to strong capacitive or electric interaction between the near-field coupled resonators, however blue shift of the higher frequency mode occurs mainly due to the reduced capacitance. The ability of near-field capacitive coupled terahertz metamaterials to excite split resonances could be significant in the construction of modulator and sensing devices beside other potential applications for terahertz domain.

Role of Resonance Modes on Terahertz Metamaterials based Thin Film Sensors.

We investigate thin film sensing capabilities of a terahertz (THz) metamaterial, which comprises of an array of single split gap ring resonators (SRRs). The top surface of the proposed metamaterial is covered with a thin layer of analyte in order to examine various sensing parameters. The sensitivity and corresponding figure of merit (FoM) of the odd and even resonant modes are analyzed with respect to different thicknesses of the coated analyte film. The sensing parameters of different resonance modes are elaborated and explained with appropriate physical explanations. We have also employed a semi-analytical transmission line model in order to validate our numerically simulated observations. Such study should be very useful for the development of metamaterials based sensing devices, bio-sensors etc in near future.